Miktoarm star polymers: advances in synthesis, self-assembly, and applications

Atom Transfer Radical Polymerization

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Design and development of polymers for gene delivery

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Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials

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The convergence of synthetic organic and polymer chemistries

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On the origins of morphological complexity in block copolymer surfactants

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Polymer Therapeutics: Concepts and Applications

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Block copolymer based nanostructures: Materials, processes, and applications to electronics

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Multicompartment Micelles from ABC Miktoarm Stars in Water

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Click Chemistry beyond Metal‐Catalyzed Cycloaddition

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The power of thiol‐ene chemistry

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Soluble Polymer Carriers for the Treatment of Cancer: The Importance of Molecular Architecture

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Macromolecular Engineering through Click Chemistry and Other Efficient Transformations

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Macromolecular architectures by living and controlled/living polymerizations

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Polylactones 48. SnOct2-Initiated Polymerizations of Lactide: A Mechanistic Study

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Linear and non-linear triblock terpolymers. Synthesis, self-assembly in selective solvents and in bulk

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Synthesis and Characterization of Star Polymers with Varying Arm Number, Length, and Composition from Organic and Hybrid Inorganic/Organic Multifunctional Initiators

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Synthesis of miktoarm star (?-star) polymers

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“Click” methodologies: efficient, simple and greener routes to design dendrimers

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Morphologies of Multicompartment Micelles Formed by ABC Miktoarm Star Terpolymers

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Synthesis of 3-Miktoarm Stars and 1st Generation Mikto Dendritic Copolymers by “Living” Radical Polymerization and “Click” Chemistry

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Simultaneous, Segregated Storage of Two Agents in a Multicompartment Micelle

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Architectural Control in “Living” Free Radical Polymerizations: Preparation of Star and Graft Polymers

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A brief review of ‘schizophrenic’ block copolymers

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Synthesis and morphology of ABC heteroarm star terpolymers of polystyrene, polybutadiene and poly(2-vinylpyridine)

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Sphere, Cylinder, and Vesicle Nanoaggregates in Poly(styrene- b -isoprene) Diblock Copolymer Solutions

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Laterally Nanostructured Vesicles, Polygonal Bilayer Sheets, and Segmented Wormlike Micelles

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Arm-First Method As a Simple and General Method for Synthesis of Miktoarm Star Copolymers

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ABC‐type hetero‐arm star terpolymers through “Click” chemistry

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Control of Structure in Multicompartment Micelles by Blending μ-ABC Star Terpolymers with AB Diblock Copolymers

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Structural Control in ATRP Synthesis of Star Polymers Using the Arm-First Method

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Dendrimer design using CuI-catalyzed alkyne–azide “click-chemistry”

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Synthesis of Degradable Miktoarm Star Copolymers via Atom Transfer Radical Polymerization

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Synthesis and characterization of model 4-miktoarm star co- and quaterpolymers

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Research in Macromolecular Science: Challenges and Opportunities for the Next Decade

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Convergent Synthesis of Second Generation AB-Type Miktoarm Dendrimers Using “Click” Chemistry Catalyzed by Copper Wire

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Drug Delivery Technologies: The Way Forward in the New Decade

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Synthesis of Amphiphilic Miktoarm ABC Star Copolymers by RAFT Mechanism Using Maleic Anhydride as Linking Agent

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Multicompartment Micelles from Polyester-Containing ABC Miktoarm Star Terpolymers

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Synthesis of ABC 3-Miktoarm Star Terpolymers from a Trifunctional Initiator by Combining Ring-Opening Polymerization, Atom Transfer Radical Polymerization, and Nitroxide-Mediated Radical Polymerization

He, T., Li, D., Sheng, X., & Zhao, B. (2004) · Macromolecules · doi:10.1021/ma036010c · Cited by 128

Facile Preparation of Well-Defined AB2 Y-Shaped Miktoarm Star Polypeptide Copolymer via the Combination of Ring-Opening Polymerization and Click Chemistry

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Synthesis and ‘Schizophrenic' Micellization of Double Hydrophilic AB4Miktoarm Star and AB Diblock Copolymers: Structure and Kinetics of Micellization

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Diels–Alder “Click” Chemistry in Designing Dendritic Macromolecules

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Direct Synthesis and Stimulus-Responsive Micellization of Y-Shaped Hydrophilic Block Copolymers

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Star Polymers with Alternating Arms from Miktofunctional μ-Initiators Using Consecutive Atom Transfer Radical Polymerization and Ring-Opening Polymerization

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Simple Approach to Stabilized Micelles Employing Miktoarm Terpolymers and Stereocomplexes with Application in Paclitaxel Delivery

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Toward an Easy Access to Asymmetric Stars and Miktoarm Stars by Atom Transfer Radical Polymerization

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Advances in the Elegance of Chemistry in Designing Dendrimers

Hourani, R., & Kakkar, A. K. (2010) · Macromolecular Rapid Communications · doi:10.1002/marc.200900712 · Cited by 111

Polymersome Formation from AB2 Type 3-Miktoarm Star Copolymers

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Selectively Degradable Core Cross-Linked Star Polymers

Wiltshire, J. T., & Qiao, G. G. (2006) · Macromolecules · doi:10.1021/ma0622027 · Cited by 108

Synthesis of Functionalized Asymmetric Star Polymers Containing Conductive Polyacetylene Segments by Living Anionic Polymerization

Youliang, Z., Higashihara, T., Sugiyama, K., & Hirao, A. (2005) · Journal of the American Chemical Society · doi:10.1021/ja054821l · Cited by 106

Preparation of ABC miktoarm star terpolymer containing poly(ethylene glycol), polystyrene, and poly(tert‐butylacrylate) arms by combining diels–alder reaction, atom transfer radical, and stable free radical polymerization routes

Durmaz, H., Karatas, F., Tunca, Ü., & Hızal, G. (2005) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.21160 · Cited by 106

Helical Vesicles, Segmented Semivesicles, and Noncircular Bilayer Sheets from Solution-State Self-Assembly of ABC Miktoarm Star Terpolymers

Kong, W., Li, B., Jin, Q., Ding, D., & Shi, A. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900405r · Cited by 102

Novel miktofunctional initiator for the preparation of an ABC‐type miktoarm star polymer via a combination of controlled polymerization techniques

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Synthesis of Well-Defined Y-Shaped Zwitterionic Block Copolymers via Atom-Transfer Radical Polymerization

Cai, Y., & Armes, S. P. (2004) · Macromolecules · doi:10.1021/ma048511j · Cited by 101

Synthesis, Characterization, and Evaluation as Transfection Reagents of Double-Hydrophilic Star Copolymers: Effect of Star Architecture

Georgiou, T. K., Vamvakaki, M., Phylactou, L. A., & Patrickios, C. S. (2005) · Biomacromolecules · doi:10.1021/bm050307w · Cited by 101

PCL Star Polymer, PCL-PS Heteroarm Star Polymer by ATRP, and Core-Carboxylated PS Star Polymer Thereof

Du, J., & Chen, Y. (2004) · Macromolecules · doi:10.1021/ma035457i · Cited by 99

“Click” Chemistry and Radical Polymerization: Potential Loss of Orthogonality

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pH-Responsive Supramolecular Self-Assembly of Well-Defined Zwitterionic ABC Miktoarm Star Terpolymers

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Multicompartment Micelles from pH-Responsive Miktoarm Star Block Terpolymers

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Synthesis of Miktoarm Star Polymers via ATRP Using the “In−Out” Method: Determination of Initiation Efficiency of Star Macroinitiators

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Synthesis of Low-Polydispersity Miktoarm Star Copolymers via a Simple “Arm-First” Method: Macromonomers as Arm Precursors

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One‐pot preparation of 3‐miktoarm star terpolymers via click [3 + 2] reaction

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Synthesis of Well-Defined 4-Miktoarm Star Quarterpolymers (4μ-SIDV) with Four Incompatible Arms: Polystyrene (S), Polyisoprene-1,4 (I), Poly(dimethylsiloxane) (D), and Poly(2-vinylpyridine) (V)

Mavroudis, A., & Hadjichristidis, N. (2005) · Macromolecules · doi:10.1021/ma052040z · Cited by 84

Synthesis of ABC-type miktoarm star polymers by “click” chemistry, ATRP and ROP

Deng, G., Ma, D., & Xu, Z. (2007) · European Polymer Journal · doi:10.1016/j.eurpolymj.2007.01.034 · Cited by 83

One‐pot preparation of 3‐miktoarm star terpolymers via “click chemistry” and atom transfer nitroxide radical coupling reaction

Fu, Q., Wang, G., Lin, W., & Huang, J. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23205 · Cited by 83

Synthesis, Characterization, and Evaluation as Transfection Reagents of Ampholytic Star Copolymers: Effect of Star Architecture

Georgiou, T. K., Phylactou, L. A., & Patrickios, C. S. (2006) · Biomacromolecules · doi:10.1021/bm060657y · Cited by 82

A new approach to 3-miktoarm star polymers using a combination of reversible addition–fragmentation chain transfer (RAFT) and ring opening polymerization (ROP) via “Click” chemistry

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Tailored polymer architectures by reversible addition-frasmentation chain transfer

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Synthesis and Characterization of Triptych μ-ABC Star Triblock Copolymers

Li, Z., Hillmyer, M. A., & Lodge, T. P. (2004) · Macromolecules · doi:10.1021/ma048607d · Cited by 82

ABCD 4‐miktoarm star quarterpolymers using click [3 + 2] reaction strategy

Altintas, O., Hızal, G., & Tunca, Ü. (2007) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22463 · Cited by 82

Design and synthesis of star polymers with hetero-arms by the combination of controlled radical polymerizations and click chemistry

Zhu, J., Zhu, X., Kang, E. T., & Neoh, K. G. (2007) · Polymer · doi:10.1016/j.polymer.2007.10.004 · Cited by 81

Synthesis of Amphiphilic ABC 3-Miktoarm Star Terpolymer by Combination of Ring-Opening Polymerization and “Click” Chemistry

Yuan, Y., Wang, Y., Du, J., & Wang, J. (2008) · Macromolecules · doi:10.1021/ma801452n · Cited by 78

Synthesis of miktoarm star and miktoarm star block copolymers via a combination of atom transfer radical polymerization and stable free‐radical polymerization

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Miktoarm stars of poly(ethylene oxide) and poly(dimethylaminoethyl methacrylate): manipulation of micellization by temperature and light

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Evolution of Multicompartment Micelles to Mixed Corona Micelles Using Solvent Mixtures

Liu, C., Hillmyer, M. A., & Lodge, T. P. (2008) · Langmuir · doi:10.1021/la802336k · Cited by 73

Synthesis and Aggregation Behavior of Multi‐Responsive Double Hydrophilic ABC Miktoarm Star Terpolymer

Zhang, Y., Liu, H., Hu, J., Li, C., & Liu, S. (2009) · Macromolecular Rapid Communications · doi:10.1002/marc.200800820 · Cited by 71

Well-Defined Star Polymers with Mixed-Arms by Sequential Polymerization of Atom Transfer Radical Polymerization and Reverse Addition−Fragmentation Chain Transfer on a Hyperbranched Polyglycerol Core

Liu, C., Zhang, Y., & Huang, J. (2007) · Macromolecules · doi:10.1021/ma071432y · Cited by 68

Synthesis of ABCD 4‐Miktoarm star‐shaped quarterpolymers by combination of the “click” chemistry with multiple polymerization mechanism

Wang, G., Luo, X., Liu, C., & Huang, J. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22550 · Cited by 67

Synthesis of amphiphilic and thermoresponsive ABC miktoarm star terpolymer via a combination of consecutive click reactions and atom transfer radical polymerization

Li, C., Ge, Z., Liu, H., & Liu, S. (2009) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23461 · Cited by 66

Successive Synthesis of Well-Defined Asymmetric Star-Branched Polymers up to Seven-Arm, Seven-Component ABCDEFG Type by an Iterative Methodology Based on Living Anionic Polymerization

Hirao, A., Higashihara, T., & Inoue, K. (2008) · Macromolecules · doi:10.1021/ma800146p · Cited by 65

Facile synthesis of AB2‐type miktoarm star polymers through the combination of atom transfer radical polymerization and ring‐opening polymerization

Erdogan, T., Özyürek, Z., Hızal, G., & Tunca, Ü. (2004) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20067 · Cited by 65

One‐pot synthesis of ABC miktoarm star terpolymers by coupling ATRP, ROP, and click chemistry techniques

Zhang, Y., Li, C., & Liu, S. (2009) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23388 · Cited by 65

Dendrimer‐like miktoarm star terpolymers: A3‐(B‐C)3 via click reaction strategy

Altintas, O., Demirel, A. L., Hızal, G., & Tunca, Ü. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22908 · Cited by 63

Block and star block copolymers by mechanism transformation X. Synthesis of poly(ethylene oxide) methyl ether/polystyrene/poly(l-lactide) ABC miktoarm star copolymers by combination of RAFT and ROP

Shi, P., Li, Y., & Pan, C. (2004) · European Polymer Journal · doi:10.1016/j.eurpolymj.2004.02.024 · Cited by 63

Micelles possessing mixed cores and thermoresponsive shells fabricated from well‐defined amphiphilic ABC miktoarm star terpolymers

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Successive Synthesis of Well-Defined Star-Branched Polymers by a New Iterative Approach Involving Coupling and Transformation Reactions

Higashihara, T., Nagura, M., Inoue, K., Haraguchi, N., & Hirao, A. (2005) · Macromolecules · doi:10.1021/ma050248e · Cited by 62

Synthesis of ABCD 4‐miktoarm star polymers by combination of RAFT, ROP, and “Click Chemistry”

Yang, L., Zhou, H., Shi, G., Wang, Y., & Pan, C. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22975 · Cited by 61

H‐shaped (ABCDE type) quintopolymer via click reaction [3 + 2] strategy

Güngör, E., Durmaz, H., Hızal, G., & Tunca, Ü. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22781 · Cited by 59

Preparation of poly(ethylene oxide) star polymers and poly(ethylene oxide)–polystyrene heteroarm star polymers by atom transfer radical polymerization

Du, J., & Chen, Y. (2004) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20061 · Cited by 59

e-Micellization: Electrochemical, Reversible Switching of Polymer Aggregation

Plamper, F. A., Murtomäki, L. S., Walther, A., Kontturi, K., & Tenhu, H. J. (2009) · Macromolecules · doi:10.1021/ma901389d · Cited by 58

Synthesis of Core Cross-Linked Star Polymers with Adjustable Coronal Properties

Wiltshire, J. T., & Qiao, G. G. (2007) · Macromolecules · doi:10.1021/ma071651j · Cited by 52

Dendritic−Linear Miktoarm Star Polymers from Orthogonal Protected Initiators

Glauser, T., Stancik, C. M., Möller, M., Voytek, S. B., Gast, A. P., & Hedrick, J. L. (2002) · Macromolecules · doi:10.1021/ma0122369 · Cited by 50

Self-Assembly and pH-Responsiveness of ABC Miktoarm Star Terpolymers

Butsele, K. V., Fustin, C., Gohy, J., Jérôme, R., & Jérôme, C. (2008) · Langmuir · doi:10.1021/la802469c · Cited by 49

Successive Synthesis of Well-Defined Many Arm Star-Branched Polymers by an Iterative Methodology Using a Specially Designed 1,1-Diphenylethylene

Hirao, A., Higashihara, T., Nagura, M., & Sakurai, T. (2006) · Macromolecules · doi:10.1021/ma061075b · Cited by 49

Controlled synthesis of pH‐responsive amphiphilic A2B2 miktoarm star block copolymer by combination of SET‐LRP and RAFT polymerization

Zhang, W., Zhang, W., Zhu, J., Zhang, Z., & Zhu, X. (2009) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23730 · Cited by 49

Controlled Synthesis of an ABC Miktoarm Star-Shaped Copolymer by Sequential Ring-Opening Polymerization of Ethylene Oxide, Benzyl β-Malolactonate, and ε-Caprolactone

Rieger, J., Coulembier, O., Dúbois, P., Bernaerts, K. V., Prez, F. D., Jérôme, R., & Jérôme, C. (2005) · Macromolecules · doi:10.1021/ma051581l · Cited by 48

Successive Synthesis of Asymmetric Star-Branched Polymers Based on Iterative Methodology Using 1,1-Diphenylethylene Derivatives of Alternative Choice at Each Iteration

Higashihara, T., Sakurai, T., & Hirao, A. (2009) · Macromolecules · doi:10.1021/ma900750n · Cited by 46

Photoresponsive poly(methyl methacrylate)2–(polystyrene)2 miktoarm star copolymer containing an azobenzene moiety at the core

Erdogan, T., Güngör, E., Durmaz, H., Hızal, G., & Tunca, Ü. (2006) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.21253 · Cited by 44

Facile synthesis of star‐shaped copolymers via combination of RAFT and ring opening polymerization

Kakwere, H., & Perrier, S. (2009) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23680 · Cited by 42

Synthesis of Branched Polymers by Means of Living Anionic Polymerization. 13. Synthesis of Well-Defined Star-Branched Polymers via an Iterative Approach Using Living Anionic Polymers

Hirao, A., & Higashihara, T. (2002) · Macromolecules · doi:10.1021/ma0203400 · Cited by 41

Synthesis of ABCD‐type miktoarm star copolymers and transformation into zwitterionic star copolymers

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Synthesis of an ABCD 4-Miktoarm Star Quaterpolymer Through a Diels–Alder Click Reaction

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