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Tropospheric OH and HO2 radicals: field measurements and model comparisons
Abstract
The hydroxyl radical, OH, initiates the removal of the majority of trace gases in the atmosphere, and together with the closely coupled species, the hydroperoxy radical, HO(2), is intimately involved in the oxidation chemistry of the atmosphere. This critical review discusses field measurements of local concentrations of OH and HO(2) radicals in the troposphere, and in particular the comparisons that have been made with numerical model calculations containing a detailed chemical mechanism. The level of agreement between field measurements of OH and HO(2) concentrations and model calculations for a given location provides an indication of the degree of understanding of the underlying oxidation chemistry. We review the measurement-model comparisons for a range of different environments sampled from the ground and from aircraft, including the marine boundary layer, continental low-NO(x) regions influenced by biogenic emissions, the polluted urban boundary layer, and polar regions. Although good agreement is found for some environments, there are significant discrepancies which remain unexplained, a notable example being unpolluted, forested regions. OH and HO(2) radicals are difficult species to measure in the troposphere, and we also review changes in detection methodology, quality assurance procedures such as instrument intercomparisons, and potential interferences.
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Cites
Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P. I., & Geron, C. (2006) · Atmospheric Chemistry and Physics · doi:10.5194/acp-6-3181-2006 · Cited by 4,603
A global model of natural volatile organic compound emissions
Guenther, A., Hewitt, C. N., Erickson, D., Fall, R., Geron, C., Graedel, T., Harley, P., Klinger, L., Lerdau, M., Mckay, W. A., et al. (1995) · Journal of Geophysical Research: Atmospheres · doi:10.1029/94jd02950 · Cited by 4,169
Saunders, S. M., Jenkin, M. E., Derwent, R. G., & Pilling, M. J. (2003) · Atmospheric Chemistry and Physics · doi:10.5194/acp-3-161-2003 · Cited by 1,637
The tropospheric degradation of volatile organic compounds: a protocol for mechanism development
Jenkin, M. E., Saunders, S. M., & Pilling, M. J. (1997) · Atmospheric Environment · doi:10.1016/s1352-2310(96)00105-7 · Cited by 1,224
A new mechanism for regional atmospheric chemistry modeling
Stockwell, W. R., Kirchner, F., Kuhn, M., & Seefeld, S. (1997) · Journal of Geophysical Research: Atmospheres · doi:10.1029/97jd00849 · Cited by 1,098
Atmospheric oxidation capacity sustained by a tropical forest
Lelieveld, J., Butler, T. M., Crowley, J. N., Dillon, T. J., Fischer, H., Ganzeveld, L., Harder, H., Lawrence, M. G., Martinez, M., Taraborrelli, D., et al. (2008) · Nature · doi:10.1038/nature06870 · Cited by 903
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene
Paulot, F., Crounse, J. D., Kjaergaard, H. G., Kürten, A., St. Clair, J. M., Seinfeld, J. H., & Wennberg, P. O. (2009) · Science · doi:10.1126/science.1172910 · Cited by 903
Atmospheric composition change – global and regional air quality
Monks, P. S., Granier, C., Fuzzi, S., Stohl, A., Williams, M. L., Akimoto, H., Amann, M., Baklanov, A., Baltensperger, U., Bey, I., et al. (2009) · Atmospheric Environment · doi:10.1016/j.atmosenv.2009.08.021 · Cited by 872
Jenkin, M. E., Saunders, S. M., Wagner, V., & Pilling, M. J. (2003) · Atmospheric Chemistry and Physics · doi:10.5194/acp-3-181-2003 · Cited by 841
Direct Kinetic Measurements of Criegee Intermediate (CH 2 OO) Formed by Reaction of CH 2 I with O 2
Welz, O., Savee, J. D., Osborn, D. L., Vasu, S. S., Percival, C. J., Shallcross, D. E., & Taatjes, C. A. (2012) · Science · doi:10.1126/science.1213229 · Cited by 707
Amplified Trace Gas Removal in the Troposphere
Hofzumahaus, A., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C.-C., Fuchs, H., Holland, F., Kita, K., Kondo, Y., et al. (2009) · Science · doi:10.1126/science.1164566 · Cited by 667
A large atomic chlorine source inferred from mid-continental reactive nitrogen chemistry
Thornton, J. A., Kercher, J. P., Riedel, T. P., Wagner, N. L., Cozic, J., Holloway, J. S., Dubé, W. P., Wolfe, G. M., Quinn, P. K., Middlebrook, A. M., et al. (2010) · Nature · doi:10.1038/nature08905 · Cited by 652
An overview of snow photochemistry: evidence, mechanisms and impacts
Grannas, A. M., Jones, A. E., Dibb, J., Ammann, M., Anastasio, C., Beine, H. J., Bergin, M., Bottenheim, J., Boxe, C. S., Carver, G., et al. (2007) · Atmospheric Chemistry and Physics · doi:10.5194/acp-7-4329-2007 · Cited by 621
Self-citationGas-phase radical chemistry in the troposphere
Monks, P. S. (2005) · Chemical Society Reviews · doi:10.1039/b307982c · Cited by 577
Bloss, C., Wagner, V., Jenkin, M. E., Volkamer, R., Bloss, W. J., Lee, J. D., Heard, D. E., Wirtz, K., Martin-Reviejo, M., Rea, G., et al. (2005) · Atmospheric Chemistry and Physics · doi:10.5194/acp-5-641-2005 · Cited by 530
Self-citationMissing OH Reactivity in a Forest: Evidence for Unknown Reactive Biogenic VOCs
Di Carlo, P., Brune, W. H., Martinez, M., Harder, H., Lesher, R., Ren, X., Thornberry, T., Carroll, M. A., Young, V., Shepson, P. B., et al. (2004) · Science · doi:10.1126/science.1094392 · Cited by 481
HOx radical regeneration in the oxidation of isoprene
Peeters, J., Nguyen, T. L., & Vereecken, L. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b908511d · Cited by 440
Extensive halogen-mediated ozone destruction over the tropical Atlantic Ocean
Read, K. A., Mahajan, A. S., Carpenter, L. J., Evans, M. J., Faria, B. V. E., Heard, D. E., Hopkins, J. R., Lee, J. D., Moller, S. J., Lewis, A. C., et al. (2008) · Nature · doi:10.1038/nature07035 · Cited by 434
Self-citationMeasurement of OH and HO2 in the Troposphere
Heard, D. E., & Pilling, M. J. (2003) · Chemical Reviews · doi:10.1021/cr020522s · Cited by 424
Self-citationStrong correlation between levels of tropospheric hydroxyl radicals and solar ultraviolet radiation
Rohrer, F., & Berresheim, H. (2006) · Nature · doi:10.1038/nature04924 · Cited by 390
OH formation by HONO photolysis during the BERLIOZ experiment
Alicke, B., Geyer, A., Hofzumahaus, A., Holland, F., Konrad, S., Pätz, H. ‐., Schäfer, J., Stutz, J., Volz‐Thomas, A., & Platt, U. (2003) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd000579 · Cited by 376
Molina, L. T., Madronich, S., Gaffney, J. S., Apel, E., de Foy, B., Fast, J., Ferrare, R., Herndon, S., Jimenez, J. L., Lamb, B., et al. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-8697-2010 · Cited by 375
Lu, K. D., Rohrer, F., Holland, F., Fuchs, H., Bohn, B., Brauers, T., Chang, C. C., Häseler, R., Hu, M., Kita, K., et al. (2012) · Atmospheric Chemistry and Physics · doi:10.5194/acp-12-1541-2012 · Cited by 364
A larger pool of ozone-forming carbon compounds in urban atmospheres
Lewis, A. C., Carslaw, N., Marriott, P. J., Kinghorn, R. M., Morrison, P., Lee, A. L., Bartle, K. D., & Pilling, M. J. (2000) · Nature · doi:10.1038/35015540 · Cited by 362
Photooxidation of dimethyl sulfide and dimethyl disulfide. I: Mechanism development
Yin, F., Grosjean, D., & Seinfeld, J. H. (1990) · Journal of Atmospheric Chemistry · doi:10.1007/bf00053780 · Cited by 347
Peroxy radical isomerization in the oxidation of isoprene
Crounse, J. D., Paulot, F., Kjaergaard, H. G., & Wennberg, P. O. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp21330j · Cited by 327
Iodine oxide in the marine boundary layer
Alicke, B., Hebestreit, K., Stutz, J., & Platt, U. (1999) · Nature · doi:10.1038/17508 · Cited by 319
OH and HO2 Chemistry in the urban atmosphere of New York City
Ren, X. (2003) · Atmospheric Environment · doi:10.1016/s1352-2310(03)00459-x · Cited by 319
Snowpack production of formaldehyde and its effect on the Arctic troposphere
Sumner, A. L., & Shepson, P. B. (1999) · Nature · doi:10.1038/18423 · Cited by 297
Boundary Layer Halogens in Coastal Antarctica
Saiz-Lopez, A., Mahajan, A. S., Salmon, R. A., Bauguitte, S. J.-B., Jones, A. E., Roscoe, H. K., & Plane, J. M. C. (2007) · Science · doi:10.1126/science.1141408 · Cited by 292
Lou, S., Holland, F., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C. C., Fuchs, H., Häseler, R., Kita, K., et al. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-11243-2010 · Cited by 287
Atmospheric Hydroxyl Radical Production from Electronically Excited NO 2 and H 2 O
Li, S., Matthews, J., & Sinha, A. (2008) · Science · doi:10.1126/science.1151443 · Cited by 277
Impacts of HONO sources on the photochemistry in Mexico City during the MCMA-2006/MILAGO Campaign
Li, G., Lei, W., Zavala, M., Volkamer, R., Dusanter, S., Stevens, P., & Molina, L. T. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-6551-2010 · Cited by 263
Impact of natural hydrocarbons on hydroxyl and peroxy radicals at a remote site
Trainer, M., Hsie, E. ‐., McKeen, S. A., Tallamraju, R. K. M. R., Parrish, D. D., Fehsenfeld, F. C., & Liu, S. C. (1987) · Journal of Geophysical Research Atmospheres · doi:10.1029/jd092id10p11879 · Cited by 248
Birmili, W., Berresheim, H., Plass-Dülmer, C., Elste, T., Gilge, S., Wiedensohler, A., & Uhrner, U. (2003) · Atmospheric Chemistry and Physics · doi:10.5194/acp-3-361-2003 · Cited by 247
Thornton, J. A., Wooldridge, P. J., Cohen, R. C., Martinez, M., Harder, H., Brune, W. H., Williams, E. J., Roberts, J. M., Fehsenfeld, F. C., Hall, S. R., et al. (2002) · Journal of Geophysical Research: Atmospheres · doi:10.1029/2001jd000932 · Cited by 235
Insights into hydroxyl measurements and atmospheric oxidation in a California forest
Mao, J., Ren, X., Zhang, L., Van Duin, D. M., Cohen, R. C., Park, J.-H., Goldstein, A. H., Paulot, F., Beaver, M. R., Crounse, J. D., et al. (2012) · Atmospheric Chemistry and Physics · doi:10.5194/acp-12-8009-2012 · Cited by 233
Vertical fluxes of NO , HONO, and HNO3 above the snowpack at Summit, Greenland
Honrath, R. E., Lu, Y., Peterson, M. C., Dibb, J. E., Arsenault, M. A., Cullen, N. J., & Steffen, K. (2002) · Atmospheric Environment · doi:10.1016/s1352-2310(02)00132-2 · Cited by 231
Chemistry of hydrogen oxide radicals (HO x ) in the Arctic troposphere in spring
Mao, J., Jacob, D. J., Evans, M. J., Olson, J. R., Ren, X., Brune, W. H., Clair, J. M. S., Crounse, J. D., Spencer, K. M., Beaver, M. R., et al. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-5823-2010 · Cited by 229
Berresheim, H., Elste, T., Tremmel, H. G., Allen, A. G., Hansson, H., Rosman, K., Maso, M. D., Mäkelä, J. M., Kulmala, M., & O'Dowd, C. D. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2000jd000229 · Cited by 227
Faloona, I. C., Tan, D., Lesher, R. L., Hazen, N. L., Frame, C. L., Simpas, J. B., Harder, H., Martinez, M., Di Carlo, P., Ren, X., et al. (2004) · Journal of Atmospheric Chemistry · doi:10.1023/b:joch.0000021036.53185.0e · Cited by 226
Chemistry of HOx radicals in the upper troposphere
Jaeglé, L. (2001) · Atmospheric Environment · doi:10.1016/s1352-2310(00)00376-9 · Cited by 217
Quantifying the magnitude of a missing hydroxyl radical source in a tropical rainforest
Whalley, L. K., Edwards, P. M., Furneaux, K. L., Goddard, A., Ingham, T., Evans, M. J., Stone, D., Hopkins, J. R., Jones, C. E., Karunaharan, A., et al. (2011) · Atmospheric Chemistry and Physics · doi:10.5194/acp-11-7223-2011 · Cited by 209
Self-citationOn the role of hydroxyl radicals in the self-cleansing capacity of the troposphere
Lelieveld, J., Dentener, F. J., Peters, W., & Krol, M. C. (2004) · Atmospheric Chemistry and Physics · doi:10.5194/acp-4-2337-2004 · Cited by 207
Oxidative capacity of the Mexico City atmosphere – Part 1: A radical source perspective
Volkamer, R., Sheehy, P., Molina, L. T., & Molina, M. J. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-6969-2010 · Cited by 202
Detection of HO 2 by laser-induced fluorescence: calibration and interferences from RO 2 radicals
Fuchs, H., Bohn, B., Hofzumahaus, A., Holland, F., Lu, K. D., Nehr, S., Rohrer, F., & Wahner, A. (2011) · Atmospheric Measurement Techniques · doi:10.5194/amt-4-1209-2011 · Cited by 194
Photochemistry of HOx in the upper troposphere at northern midlatitudes
Jaeglé, L., Jacob, D. J., Brune, W. H., Faloona, I., Tan, D., Heikes, B. G., Kondo, Y., Sachse, G. W., Anderson, B., Gregory, G. L., et al. (2000) · Journal of Geophysical Research: Atmospheres · doi:10.1029/1999jd901016 · Cited by 193
Singh, H. B., Brune, W. H., Crawford, J. H., Flocke, F., & Jacob, D. J. (2009) · Atmospheric Chemistry and Physics · doi:10.5194/acp-9-2301-2009 · Cited by 192
Hasson, A. S., Tyndall, G. S., & Orlando, J. J. (2004) · The Journal of Physical Chemistry A · doi:10.1021/jp048873t · Cited by 191
Martínez, M., Harder, H., Kovacs, T. A., Simpas, J. B., Bassis, J. N., Lesher, R. L., Brune, W. H., Frost, G. J., Williams, E. J., Stroud, C., et al. (2003) · Journal of Geophysical Research Atmospheres · doi:10.1029/2003jd003551 · Cited by 190
HOx concentrations and OH reactivity observations in New York City during PMTACS-NY2001
Ren, X. (2003) · Atmospheric Environment · doi:10.1016/s1352-2310(03)00460-6 · Cited by 187
Peeters, J., & Müller, J.-F. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/c0cp00811g · Cited by 184
Hydroxyl radical buffered by isoprene oxidation over tropical forests
Taraborrelli, D., Lawrence, M. G., Crowley, J. N., Dillon, T. J., Gromov, S., Groß, C. B. M., Vereecken, L., & Lelieveld, J. (2012) · Nature Geoscience · doi:10.1038/ngeo1405 · Cited by 177
Dillon, T. J., & Crowley, J. N. (2008) · Atmospheric Chemistry and Physics · doi:10.5194/acp-8-4877-2008 · Cited by 174
Observations of iodine monoxide in the remote marine boundary layer
Allan, B. J., McFiggans, G., Plane, J. M. C., & Coe, H. (2000) · Journal of Geophysical Research: Atmospheres · doi:10.1029/1999jd901188 · Cited by 172
Measuring atmospheric composition change
Laj, P., Klausen, J., Bilde, M., Plaß-Duelmer, C., Pappalardo, G., Clerbaux, C., Baltensperger, U., Hjorth, J., Simpson, D., Reimann, S., et al. (2009) · Atmospheric Environment · doi:10.1016/j.atmosenv.2009.08.020 · Cited by 169
Measurement and modelling of tropospheric reactive halogen species over the tropical Atlantic Ocean
Mahajan, A. S., Plane, J. M. C., Oetjen, H., Mendes, L., Saunders, R. W., Saiz-Lopez, A., Jones, C. E., Carpenter, L. J., & McFiggans, G. B. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-4611-2010 · Cited by 166
Ren, X., Olson, J. R., Crawford, J. H., Brune, W. H., Mao, J., Long, R. B., Chen, Z., Chen, G., Avery, M. A., Sachse, G. W., et al. (2008) · Journal of Geophysical Research: Atmospheres · doi:10.1029/2007jd009166 · Cited by 161
Comparison of tropospheric gas-phase chemistry schemes for use within global models
Emmerson, K. M., & Evans, M. J. (2009) · Atmospheric Chemistry and Physics · doi:10.5194/acp-9-1831-2009 · Cited by 159
Ozone photochemistry and elevated isoprene during the UK heatwave of august 2003
Lee, J. D., Lewis, A. C., Monks, P. S., JACOB, M., Hamilton, J. F., Hopkins, J. R., Watson, N., Saxton, J. E., Ennis, C. J., & Carpenter, L. J. (2006) · Atmospheric Environment · doi:10.1016/j.atmosenv.2006.06.057 · Cited by 146
Investigation of the radical product channel of the CH3C(O)O2 + HO2 reaction in the gas phase
Jenkin, M. E., Hurley, M. D., & Wallington, T. J. (2007) · Physical Chemistry Chemical Physics · doi:10.1039/b702757e · Cited by 142
Erratum: Hydroxyl radical buffered by isoprene oxidation over tropical forests
Taraborrelli, D., Lawrence, M. G., Crowley, J. N., et al. (2012) · Nature Geoscience · doi:10.1038/ngeo1433 · Cited by 140
Peroxy radicals during BERLIOZ at Pabstthum: Measurements, radical budgets and ozone production
Mihelcic, D., Holland, F., Hofzumahaus, A., et al. (2003) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd001014 · Cited by 140
McKeen, S. A., Mount, G. H., Eisele, F. L., Williams, E. J., Harder, J. W., Goldan, P. D., Kuster, W. C., Liu, S. C., Baumann, K., Tanner, D. J., et al. (1997) · Journal of Geophysical Research Atmospheres · doi:10.1029/96jd03322 · Cited by 139
Simultaneous measurements of peroxy and nitrate radicals at Schauinsland
Mihelcic, D., Klemp, D., M�sgen, P., P�tz, H. W., & Volz‐Thomas, A. (1993) · Journal of Atmospheric Chemistry · doi:10.1007/bf01032628 · Cited by 139
Carpenter, L. J., Fleming, Z. L., Read, K., Lee, J. D., Moller, S. J., Hopkins, J. R., Purvis, R. M., Lewis, A. C., Müller, K., Heinold, B., et al. (2010) · Journal of Atmospheric Chemistry · doi:10.1007/s10874-011-9206-1 · Cited by 136
Self-citationFaloona, I. C., Tan, D., Brune, W. H., Hurst, J. M., Barket, D. J., Couch, T. L., Shepson, P. B., Apel, E. C., Riemer, D. D., Thornberry, T., et al. (2001) · Journal of Geophysical Research Atmospheres · doi:10.1029/2000jd900691 · Cited by 135
Harrison, R. M., Yin, J., Tilling, R. M., Cai, X. M., Seakins, P. W., Hopkins, J. R., Lansley, D. L., Lewis, A. C., Hunter, M. C., Heard, D. E., et al. (2005) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2005.08.053 · Cited by 133
Self-citationHigh levels of the hydroxyl radical in the winter urban troposphere
Heard, D. E., Carpenter, L. J., Creasey, D. J., Hopkins, J. R., Lee, J. D., Lewis, A. C., Pilling, M. J., Seakins, P. W., Carslaw, N., & Emmerson, K. M. (2004) · Geophysical Research Letters · doi:10.1029/2004gl020544 · Cited by 133
Self-citationObservations of hydroxyl and the sum of peroxy radicals at Summit, Greenland during summer 2003
Sjostedt, S. J., Huey, L. G., Tanner, D. J., et al. (2006) · Atmospheric Environment · doi:10.1016/j.atmosenv.2006.06.065 · Cited by 131
Crawford, J. H., Davis, D. D., Olson, J. R., Chen, G., Liu, S., Gregory, G., Barrick, J. D. W., Sachse, G. W., Sandholm, S. T., Heikes, B. G., et al. (1999) · Journal of Geophysical Research Atmospheres · doi:10.1029/1999jd900106 · Cited by 131
Dusanter, S., Vimal, D., Stevens, P. S., Volkamer, R., Molina, L. T., Baker, A. K., Meinardi, S., Blake, D. R., Sheehy, P. M., Merten, A., et al. (2009) · Atmospheric chemistry and physics · doi:10.5194/acp-9-6655-2009 · Cited by 130
Butler, T. M., Taraborrelli, D., Brühl, C., Fischer, H., Harder, H., Martínez, M., Williams, J., Lawrence, M. G., & Lelieveld, J. (2008) · Atmospheric chemistry and physics · doi:10.5194/acp-8-4529-2008 · Cited by 130
Rapid formation of isoprene photo-oxidation products observed in Amazonia
Karl, T., Guenther, A., Turnipseed, A. A., Tyndall, G. S., Artaxo, P. E., & Martin, S. T. (2009) · Atmospheric chemistry and physics · doi:10.5194/acp-9-7753-2009 · Cited by 129
OH Reactivity Measurements within a Boreal Forest: Evidence for Unknown Reactive Emissions
Sinha, V., Williams, J., Lelieveld, J., Ruuskanen, T. M., Kajos, M. K., Patokoski, J., Hellén, H., Hakola, H., Mogensen, D., Boy, M. H., et al. (2010) · Environmental Science & Technology · doi:10.1021/es101780b · Cited by 126
Clemitshaw, K. C. (2004) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643380490265117 · Cited by 123
Dusanter, S., Vimal, D., Stevens, P. S., Volkamer, R., & Molina, L. T. (2009) · Atmospheric chemistry and physics · doi:10.5194/acp-9-1665-2009 · Cited by 123
Sources of HO x and production of ozone in the upper troposphere over the United States
Jaeglé, L., Jacob, D. J., Brune, W. H., Tan, D., Faloona, I. C., Weinheimer, A. J., Ridley, B. A., Campos, T. L., & Sachse, G. W. (1998) · Geophysical Research Letters · doi:10.1029/98gl00041 · Cited by 121
Impacts of mechanistic changes on HO x formation and recycling in the oxidation of isoprene
Archibald, A. T., Cooke, M. C., Utembe, S. R., Shallcross, D. E., Derwent, R. G., & Jenkin, M. E. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-8097-2010 · Cited by 120
Hydroxyl radicals in the tropical troposphere over the Suriname rainforest: airborne measurements
Martínez, M., Harder, H., Kubistin, D., Rudolf, M., Bozem, H., Eerdekens, G., Fischer, H., Klüpfel, T., Gurk, C., Königstedt, R., et al. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-3759-2010 · Cited by 119
Vrekoussis, M., Kanakidou, M., Mihalopoulos, N., Crutzen, P. J., Lelieveld, J., Perner, D., Berresheim, H., & Baboukas, E. (2004) · Atmospheric chemistry and physics · doi:10.5194/acp-4-169-2004 · Cited by 117
Pugh, T. A. M., MacKenzie, A. R., HEWITT, C. N., Langford, B., Edwards, P. M., Furneaux, K. L., Heard, D. E., Hopkins, J. R., Jones, C. E., Karunaharan, A., et al. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-279-2010 · Cited by 115
Self-citationA broadband cavity ringdown spectrometer for in-situ measurements of atmospheric trace gases
Bitter, M., Ball, S. M., Povey, I. M., & Jones, R. L. (2005) · Atmospheric chemistry and physics · doi:10.5194/acp-5-2547-2005 · Cited by 112
Measurements and modelling of I 2 , IO, OIO, BrO and NO 3 in the mid-latitude marine boundary layer
Saiz‐Lopez, A., Shillito, J. A., Coe, H., & Plane, J. M. C. (2006) · Atmospheric chemistry and physics · doi:10.5194/acp-6-1513-2006 · Cited by 112
Thornton, J. A., Jaeglé, L., & McNeill, V. F. (2008) · Journal of Geophysical Research Atmospheres · doi:10.1029/2007jd009236 · Cited by 111
HEWITT, C. N., Lee, J. D., MacKenzie, A. R., Barkley, M. P., Carslaw, N., Carver, G., Chappell, N. A., Coe, H., Collier, C., Commane, R., et al. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-169-2010 · Cited by 108
Self-citationKubistin, D., Harder, H., Martínez, M., Rudolf, M., Sander, R., Bozem, H., Eerdekens, G., Fischer, H., Gurk, C., Klüpfel, T., et al. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-9705-2010 · Cited by 106
Brune, W. H., Faloona, I. C., Tan, D., Weinheimer, A. J., Campos, T. L., Ridley, B. A., Vay, S. A., Collins, J. E., Sachse, G. W., Jaeglé, L., et al. (1998) · Geophysical Research Letters · doi:10.1029/97gl03098 · Cited by 101
Concentrations of OH and HO 2 radicals during NAMBLEX: measurements and steady state analysis
Smith, S. C., Lee, J. D., Bloss, W. J., Johnson, G. P., Ingham, T., & Heard, D. E. (2006) · Atmospheric chemistry and physics · doi:10.5194/acp-6-1435-2006 · Cited by 99
Self-citationStavrakou, T., Peeters, J., & Müller, J. ‐. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-9863-2010 · Cited by 98
Swanson, A. L., Blake, N. J., Dibb, J. E., Albert, M. R., Blake, D. R., & Rowland, F. S. (2002) · Atmospheric Environment · doi:10.1016/s1352-2310(02)00127-9 · Cited by 93
Salisbury, G., Rickard, A. R., Monks, P. S., Allan, B. J., Bauguitte, S. J.-B., Penkett, S. A., Carslaw, N., Lewis, A. C., Creasey, D. J., Heard, D. E., et al. (2001) · Journal of Geophysical Research Atmospheres · doi:10.1029/2000jd900754 · Cited by 92
Self-citationWater Dependence of the HO2 Self Reaction: Kinetics of the HO2−H2O Complex
Kanno, N., Tonokura, K., Tezaki, A., & Koshi, M. (2005) · The Journal of Physical Chemistry A · doi:10.1021/jp044592+ · Cited by 92
OH and HO 2 chemistry in clean marine air during SOAPEX-2
Sommariva, R., Haggerstone, A. ‐., Carpenter, L. J., Carslaw, N., Creasey, D. J., Heard, D. E., Lee, J. D., Lewis, A. C., Pilling, M. J., & Zádor, J. (2004) · Atmospheric chemistry and physics · doi:10.5194/acp-4-839-2004 · Cited by 91
Self-citationWilliams, J., Crowley, J. N., Fischer, H., Harder, H., Martínez, M., Petäjä, T., Rinne, J., Bäck, J. K., Boy, M. H., Maso, M. D., et al. (2011) · Atmospheric chemistry and physics · doi:10.5194/acp-11-10599-2011 · Cited by 91
Siese, M., Becker, K. H., Brockmann, K. J., Geiger, H., Hofzumahaus, A., Holland, F., Mihelcic, D., & Wirtz, K. (2001) · Environmental Science & Technology · doi:10.1021/es010150p · Cited by 87
Fuchs, H., Dorn, H., Bachner, M., Bohn, B., Brauers, T., Gomm, S., Hofzumahaus, A., Holland, F., Nehr, S., Röhrer, F., et al. (2012) · Atmospheric measurement techniques · doi:10.5194/amt-5-1611-2012 · Cited by 86
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Platt, U., Alicke, B., Dubois, R., Geyer, A., Hofzumahaus, A., Holland, F., Martínez, M., Mihelcic, D., Klüpfel, T., Lohrmann, B., et al. (2002) · Springer eBooks · doi:10.1007/978-94-010-0399-5_15 · Cited by 85
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Arnold, S. R., Chipperfield, M. P., & Blitz, M. A. (2005) · Journal of Geophysical Research Atmospheres · doi:10.1029/2005jd005998 · Cited by 85
Beygi, Z. H., Fischer, H., Harder, H., Martínez, M., Sander, R., Williams, J., Brookes, D. M., Monks, P. S., & Lelieveld, J. (2011) · Atmospheric chemistry and physics · doi:10.5194/acp-11-8497-2011 · Cited by 83
Blitz, M. A., Heard, D. E., Pilling, M. J., Arnold, S. R., & Chipperfield, M. P. (2004) · Geophysical Research Letters · doi:10.1029/2003gl018793 · Cited by 83
Self-citationSchlosser, E., Brauers, T., Dorn, H., Fuchs, H., Häseler, R., Hofzumahaus, A., Holland, F., Wahner, A., Kanaya, Y., Kajii, Y., et al. (2009) · Atmospheric chemistry and physics · doi:10.5194/acp-9-7923-2009 · Cited by 83
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A calibrated peroxy radical chemical amplifier for ground‐based tropospheric measurements
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Kim, S., Guenther, A., Karl, T., & Greenberg, J. (2011) · Atmospheric chemistry and physics · doi:10.5194/acp-11-8613-2011 · Cited by 80
Butkovskaya, N. I., Kukui, A., & Bras, G. L. (2007) · The Journal of Physical Chemistry A · doi:10.1021/jp074117m · Cited by 79
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Physically based modeling of atmosphere‐to‐snow‐to‐firn transfer of H2O2 at South Pole
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Water Vapor Effect on the HNO3 Yield in the HO2 + NO Reaction: Experimental and Theoretical Evidence
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Heterogeneous loss of HO2 by KCl, synthetic sea salt, and natural seawater aerosol particles
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Brauers, T., Hausmann, M., Bister, A., Kraus, A., & Dorn, H. (2001) · Journal of Geophysical Research Atmospheres · doi:10.1029/2000jd900679 · Cited by 70
Seasonal observations of OH and HO 2 in the remote tropical marine boundary layer
Vaughan, S., Ingham, T., Whalley, L. K., Stone, D., Evans, M. J., Read, K., Lee, J. D., Moller, S. J., Carpenter, L. J., Lewis, A. C., et al. (2012) · Atmospheric chemistry and physics · doi:10.5194/acp-12-2149-2012 · Cited by 68
Self-citationOH and HO2 in the tropical Pacific: Results from PEM‐Tropics B
Tan, D., Faloona, I. C., Simpas, J. B., Brune, W. H., Olson, J. R., Crawford, J. H., Avery, M. A., Sachse, G. W., Vay, S., Sandholm, S. T., et al. (2001) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd900002 · Cited by 68
Formation of Nitric Acid in the Gas-Phase HO2 + NO Reaction: Effects of Temperature and Water Vapor
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Kanno, N., Tonokura, K., & Koshi, M. (2006) · Journal of Geophysical Research Atmospheres · doi:10.1029/2005jd006805 · Cited by 66
Night-time radical chemistry during the TORCH campaign
Emmerson, K. M., & Carslaw, N. (2009) · Atmospheric Environment · doi:10.1016/j.atmosenv.2009.03.042 · Cited by 66
Design of and initial results from a Highly Instrumented Reactor for Atmospheric Chemistry (HIRAC)
Glowacki, D. R., Goddard, A., Hemavibool, K., Malkin, T. L., Commane, R., Anderson, F. E., Bloss, W. J., Heard, D. E., Ingham, T., Pilling, M. J., et al. (2007) · Atmospheric chemistry and physics · doi:10.5194/acp-7-5371-2007 · Cited by 66
Self-citationA reevaluation of airborne HOx observations from NASA field campaigns
Olson, J. R., Crawford, J. H., Chen, G., Brune, W. H., Faloona, I. C., Tan, D., Harder, H., & Martínez, M. (2006) · Journal of Geophysical Research Atmospheres · doi:10.1029/2005jd006617 · Cited by 64
The importance of weak absorption features in promoting tropospheric radical production
Matthews, J., Sinha, A., & Francisco, J. S. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0502687102 · Cited by 63
HO x observations over West Africa during AMMA: impact of isoprene and NO x
Stone, D., Evans, M. J., Commane, R., Ingham, T., Floquet, C. F. A., McQuaid, J. B., Brookes, D. M., Monks, P. S., Purvis, R. M., Hamilton, J. F., et al. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-9415-2010 · Cited by 60
Self-citationCoupling of HO x , NO x and halogen chemistry in the antarctic boundary layer
Bloss, W. J., Camredon, M., Lee, J. D., Heard, D. E., Plane, J. M. C., Saiz‐Lopez, A., Bauguitte, S. J.-B., Salmon, R. A., & Jones, A. E. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-10187-2010 · Cited by 58
Self-citationATMOSPHERIC FIELD MEASUREMENTS OF THE HYDROXYL RADICAL USING LASER-INDUCED FLUORESCENCE SPECTROSCOPY
Heard, D. E. (2005) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.57.032905.104516 · Cited by 53
Self-citationParameterisation and impact of aerosol uptake of HO 2 on a global tropospheric model
Macintyre, H. L., & Evans, M. J. (2011) · Atmospheric chemistry and physics · doi:10.5194/acp-11-10965-2011 · Cited by 51
Implications of iodine chemistry for daytime HO 2 levels at Rishiri Island
Kanaya, Y., Yokouchi, Y., Matsumoto, J., Nakamura, K., Kato, S., Tanimoto, H., Furutani, H., Toyota, K., & Akimoto, H. (2002) · Geophysical Research Letters · doi:10.1029/2001gl014061 · Cited by 49
Ravetta, F., Jacob, D. J., Brune, W. H., Heikes, B. G., Anderson, B. E., Blake, D. R., Gregory, G. L., Sachse, G. W., Sandholm, S. T., Shetter, R. E., et al. (2001) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd900009 · Cited by 47
Vaughan, S., Canosa‐Mas, C. E., Pfrang, C., Shallcross, D. E., Watson, L., & Wayne, R. P. (2006) · Physical Chemistry Chemical Physics · doi:10.1039/b605569a · Cited by 47
Photodissociation of acetone: Atmospheric implications of temperature‐dependent quantum yields
Arnold, S. R., Chipperfield, M. P., Blitz, M. A., et al. (2004) · Geophysical Research Letters · doi:10.1029/2003gl019099 · Cited by 44
Pugh, T. A. M., MacKenzie, A. R., Langford, B., et al. (2011) · Atmospheric chemistry and physics · doi:10.5194/acp-11-4121-2011 · Cited by 40
Sillman, S., Carroll, M. A., Thornberry, T., Lamb, B., Westberg, H. H., Brune, W. H., Faloona, I. C., Tan, D., Shepson, P. B., Sumner, A. L., et al. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd000449 · Cited by 37
Olson, J. R., Crawford, J. H., Brune, W. H., Mao, J., Ren, X., Fried, A., Anderson, B. E., Apel, E. C., Beaver, M. R., Blake, D. R., et al. (2012) · Atmospheric chemistry and physics · doi:10.5194/acp-12-6799-2012 · Cited by 35
Cariolle, D., Evans, M. J., Chipperfield, M. P., Butkovskaya, N. I., Kukui, A., & Bras, G. L. (2008) · Atmospheric chemistry and physics · doi:10.5194/acp-8-4061-2008 · Cited by 35
Michou, M., Saint‐Martin, D., Teyssèdre, H., et al. (2011) · Geoscientific model development · doi:10.5194/gmd-4-873-2011 · Cited by 33
Marine latitude/altitude OH distributions: Comparison of Pacific Ocean observations with models
Davis, D. D., Grodzinsky, G., Chen, G., Crawford, J. H., Eisele, F. L., Mauldin, L. E., III, Tanner, D. J., Cantrell, C. A., Brune, W. H., Tan, D., et al. (2001) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd900141 · Cited by 26
Night-time radical chemistry during the NAMBLEX campaign
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Metadata
- Authors
- Stone, D., Whalley, L. K., & Heard, D. E.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 41
- Issue
- 19
- Pages
- 6348
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W1980182854
- Cited by
- 599
- References
- 145
- FWCI
- 2.57
- Type
- journal article
- Language
- en
- Open access
- closed
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
