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CO2-triggered switchable solvents, surfactants, and other materials
Abstract
Waste CO2 at atmospheric pressure can be used to trigger dramatic changes in the properties of certain switchable materials. Compared to other triggers such as light, acids and oxidants, CO2 has the advantages that it is inexpensive, nonhazardous, non-accumulating in the system, easily removed, and it does not require the material to be transparent. Known CO2-triggered switchable materials now include solvents, surfactants, solutes, catalysts, particles, polymers, and gels. These have also been described as “smart” materials or, for some of the switchable solvents, “reversible ionic liquids”. The added flexibility of switchable materials represents a new strategy for minimizing energy and material consumption in process and product design.
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Cited by
Green and sustainable solvents in chemical processes
Clarke, C. J., Tu, W.-C., Levers, O., Bröhl, A., & Hallett, J. P. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00571 · Cited by 2,071
Phase change solvents for post-combustion CO2 capture: Principle, advances, and challenges
Zhang, S., Shen, Y., Wang, L., Chen, J., & Lu, Y. (2019) · Applied Energy · doi:10.1016/j.apenergy.2019.01.242 · Cited by 404
Alternative and efficient extraction methods for marine-derived compounds
Grosso, C., Valentão, P., Ferreres, F., & Andrade, P. (2015) · Marine Drugs · doi:10.3390/md13053182 · Cited by 248
Microalgae as Sources of Omega-3 Polyunsaturated Fatty Acids: Biotechnological Aspects
Barta, D. G., Coman, V., & Vodnar, D. C. (2021) · Algal Research · doi:10.1016/j.algal.2021.102410 · Cited by 178
Responsive switchable deep eutectic solvents: A review
Zhang, J., Li, S., Yao, L., Yi, Y., Shen, L., Li, Z., & Qiu, H. (2023) · Chinese Chemical Letters · doi:10.1016/j.cclet.2022.107750 · Cited by 126
Metadata
- Authors
- Jessop, P. G., Mercer, S. M., & Heldebrant, D. J.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 6
- Pages
- 7240
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2163482182
- Cited by
- 518
- References
- 0
- FWCI
- 12.84
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jessop, P. G., Mercer, S. M., & Heldebrant, D. J. (2012). CO2-triggered switchable solvents, surfactants, and other materials. Energy & Environmental Science. https://doi.org/10.1039/c2ee02912j
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
