Random introduction of degradable linkages into functional vinyl polymers by radical ring-opening polymerization, tailored for soft tissue engineering
Abstract
Vinyl polymers, e.g. polyvinyl acetate and polyvinyl alcohol, have properties which suit tissue engineering in many perspectives. A copolymer of 2-methylene-1,3-dioxepane (MDO) with vinyl acetate (VAc) should combine the desirable properties of vinyl polymers with the degradability of aliphatic polyesters. Our results and detailed kinetics information show that it is possible to vary the amount of MDO widely in the copolymer. Between 1 and 70% MDO was incorporated into the polymer when copolymerized with VAc at 60 °C using 2,2-azobisisobutyronitrile (AIBN) as an initiator. The amount of MDO in the copolymer was strictly controlled by the feed ratio, the copolymerization resulted in a high conversion, and the copolymers had high number average molar masses. The polymerization kinetics indicated that the ester units were added in a randomized manner to the vinyl backbone. This was a crucial point since the distribution of degradable bonds provides the opportunity to design the degradation profile of the polymer. The reactivity ratios for MDO and VAc were determined to be rMDO = 0.93 and rVAc = 1.71. The glass transition temperature and the number average molar masses increased with increasing amount of VAc in the feed. We confirmed that the copolymer degraded rapidly in alkali hydrolysis and less in enzymatic hydrolysis and it was apparent that it is possible to synthesize various degradable materials based on VAc and MDO with predetermined polymer compositions and high number average molar masses.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Increasing interest in biodegradable polyesters and the versatility of RROP with respect to structures accessible via different monomers and their copolymerization with conventional vinyl monomers has changed the situation significantly.
“However, with the increasing interest in biodegradable polyesters and the versatility of RROP with respect to the structures accessible via very different monomers [25] and their copolymerization with conventional vinyl monomers [26 -34] has changed the situation significantly.”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [33]
Cites
Synthesis of polycaprolactone: A review
Labet, M., & Thielemans, W. (2009) · Chemical Society Reviews · doi:10.1039/b820162p · Cited by 1,673 · see citing works
Agarwal, S. (2010) · Polymer Chemistry · doi:10.1039/c0py00040j · Cited by 263 · see citing works
Bailey, W. J., Ni, Z., & Wu, S. (1982) · Journal of Polymer Science Polymer Chemistry Edition · doi:10.1002/pol.1982.170201101 · Cited by 259 · see citing works
Bailey, W. J., Ni, Z., & Wu, S. R. (1982) · Macromolecules · doi:10.1021/ma00231a006 · Cited by 171 · see citing works
Jin, S. Z., & Gonsalves, K. E. (1997) · Macromolecules · doi:10.1021/ma961590h · Cited by 114 · see citing works
Synthesis of block, graft and star polymers from inorganic macroinitiators
Matyjaszewski, K. A., Miller, P. J., Fossum, E., & Nakagawa, Y. (1998) · Applied Organometallic Chemistry · doi:10.1002/(sici)1099-0739(199810/11)12:10/11 · Cited by 112 · see citing works
Roberts, G. E., Coote, M. L., Heuts, J. P. A., Morris, L. M., & Davis, T. P. (1999) · Macromolecules · doi:10.1021/ma9813587 · Cited by 107 · see citing works
Jin, S. Z., & Gonsalves, K. E. (1998) · Macromolecules · doi:10.1021/ma9707289 · Cited by 101 · see citing works
Agarwal, S., Kumar, R., Kissel, T., & Reul, R. (2009) · Polymer Journal · doi:10.1295/polymj.pj2009091 · Cited by 83 · see citing works
Klemm, E., & Schulze, T. G. (1999) · Acta Polymerica · doi:10.1002/(sici)1521-4044(19990101)50:1 · Cited by 52 · see citing works
Photoinitiated ring‐opening polymerization of 2‐methylene‐1,3‐dioxepane
Endo, T., Okawara, M., Bailey, W. J., Azuma, K., Nate, K., & Yokono, H. (1983) · Journal of Polymer Science Polymer Letters Edition · doi:10.1002/pol.1983.130210510 · Cited by 49 · see citing works
Recent Advances in Free-Radical Ring-Opening Polymerization
Bailey, W. J., Chou, J. L., Feng, P.-Z., Issari, B., Kuruganti, V., & Zhou, L. (1988) · Journal of Macromolecular Science Part A - Chemistry · doi:10.1080/00222338808053398 · Cited by 42 · see citing works
Undin, J., Plikk, P., Finne‐Wistrand, A., & Albertsson, A. (2010) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24292 · Cited by 42 · see citing works
Self-citationWei, Y., CONNORS, E. J., Jia, X., & Wang, B. (1996) · Chemistry of Materials · doi:10.1021/cm950487o · Cited by 35 · see citing works
A new elimination with phase-transfer catalysis for cyclic ketene acetals
Bailey, W. J., & Zhou, L. (1991) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)74266-3 · Cited by 32 · see citing works
Plikk, P., Tyson, T., Finne‐Wistrand, A., & Albertsson, A. (2009) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.23511 · Cited by 31 · see citing works
Self-citationLipase specificity for the hydrolysis of poly (vinyl acetate)
Chattopadhyay, S., Sivalingam, G., & Madras, G. (2003) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(03)00031-4 · Cited by 23 · see citing works
Exploratory ring-opening polymerization: Ring-opening polymerization of vinylketene cyclic acetal
Cho, I., & Kim, S. (1990) · Journal of Polymer Science Polymer Letters Edition · doi:10.1002/pol.1990.140281304 · Cited by 16 · see citing works
Introduction to polymer science and chemistry: a problem solving guide
(2007) · Choice Reviews Online · doi:10.5860/choice.44-2711 · Cited by 1 · see citing works
Controlled free radical ring-opening polymerization and chain extension of the living polymer
Wei, Y., Connors, E. J., Jia, X., & Wang, C. (1998) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/(sici)1099-0518(19980415)36:5
Flagged first, then by citations
Cited by
Sorted by citations
Tardy, A., Nicolas, J., Gigmes, D., Lefay, C., & Guillaneuf, Y. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00319 · Cited by 469 · see citing works
Ring-Opening Polymerization—An Introductory Review
Nuyken, O., & Pask, S. (2013) · Polymers · doi:10.3390/polym5020361 · Cited by 456 · see citing works
Toughening hydrogels through force-triggered chemical reactions that lengthen polymer strands
Wang, Z., Zheng, X., Ouchi, T., Kouznetsova, T. B., Beech, H. K., Av-Ron, S., Matsuda, T., Bowser, B. H., Wang, S., Johnson, J. A., et al. (2021) · Science · doi:10.1126/science.abg2689 · Cited by 369 · see citing works
Pesenti, T., & Nicolas, J. (2020) · ACS Macro Letters · doi:10.1021/acsmacrolett.0c00676 · Cited by 214 · see citing works
Tardy, A., Honore, J., Tran, J., Siri, D., Delplace, V., Bataille, I., Letourneur, D., Perrier, J., Nicoletti, C., Maresca, M., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201707043 · Cited by 114 · see citing works
Wong, E. H. H., Khin, M. M., Ravikumar, V., Si, Z., Rice, S. A., & Chan‐Park, M. B. E. (2016) · Biomacromolecules · doi:10.1021/acs.biomac.5b01766 · Cited by 109 · see citing works
Cui, H., Liu, Y., Cheng, Y., Zhang, Z., Zhang, P., Chen, X., & Wei, Y. (2014) · Biomacromolecules · doi:10.1021/bm4018963 · Cited by 110 · see citing works
Delplace, V., Tardy, A., Harrisson, S., Mura, S., Gigmès, D., Guillaneuf, Y., & Nicolas, J. (2013) · Biomacromolecules · doi:10.1021/bm401157g · Cited by 109 · see citing works
New Chemistry in Functional Aliphatic Polyesters
Tong, R. (2017) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b00524 · Cited by 106 · see citing works
Olsén, P., Undin, J., Odelius, K., Keul, H., & Albertsson, A. (2016) · Biomacromolecules · doi:10.1021/acs.biomac.6b01375 · Cited by 98 · see citing works
Self-citationLefay, C., & Guillaneuf, Y. (2023) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2023.101764 · Cited by 101 · see citing works
Hedir, G. G., Bell, C. A., O’Reilly, R. K., & Dove, A. P. (2015) · Biomacromolecules · doi:10.1021/acs.biomac.5b00476 · Cited by 95 · see citing works
Functional Degradable Polymers by Xanthate-Mediated Polymerization
Hedir, G. G., Bell, C. A., Ieong, N. S., Chapman, E., Collins, I. R., O’Reilly, R. K., & Dove, A. P. (2014) · Macromolecules · doi:10.1021/ma500428e · Cited by 92 · see citing works
Polymeric biomaterials with engineered degradation
Deshayes, S., & Kasko, A. M. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26765 · Cited by 90 · see citing works
Radical Ring-Opening Copolymerization-Induced Self-Assembly (rROPISA)
Guégain, E., Zhu, C., Giovanardi, E., & Nicolas, J. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b00161 · Cited by 84 · see citing works
Zeng, T., You, W., Chen, G., Nie, X., Zhang, Z., Xia, L., Hong, C., Chen, C., & You, Y. (2020) · iScience · doi:10.1016/j.isci.2020.100904 · Cited by 75 · see citing works
Undin, J., Finne‐Wistrand, A., & Albertsson, A. (2013) · Biomacromolecules · doi:10.1021/bm4004783 · Cited by 71 · see citing works
Self-citationGuégain, E., Michel, J., Boissenot, T., & Nicolas, J. (2018) · Macromolecules · doi:10.1021/acs.macromol.7b02655 · Cited by 72 · see citing works
Controlling the synthesis of degradable vinyl polymers by xanthate-mediated polymerization
Bell, C. A., Hedir, G. G., O’Reilly, R. K., & Dove, A. P. (2015) · Polymer Chemistry · doi:10.1039/c5py01156f · Cited by 70 · see citing works
Tran, J., Guégain, E., Ibrahim, N., Harrisson, S., & Nicolas, J. (2016) · Polymer Chemistry · doi:10.1039/c6py00778c · Cited by 69 · see citing works
Gigmès, D., Steenberge, P. H. M. V., Siri, D., D’hooge, D., Guillaneuf, Y., & Lefay, C. (2018) · Macromolecular Rapid Communications · doi:10.1002/marc.201800193 · Cited by 66 · see citing works
Delplace, V., Guégain, E., Harrisson, S., Gigmès, D., Guillaneuf, Y., & Nicolas, J. (2015) · Chemical Communications · doi:10.1039/c5cc04610f · Cited by 64 · see citing works
Hedir, G. G., Arno, M. C., Langlais, M., Husband, J. T., O’Reilly, R. K., & Dove, A. P. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201703763 · Cited by 64 · see citing works
Lena, J.-B., Jackson, A. W., Chennamaneni, L. R., Wong, C. T., Lim, F. C. H., Andriani, Y., Thoniyot, P., & van Herk, A. M. (2020) · Macromolecules · doi:10.1021/acs.macromol.0c00207 · Cited by 64 · see citing works
Bossion, A., Zhu, C., Guerassimoff, L., Mougin, J., & Nicolas, J. (2022) · Nature Communications · doi:10.1038/s41467-022-30220-y · Cited by 63 · see citing works
Delplace, V., Harrisson, S., Tardy, A., Gigmès, D., Guillaneuf, Y., & Nicolas, J. (2013) · Macromolecular Rapid Communications · doi:10.1002/marc.201300809 · Cited by 57 · see citing works
Ivanchenko, O., Authesserre, U., Coste, G., Mazières, S., Destarac, M., & Harrisson, S. (2021) · Polymer Chemistry · doi:10.1039/d1py00080b · Cited by 56 · see citing works
Lena, J.-B., & van Herk, A. M. (2019) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.9b02375 · Cited by 56 · see citing works
Guégain, E., Tran, J., Deguettes, Q., & Nicolas, J. (2018) · Chemical Science · doi:10.1039/c8sc02256a · Cited by 55 · see citing works
Tran, J., Pesenti, T., Cressonnier, J., Lefay, C., Gigmès, D., Guillaneuf, Y., & Nicolas, J. (2018) · Biomacromolecules · doi:10.1021/acs.biomac.8b01500 · Cited by 52 · see citing works
Undin, J., Finne‐Wistrand, A., & Albertsson, A. (2014) · Biomacromolecules · doi:10.1021/bm500689g · Cited by 50 · see citing works
Self-citationDing, D., Pan, X., Zhang, Z., Li, N., Zhu, J., & Zhu, X. (2016) · Polymer Chemistry · doi:10.1039/c6py01061j · Cited by 47 · see citing works
RAFT/MADIX copolymerization of vinyl acetate and 5,6‐benzo‐2‐methylene‐1,3‐dioxepane
d’Ayala, G. G., Malinconico, M., Laurienzo, P., Tardy, A., Guillaneuf, Y., Lansalot, M., D’Agosto, F., & Charleux, B. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26976 · Cited by 41 · see citing works
Main-chain degradable single-chain cyclized polymers as gene delivery vectors
Gao, Y., Böhmer, V. I., Zhou, D., Zhao, T., Wang, W., & Paulusse, J. M. J. (2016) · Journal of Controlled Release · doi:10.1016/j.jconrel.2016.07.046 · Cited by 41 · see citing works
Backbone-Degradable Vinyl Acetate Latex: Coatings for Single-Use Paper Products
Carter, M. C. D., Hejl, A., Woodfin, S., Einsla, B. R., Jančo, M., DeFelippis, J., Cooper, R. J., & Even, R. C. (2021) · ACS Macro Letters · doi:10.1021/acsmacrolett.1c00172 · Cited by 41 · see citing works
Synthesis and Characterization of Backbone Degradable Azlactone-Functionalized Polymers
Carter, M. C. D., Jennings, J., Appadoo, V., & Lynn, D. M. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b01212 · Cited by 40 · see citing works
Mothe, S. R., Tan, J. S. J., Chennamaneni, L. R., Aidil, F., Su, Y., Kang, H. C., Lim, F. C. H., & Thoniyot, P. (2020) · Journal of Polymer Science · doi:10.1002/pol.20200210 · Cited by 39 · see citing works
Uchiyama, M., Murakami, Y., Satoh, K., & Kamigaito, M. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202215021 · Cited by 38 · see citing works
Tardy, A., Gil, N., Plummer, C. M., Zhu, C., Harrisson, S., Siri, D., Nicolas, J., Gigmès, D., Guillaneuf, Y., & Lefay, C. (2020) · Polymer Chemistry · doi:10.1039/d0py01179g · Cited by 38 · see citing works
Self-Cross-Linking Degradable Polymers for Antifouling Coatings
Xie, Q., Zhou, X. C., Ma, C., & Zhang, G. (2017) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b00557 · Cited by 33 · see citing works
Wenzel, F., Hamzehlou, S., Pardo, L. M., Aguirre, M., & Leiza, J. R. (2020) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.0c04117 · Cited by 33 · see citing works
Kobben, S., Ethirajan, A., & Junkers, T. (2014) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.27180 · Cited by 32 · see citing works
Scott, A. J., & Penlidis, A. (2018) · Processes · doi:10.3390/pr6010008 · Cited by 32 · see citing works
Oh, X. Y., Ge, Y., & Goto, A. (2021) · Chemical Science · doi:10.1039/d1sc03560f · Cited by 26 · see citing works
Tokiwa, Y., & Calabia, B. P. (2015) · Springer eBooks · doi:10.1007/978-3-642-36199-9_402-1 · Cited by 26 · see citing works
Biodegradable Inorganic–Organic POSS–PEG Hybrid Hydrogels as Scaffolds for Tissue Engineering
Yu, J., Liu, Z., Shen, J., Lu, C., Hu, X., Dong, N., Yang, G., Chen, Z., & Nie, J. (2017) · Macromolecular Materials and Engineering · doi:10.1002/mame.201700142 · Cited by 24 · see citing works
Ai, X., Pan, J., Xie, Q., Ma, C., & Zhang, G. (2021) · Polymer Chemistry · doi:10.1039/d1py00810b · Cited by 22 · see citing works
Zeng, T., Xia, L., Zhang, Z., Hong, C., & You, Y. (2020) · Polymer Chemistry · doi:10.1039/d0py00200c · Cited by 23 · see citing works
Tardy, A., Honore, J., Tran, J., Siri, D., Delplace, V., Bataille, I., Letourneur, D., Perrier, J., Nicoletti, C., Maresca, M., et al. (2017) · Angewandte Chemie · doi:10.1002/ange.201707043 · Cited by 26 · see citing works
Uchiyama, M., Imai, M., & Kamigaito, M. (2024) · Polymer Journal · doi:10.1038/s41428-023-00869-3 · Cited by 21 · see citing works
Hedir, G. G., Pitto‐Barry, A., Dove, A. P., & O’Reilly, R. K. (2015) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.27915 · Cited by 19 · see citing works
Endo, T., & Sudo, A. (2015) · ACS symposium series · doi:10.1021/bk-2015-1187.ch002 · Cited by 18 · see citing works
Kertsomboon, T., Agarwal, S., & Chirachanchai, S. (2020) · Macromolecular Rapid Communications · doi:10.1002/marc.202000243 · Cited by 18 · see citing works
Undin, J., Olsén, P., Godfrey, J., Odelius, K., & Albertsson, A.-C. (2016) · Polymer · doi:10.1016/j.polymer.2016.01.067 · Cited by 17 · see citing works
Self-citationGhorbani, M., & Prince, E. (2024) · Biomacromolecules · doi:10.1021/acs.biomac.4c01116 · Cited by 17 · see citing works
Mousa, M., Jonsson, M., Wilson, O. R., Geerts, R., Bergenudd, H., Bengtsson, C., Kron, A. L., & Malmström, E. (2023) · Polymer Chemistry · doi:10.1039/d3py00630a · Cited by 16 · see citing works
Carter, M. C. D., Hejl, A., Jančo, M., DeFelippis, J., Yang, P., Gallagher, M., & Liang, Y. (2023) · Macromolecules · doi:10.1021/acs.macromol.3c00571 · Cited by 15 · see citing works
Balaji, A., Bell, C. A., Houston, Z. H., Bridle, K. R., Genz, B., Fletcher, N. L., Ramm, G. A., & Thurecht, K. J. (2023) · Biomaterials · doi:10.1016/j.biomaterials.2023.122318 · Cited by 15 · see citing works
Hedir, G. G., Arno, M. C., Langlais, M., Husband, J. T., O’Reilly, R. K., & Dove, A. P. (2017) · Angewandte Chemie · doi:10.1002/ange.201703763 · Cited by 16 · see citing works
Mothe, S. R., Zhao, W., van Herk, A. M., & Thoniyot, P. (2024) · Macromolecules · doi:10.1021/acs.macromol.3c02474 · Cited by 14 · see citing works
Mothe, S. R., Kanaujia, P., Oh, A. B. Y., Ang, P., & Thoniyot, P. (2023) · European Polymer Journal · doi:10.1016/j.eurpolymj.2023.112287 · Cited by 13 · see citing works
Joubert, F., & Pasparakis, G. (2020) · Journal of Polymer Science · doi:10.1002/pol.20200303 · Cited by 13 · see citing works
Toughening Hydrogels Through Force-triggered Chemical Reactions that Lengthen Polymer StrandsPreprint
Wang, Z., Zheng, X. J., Ouchi, T., Kouznetsova, T. B., Beech, H. K., Av-Ron, S. H. M., Bowser, B. H., Wang, S., Johnson, J. A., Kalow, J. A., et al. (2021) · ChemRxiv · doi:10.26434/chemrxiv.13514377.v1 · Cited by 13 · see citing works
Du, Y., Ren, L., Sloan, J., Chong, S., Lamprou, A., Du, Y., & Coughlin, E. B. (2024) · Polymer · doi:10.1016/j.polymer.2024.127444 · Cited by 12 · see citing works
Biodegradable polyacrylate copolymer coating for bio-functional magnesium alloy
Shi, H., Hong, L., Pan, K., Wei, W., Liu, X., & Li, X. (2021) · Progress in Organic Coatings · doi:10.1016/j.porgcoat.2021.106422 · Cited by 12 · see citing works
Degradable Vinyl-Based Polymers by Radical Ring-Opening Polymerization: A User Guide
Luzel, B., Kouider, S., D’Agosto, F., Gigmès, D., Lansalot, M., Bates, C. M., Ackerman, E., Labalme, S., Johnson, J. A., Niu, J., et al. (2026) · ACS Polymers Au · doi:10.1021/acspolymersau.5c00191 · Cited by 11 · see citing works
Insertion of ester bonds in three terpolymerization systems
Lena, J.-B., Ramalingam, B., Rusli, W., Chennamaneni, L. R., Thoniyot, P., & van Herk, A. M. (2022) · European Polymer Journal · doi:10.1016/j.eurpolymj.2022.111627 · Cited by 12 · see citing works
Mothe, S. R., Chennamaneni, L. R., Tan, J. S. J., Lim, F. C. H., Zhao, W., & Thoniyot, P. (2023) · Macromolecular Chemistry and Physics · doi:10.1002/macp.202300221 · Cited by 11 · see citing works
Ahmed, S. E., Fletcher, N. L., Prior, A. R., Huda, P., Bell, C. A., & Thurecht, K. J. (2022) · Polymer Chemistry · doi:10.1039/d2py00257d · Cited by 10 · see citing works
Balaji, A., Prior, A. R., O’Reilly, R. K., Dove, A. P., Thurecht, K. J., & Bell, C. A. (2024) · Polymer Chemistry · doi:10.1039/d4py00049h · Cited by 10 · see citing works
Wang, Z., & Debuigne, A. (2023) · Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics · doi:10.1080/15583724.2023.2181819 · Cited by 9 · see citing works
Progress in the Preparation of Functional and (Bio)Degradable Polymers via Living Polymerizations
Lin, S.-T., Wang, C., Chang, C., Nakamura, Y., Lin, K. A., & Huang, C. (2020) · International Journal of Molecular Sciences · doi:10.3390/ijms21249581 · Cited by 8 · see citing works
Nugroho, R. W. N., Roy, P. K., Odelius, K., & Albertsson, A. (2012) · Polymers for Advanced Technologies · doi:10.1002/pat.3098 · Cited by 8 · see citing works
Self-citationUse of Hydrolysis-Robust Cyclic Vinyl Acetals in Radical Ring-Opening Emulsion Copolymerization
Kordes, B. R., & Agarwal, S. (2023) · Macromolecules · doi:10.1021/acs.macromol.3c01213 · Cited by 7 · see citing works
Movafagh, M., Meek, K. M., & Dubé, M. A. (2024) · ChemSusChem · doi:10.1002/cssc.202402478 · Cited by 5 · see citing works
Movafagh, M., Meek, K. M., Scott, A. J., Penlidis, A., & Dubé, M. A. (2024) · Polymers · doi:10.3390/polym16101330 · Cited by 5 · see citing works
Reischke, R. (2022) · Macromolecular Theory and Simulations · doi:10.1002/mats.202200063 · Cited by 5 · see citing works
Chen, J., & Jackson, N. E. (2025) · Chemistry of Materials · doi:10.1021/acs.chemmater.5c01608 · Cited by 4 · see citing works
Toughening Hydrogels Through Force-triggered Chemical Reactions that Lengthen Polymer StrandsPreprint
Wang, Z., Zheng, X. J., Ouchi, T., Kouznetsova, T., Beech, H. K., Av-Ron, S. H. M., Bowser, B. H., Wang, S., Johnson, J. A., Kalow, J. A., et al. (2021) · ChemRxiv · doi:10.26434/chemrxiv.13514377 · Cited by 4 · see citing works
Tokiwa, Y., & Calabia, B. P. (2015) · Springer eBooks · doi:10.1007/978-3-642-29648-2_402 · Cited by 4 · see citing works
Sugihara, S., Endo, A., Raje, K., Matsumoto, A., Fujita, S., & Maeda, Y. (2025) · Polymer Chemistry · doi:10.1039/d5py00398a · Cited by 3 · see citing works
Kinetic Features of Radical Ring-Opening Polymerization of Ketene Acetals
Zaremski, M. Y., & Aliev, E. E. (2024) · Polymer Science Series B · doi:10.1134/s156009042460147x · Cited by 3 · see citing works
Degradable aqueous polymer dispersions
Barquero, A., González, E., Aguirre, M., & Hamzehlou, S. (2023) · Advances in chemical engineering · doi:10.1016/bs.ache.2023.08.003 · Cited by 2 · see citing works
Mothe, S. R., Ang, P., Lau, H. H., Oh, A. B. Y., & Thoniyot, P. (2023) · Next Materials · doi:10.1016/j.nxmate.2023.100055 · Cited by 2 · see citing works
Castro, N. L. D. S. E., Deng, Y., Chen, X., Nele, M., Pinto, J. C., & Gaitzsch, J. (2025) · Journal of Polymer Science · doi:10.1002/pol.20250388 · Cited by 2 · see citing works
Uchiyama, M., Murakami, Y., Satoh, K., & Kamigaito, M. (2022) · Angewandte Chemie · doi:10.1002/ange.202215021 · Cited by 2 · see citing works
Кинетические особенности радикальной полимеризации кетенацеталей с раскрытием цикла
Заремский, М. Ю., & Aliev, E. E. (2024) · Высокомолекулярные соединения С · doi:10.31857/s2308114724020019
Deng, Y., Mehner, F., & Gaitzsch, J. (2026) · Elsevier eBooks · doi:10.1016/b978-0-323-95486-0.00202-7
Synthesis of degradable vinyl polymer nanoparticles by radical ring opening copolymerization (rROP)
Lages, M. (2022) · theses.fr (ABES) · doi:10.70675/fcc7fd8fz34bcz43ecz9067z819dba10aac3
Aqueous emulsion polymerization for the synthesis of degradable vinylic polymer particles
Galanopoulo, P. (2022) · theses.fr (ABES) · doi:10.70675/b187f2d0z7673z4405zb56bze940c6b00bb4
Luo, Q., Li, J., Li, C. B., Zhao, L., & Xi, Z. (2026) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.6c00880
- Authors
- Undin, J., Illanes, T., Finne-Wistrand, A., & Albertsson, A.-C.
- Affiliations
- KTH Royal Institute of Technology (SE)
- Corresponding author
- Albertsson, Ann-Christine
- Venue
- Polymer Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 3
- Issue
- 5
- Pages
- 1260
- ISSN
- 1759-9954 (ISSN-L)
- 1759-9962
- OpenAlex
- W2018248204
- Cited by
- 97
- References
- 20
- Citations by year
- 2026: 3 · 2025: 3 · 2024: 9 · 2023: 10 · 2022: 10 · 2021: 9 · 2020: 10 · 2019: 3 · 2018: 6 · 2017: 8 · 2016: 7 · 2015: 7 · 2014: 5 · 2013: 6 · 2012: 1
- FWCI
- 2.46
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer Chemistry (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Medicine › Hydrogels: synthesis, properties, applications
- Keywords
- 2-methylene-1,3-dioxepane, vinyl acetate, copolymerization, radical ring-opening polymerization, degradable polymers, aliphatic polyesters, polyvinyl acetate, polyvinyl alcohol, copolymerization kinetics, reactivity ratios, alkaline hydrolysis, enzymatic hydrolysis, degradation profile, glass transition temperature, soft tissue engineering
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
