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Fully Degradable Thioester-Functional Homo- and Alternating Copolymers Prepared through Thiocarbonyl Addition–Ring-Opening RAFT Radical Polymerization

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Limits of Vinylidene Fluoride RAFT Polymerization

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Thioester-Functional Polyacrylamides: Rapid Selective Backbone Degradation Triggers Solubility Switch Based on Aqueous Lower Critical Solution Temperature/Upper Critical Solution Temperature

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Degradable PE-Based Copolymer with Controlled Ester Structure Incorporation by Cobalt-Mediated Radical Copolymerization under Mild Condition

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Efficient synthesis of 2-methylene-4-phenyl-1,3-dioxolane, a cyclic ketene acetal for controlling the NMP of methyl methacrylate and conferring tunable degradability

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Controlled Organocatalytic Ring-Opening Polymerization of ε-Thionocaprolactone

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A ring to rule them all: a cyclic ketene acetal comonomer controls the nitroxide-mediated polymerization of methacrylates and confers tunable degradability

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Enhanced Solubility of Polyvinyl Esters in scCO2by Means of Vinyl Trifluorobutyrate Monomer

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Nitroxide‐Mediated Radical Ring‐Opening Copolymerization: Chain‐End Investigation and Block Copolymer Synthesis

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Anionic Ring-Opening Polymerization of ε-Thionocaprolactone

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RAFT/MADIX copolymerization of vinyl acetate and 5,6‐benzo‐2‐methylene‐1,3‐dioxepane

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Copolymerization Behavior of 7-Methylene-2-methyl-1,5-dithiacyclooctane: Reversible Cross-Propagation

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DFT-calculation-assisted prediction of the copolymerization between cyclic ketene acetals and traditional vinyl monomers

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Phosphonate‐terminated poly(vinyl acetate) synthesized by RAFT/MADIX polymerization

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Aminolysis induced functionalization of (RAFT) polymer-dithioester with thiols and disulfides

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Dithiocarbamate-mediated controlled copolymerization of ethylene with cyclic ketene acetals towards polyethylene-based degradable copolymers

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Enhanced Stabilization of Water/scCO2 Interface by Block-Like Spontaneous Gradient Copolymers

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Functional polythiiranes 6: Hydrolysis of side chains ester and monothioacetal functions of comb-like polythiiranes

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Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach

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Recent advances in the ring-opening polymerization of sulfur-containing monomers

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Thiocarbonyl chemistry in polymer science

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Fully Degradable Polyacrylate Networks from Conventional Radical Polymerization Enabled by Thionolactone Addition

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Spotlight on the Life Cycle of Acrylamide-Based Polymers Supporting Reductions in Environmental Footprint: Review and Recent Advances

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Direct Radical Copolymerizations of Thioamides To Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbones

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Development of an Efficient Thionolactone for Radical Ring-Opening Polymerization by a Combined Theoretical/Experimental Approach

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Biocompatibility and Physiological Thiolytic Degradability of Radically Made Thioester-Functional Copolymers: Opportunities for Drug Release

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Mechanistic Investigation of ε-Thiono-Caprolactone Radical Polymerization: An Interesting Tool to Insert Weak Bonds into Poly(vinyl esters)

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Addition–Fragmentation Ring‐Opening Polymerization of Bio‐Based Thiocarbonyl <scp>l</scp>‐Lactide for Dual Degradable Vinyl Copolymers

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Interlocking degradation of vinyl polymers via main‐chain CC bonds scission by introducing pendant‐responsive comonomers

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A General Strategy for Radical Ring-Opening Polymerization of Macrocyclic Allylic Sulfides

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Radical ring-opening polymerization of sustainably-derived thionoisochromanone

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Insertion of Degradable Thioester Linkages into Styrene and Methacrylate Polymers: Insights into the Reactivity of Thionolactones

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Degradable Linear and Bottlebrush Thioester-Functional Copolymers through Atom-Transfer Radical Ring-Opening Copolymerization of a Thionolactone

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Lactide-derived monomers for radical thiocarbonyl addition ring-opening copolymerisation

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Recent advances and future perspectives in engineering biodegradable face masks

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Degradable Latexes by Nitroxide-mediated Aqueous Seeded Emulsion Copolymerization Using a Thionolactone

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Ring size-reactivity relationship in radical ring-opening copolymerisation of thionolactones with vinyl pivalate

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On-Demand Degradation of Thioester/Thioketal Functions in Vinyl Pivalate-Derived Copolymers with Thionolactones

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Plenty of Space in the Backbone: Radical Ring‐Opening Polymerization

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RAFT step-growth polymerization of bis-acrylamides and their facile degradation

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Radical Ring-Opening Polymerization: Unlocking the Potential of Vinyl Polymers for Drug Delivery, Tissue Engineering, and More

Ghorbani, M., & Prince, E. (2024) · Biomacromolecules · doi:10.1021/acs.biomac.4c01116 · Cited by 17 · see citing works

Umpolung Isomerization in Radical Copolymerization of Benzyl Vinyl Ether with Pentafluorophenylacrylate Leading to Degradable AAB Periodic Copolymers

Kuroda, K., & Ouchi, M. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202316875 · Cited by 18 · see citing works

Easy Access to Diverse Multiblock Copolymers with On‐Demand Blocks via Thioester‐Relayed In‐Chain Cascade Copolymerization

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Synthesis of Degradable Polystyrene and Its Derivative with In-Chain Thioester via Radical and Cationic Copolymerizations with a Seven-Membered Benzene-Fused Thionolactone

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1,1′- Thiocarbonyldiimidazole Radical Copolymerization for the Preparation of Degradable Vinyl Polymers

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Topochemical Ring-Opening Polymerization of an Oxathianethione

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Degradable Vinyl-Based Polymers by Radical Ring-Opening Polymerization: A User Guide

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Fast and Selective Main-Chain Scission of Vinyl Polymers Using the Domino Reaction in the Alternating Sequence for Transesterification

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Backbone Degradable Polymers via Chain-growth Radical Polymerization

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Degradable N-Vinyl Copolymers through Radical Ring-Opening Polymerization of Cyclic Thionocarbamates

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Synthesis and Properties of Phosphorus-Containing Pseudo-Poly(Amino Acid)sof Polyester Type Based on N-Derivatives of Glutaminic Acid

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Synthesis of Degradable Polyethylene and Poly(ethylene-co-vinyl acetate) by Radical Co- and Terpolymerization of Ethylene, ε-Thionocaprolactone, and Vinyl Acetate

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The successful impossible radical ring-opening copolymerization of thionolactones and methacrylates via an auxiliary third comonomer

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Understanding synthesis and degradation of backbone deconstructable (co)polymers by radical ring-opening polymerization through theoretical calculation and numerical simulation

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An orthogonal O , S -CKA monomer for the introduction of thioester and/or thionoester functionalities by radical polymerization

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Thioester-rich degradable copolymers from a thionolactone and S-vinyl and P-vinyl monomers

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Radical Copolymerization of Thionoglycolide and Derivatives for Preparation of Degradable Vinyl Polymers

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Degradable vinyl copolymers featuring backbone dithiocarbonates by radical copolymerization of a cyclic xanthate

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Single-Unit Comonomer Insertion Initiates Radical Polymerization of Thionolactone to Give Chemically and Thermally Degradable Polythioesters

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Dithioketal Polymers Via Radical Polymerization of γ‐Dithiobutyrolactone

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Degradable Telechelic Polythioesters from Activated Diesters and Their Site-Selective End-Group Functionalization

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Dithioketal Polymers Via Radical Polymerization of γ‐Dithiobutyrolactone

Odnoroh, M., Ivanchenko, O., Kroeger, A. A., Coote, M. L., Mazières, S., & Destarac, M. (2026) · Angewandte Chemie International Edition · doi:10.1002/anie.2024128 · Cited by 1 · see citing works

Easy Access to Diverse Multiblock Copolymers with On‐Demand Blocks via Thioester‐Relayed In‐Chain Cascade Copolymerization

Zhang, Z., Xiong, Y., Yang, P., Li, Y., Tang, R., Nie, X., Chen, G., Wang, L., Hong, C., & You, Y. (2023) · Angewandte Chemie · doi:10.1002/ange.202216685 · Cited by 1 · see citing works

Umpolung Isomerization in Radical Copolymerization of Benzyl Vinyl Ether with Pentafluorophenylacrylate Leading to Degradable AAB Periodic Copolymers

Kuroda, K., & Ouchi, M. (2023) · Angewandte Chemie · doi:10.1002/ange.202316875 · Cited by 1 · see citing works

Advances in Radical Ring-opening Polymerization Toward (bio)degradable Polymers: From Synthesis to Application

Deng, Y., Mehner, F., & Gaitzsch, J. (2026) · Elsevier eBooks · doi:10.1016/b978-0-323-95486-0.00202-7

Radical ring-opening copolymerization of cyclic ketene acetals : a new route for the synthesis of degradable and functional polymers for cancer therapy

Pesenti, T. (2022) · doi:10.70675/a7d8b5f0z8289z4baczac21zc6e15d2b455e

Controlled radical polymerization of ethylene by iodine transfer

Baffie, F. (2021) · doi:10.70675/1908d59dzb569z43daz808czdef17dd4a603

Synthesis of degradable vinyl polymer nanoparticles by radical ring opening copolymerization (rROP)

Lages, M. (2022) · theses.fr (ABES) · doi:10.70675/fcc7fd8fz34bcz43ecz9067z819dba10aac3

Synthèse de polymères vinyliques dégradables par insertion de liaisons clivables : de la modélisation au matériau

Gil, N. (2022) · doi:10.70675/3d26a1b1z6117z4218zbd1bzdc5ec40389a8

Aqueous emulsion polymerization for the synthesis of degradable vinylic polymer particles

Galanopoulo, P. (2022) · theses.fr (ABES) · doi:10.70675/b187f2d0z7673z4405zb56bze940c6b00bb4

(6) Fundamental Chemistry and Recent Development of Ring-Opening Polymerization

SUZUKI, M., & MATSUOKA, S.-I. (2022) · Journal of The Adhesion Society of Japan · doi:10.11618/adhesion.58.361

From Plant-Derived Monomers to Degradable Polymers via Precision Polymerization

Satoh, K., & Kubo, T. (2026) · Journal of Synthetic Organic Chemistry Japan · doi:10.5059/yukigoseikyokaishi.84.569

Sequence Modulated Thionoester‐Containing Poly(ε‐caprolactone) for Stimuli‐Triggered Degradation

Molina, A. M., Liang, Z., Kubo, T., & Satoh, K. (2026) · Macromolecular Chemistry and Physics · doi:10.1002/macp.70297

Turning Readily Available Acrylates into Cyclic Xanthates for Radical Ring-Opening Polymerizations

Bätz, R., Nestmann, N., & Brendel, J. C. (2026) · ACS Polymers Au · doi:10.1021/acspolymersau.6c00183

Mechanistic Investigation of ε-Thiono-Caprolactone Radical Polymerization: An Interesting Tool to Insert Weak Bonds into Poly(vinyl esters)

Plummer, C. M., Gil, N., Dufils, P.-E., Wilson, D. J., Lefay, C., Gigmes, D., & Guillaneuf, Y. (2021) · ACS Applied Polymer Materials · doi:10.1021/acsapm.1c00569 · Cited by 45 · see citing works

Synthesis of Degradable Polyethylene and Poly(ethylene-co-vinyl acetate) by Radical Co- and Terpolymerization of Ethylene, ε-Thionocaprolactone, and Vinyl Acetate

Vũ, N. Đ., Ivanchenko, O., Baffie, F., Guillaneuf, Y., Gigmès, D., Harrisson, S., Monteil, V., Destarac, M., & D’Agosto, F. (2024) · Macromolecules · doi:10.1021/acs.macromol.4c00085 · Cited by 9 · see citing works

Degradable vinyl copolymers through thiocarbonyl addition–ring-opening (TARO) polymerization

Bingham, N. M., & Roth, P. J. (2019) · Chemical Communications · doi:10.1039/c8cc08287a · Cited by 176 · see citing works

Thioester-rich degradable copolymers from a thionolactone and S-vinyl and P-vinyl monomers

Hepburn, K. S., Zulkifli, N. S., Delorme, C., Kazmi, T., Bakar, R. A., & Roth, P. J. (2024) · Polymer · doi:10.1016/j.polymer.2024.127485 · Cited by 5 · see citing works

Structure and properties of polyurethanes based on halogenated and nonhalogenated soy-polyols

Petrovìć, Z. S., Guo, A., & Zhang, W. (2000) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/1099-0518(20001115)38:22 · Cited by 160 · see citing works