The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Quantifying and understanding the electronic properties of N-heterocyclic carbenes
Abstract
The use of N-heterocyclic carbenes (NHCs) in chemistry has developed rapidly over the past twenty years. These interesting compounds are predominantly employed in organometallic chemistry as ligands for various metal centres, and as organocatalysts able to mediate an exciting range of reactions. However, the sheer number of NHCs known in the literature can make the appropriate choice of NHC for a given application difficult. A number of metrics have been explored that allow the electronic properties of NHCs to be quantified and compared. In this review, we discuss these various metrics and what they can teach about the electronic properties of NHCs. Data for approximately three hundred NHCs are presented, obtained from a detailed survey of the literature.
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Cites
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824
Cited by
Riener, K., Haslinger, S., Raba, A., Högerl, M. P., Cokoja, M., Herrmann, W. A., & Kühn, F. E. (2014) · Chemical Reviews · doi:10.1021/cr4006439 · Cited by 411
Computational Ligand Descriptors for Catalyst Design
Durand, D. J., & Fey, N. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00588 · Cited by 406
Quantifying and understanding the steric properties of N-heterocyclic carbenes
Gómez-Suárez, A., Nelson, D. J., & Nolan, S. P. (2017) · Chemical Communications · doi:10.1039/c7cc00255f · Cited by 391
Self-citationLiske, A., Verlinden, K., Buhl, H., Schaper, K., & Ganter, C. (2013) · Organometallics · doi:10.1021/om400858y · Cited by 375
Gan, M.-M., Liu, J.-Q., Zhang, L., Wang, Y.-Y., Hahn, F. E., & Han, Y.-F. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00119 · Cited by 346
Metadata
- Authors
- Nelson, D. J., & Nolan, S. P.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 42
- Issue
- 16
- Pages
- 6723
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2156475195
- Cited by
- 1,092
- References
- 1
- FWCI
- 3.44
- Type
- journal article
- Language
- en
- Open access
- closed
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