The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Current density dependence of peroxide formation in the Li–O2 battery and its effect on charge
Abstract
We report a significant difference in the growth mechanism of Li2O2 in Li–O2 batteries for toroidal and thin-film morphologies which is dependent on the current rate that governs the electrochemical pathway. Evidence from diffraction, electrochemical, FESEM and STEM measurements shows that slower current densities favor aggregation of lithium peroxide nanocrystallites nucleated via solution dismutase on the surface of the electrode; whereas fast rates deposit quasi-amorphous thin films. The latter provide a lower overpotential on charge due to their nature and close contact with the conductive electrode surface, albeit at the expense of lower discharge capacity.
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Cites
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Metadata
- Authors
- Adams, B. D., Radtke, C., Black, R., Trudeau, M. L., Zaghib, K., & Nazar, L. F.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 6
- Issue
- 6
- Pages
- 1772
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2159411932
- Cited by
- 678
- References
- 27
- FWCI
- 51.72
- Type
- journal article
- Language
- en
- Open access
- closed
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