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Cited by 285

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Nitrogen-doped graphene for dye-sensitized solar cells and the role of nitrogen states in triiodide reduction

Hou, Shaocong, Cai, Xin, Wu, Hongwei, Yu, Xiao, Peng, Ming, Yan, Kai, Zou, Dechun·2013·Energy & Environmental Science

Abstract

Nitrogen-doped graphene was demonstrated as an efficient and alternative metal-free electrocatalyst for dye-sensitized solar cells. Electrochemical measurements showed that the nitrogen-doping process can remarkably improve the catalytic activity of graphene toward triiodide reduction, lower the charge transfer resistance, and thus enhance the corresponding photovoltaic performance. Furthermore, the nitrogen doping levels ranging from 3.5 at% to 18 at%, as well as the nitrogen states (including pyrrolic, pyridinic and quaternary configurations) in graphene, were controlled to interpret the roles of graphene structure in catalytic activity and device performance. The results suggested that the nitrogen states, rather than the total N content, have a significant effect on the catalytic activity. Both pyridinic and quaternary nitrogen states can provide active sites for promoting triiodide reduction reaction, probably due to the shift in redox potential and the lowered adsorption energy.

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Metadata

Authors
Hou, S., Cai, X., Wu, H., Yu, X., Peng, M., Yan, K., & Zou, D.
Venue
Energy & Environmental Science
Published
2013
Volume
6
Issue
11
Pages
3356
ISSN
  • 1754-5692 (ISSN-L)
  • 1754-5706
OpenAlex
W2059294885
Cited by
285
References
2
FWCI
12.62
Type
journal article
Language
en
Open access
closed

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