Large-ring lactones from plant oils
Abstract
Large-ring lactones and lactams were prepared utilising the full fatty acid chain of common plant oils as a source of the macrocycle. Ring closure via acyloin condensation does not require large volumes of solvents for dilution. Nonadecalactone (NDL) and tricosalactone (TCL) can be converted to novel polyesters by ring opening.
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ROP of macrolactones with ring sizes of 19 and 23 generates long-chain polyesters with higher and more predictable molecular weights than the ones prepared from the polycondensation of fatty acids.
“ROP of these macrolactones generates long-chain polyesters with higher and more predicable molecular weights than the ones prepared from the polycondensation of fatty acids.”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [181]
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- Authors
- Witt, T., & Mecking, S.
- Affiliations
- University of Konstanz (DE)
- Corresponding author
- Mecking, Stefan
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 15
- Issue
- 9
- Pages
- 2361
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2026510269
- Cited by
- 35
- References
- 21
- Citations by year
- 2026: 2 · 2024: 6 · 2022: 2 · 2021: 3 · 2020: 4 · 2019: 2 · 2018: 1 · 2017: 4 · 2016: 4 · 2015: 4 · 2014: 2 · 2013: 1
- FWCI
- 1.40
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Green Chemistry (publishedVersion)
- KOPS (University of Konstanz) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Synthesis and Reactions
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- lactams, vegetable oils, acyloin condensation, cyclization, ring opening, polyesters, solvent-free synthesis
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