The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Metal-free doped carbon materials as electrocatalysts for the oxygen reduction reaction
Abstract
Carbon materials such as graphite, graphene, carbon nanotubes and ordered mesoporous carbon have attracted a lot of attention for their use in fuel cells, due to beneficial properties like high conductivity, high mechanical and chemical stability and, for the latter, high surface area. Doping these materials with nitrogen or, less commonly, other elements alters their (electronic) properties, making them particularly suitable for application as electrocatalysts for the oxygen reduction reaction (ORR) in a fuel cell. This paper reviews the synthesis methods employed for the doping of these different types of carbon materials with various elements and the characterization techniques used to investigate their physicochemical properties such as degree of graphitization, dopant content, dopant configuration and surface area. Furthermore, their application as electrocatalysts for the oxygen reduction in a fuel cell is reviewed. Finally, the possible mechanisms for the ORR on N-doped carbon materials are critically discussed and compared to the mechanisms of commercial Pt/C electrocatalysts.
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Citations
Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Wang, H., Maiyalagan, T., & Wang, X. (2012) · ACS Catalysis · doi:10.1021/cs200652y · Cited by 3,618
High oxygen-reduction activity and durability of nitrogen-doped graphene
Geng, D., Chen, Y., Chen, Y., Li, Y., Li, R., Sun, X., Ye, S., & Knights, S. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00326c · Cited by 1,219
Shao, Y., Sui, J., Yin, G., & Gao, Y. (2008) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2007.09.047 · Cited by 763
Cited by
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
Metal-Free Catalysts for Oxygen Reduction Reaction
Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380
Recent advances in heterogeneous electrocatalysts for the hydrogen evolution reaction
Zeng, M., & Li, Y. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta02974k · Cited by 1,294
Nitrogen-doped carbon materials
Inagaki, M., Toyoda, M., Soneda, Y., & Morishita, T. (2018) · Carbon · doi:10.1016/j.carbon.2018.02.024 · Cited by 867
Zhang, J., & Dai, L. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01563 · Cited by 590
Metadata
- Authors
- Daems, N., Sheng, X., Vankelecom, I. F. J., & Pescarmona, P. P.
- Venue
- J. Mater. Chem. A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 2
- Issue
- 12
- Pages
- 4085-4110
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W2100647938
- Cited by
- 680
- References
- 4
- FWCI
- 20.08
- Type
- journal article
- Language
- en
- Open access
- closed
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