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Cited by 109biodegradable polymer synthesis and propertiesOrganometallic Complex Synthesis and CatalysisAsymmetric Synthesis and Catalysis

Zirconium complexes of bipyrrolidine derived salan ligands for the isoselective polymerisation of rac -lactide

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Jones, Matthew D., Hancock, Stuart L., McKeown, Paul, Schäfer, Pascal M., Buchard, Antoine, Thomas, Lynne H., Mahon, Mary F., Lowe, John P.·2014·Chem. Commun.
DOI 10.1039/c4cc07871c
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Abstract

We report a series of Zr( iv ) 2,2′-bipyrrolidine–salan derived complexes and their exploitation for the ROP of rac -lactide to afford highly isotactically enriched PLA.

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  • Other metal catalysts such as zirconium complexes with bispyrrolidine-salan ligand and zinc complexes with chiral or achiral auxiliary ligands have also been used to generate iso-enriched stereoblock PLAs from rac-LA.

    “Other metal catalysts such as zirconium complexes with bispyrrolidine-salan ligand 312 and zinc complexes with chiral or achiral auxiliary ligands [313][314][315][316] (Figure 7) have also been used to generate iso-enriched stereoblock PLAs from rac-LA.”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [312]

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Research works printed but not linked: 34

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Authors
Jones, M. D., Hancock, S. L., McKeown, P., Schäfer, P. M., Buchard, A., Thomas, L. H., Mahon, M. F., & Lowe, J. P.
Affiliations
University of Bath (GB)
Corresponding author
  • Jones, Matthew D.
  • Mahon, Mary F.
ORCID
Venue
Chem. Commun.
Publisher
Royal Society of Chemistry (RSC)
Published
2014
Volume
50
Issue
100
Pages
15967-15970
ISSN
  • 1359-7345 (ISSN-L)
  • 1364-548X
DOI
10.1039/c4cc07871c
OpenAlex
W2136605826
Cited by
109
References
40
Citations by year
2026: 2 · 2024: 2 · 2023: 1 · 2022: 4 · 2021: 10 · 2020: 7 · 2019: 11 · 2018: 15 · 2017: 27 · 2016: 18 · 2015: 12
FWCI
7.16
Type
journal article
Language
en
Open access
Licence
cc-by
Locations
  • Chemical Communications (publishedVersion, cc-by)
  • PubMed (publishedVersion)
  • Pure (University of Bath) (publishedVersion, cc-by)
  • The University of Bath Online Publications Store (The University of Bath) (submittedVersion, cc-by)
Funders
Engineering and Physical Sciences Research Council (1223532, EP/J003921/1)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
  • Physical Sciences › Chemistry › Organic Chemistry › Asymmetric Synthesis and Catalysis
Keywords
zirconium complexes, salan ligands, ring-opening polymerization, rac-lactide, isotactic polymers, stereoselective polymerization

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