Hemicellulose-derived chemicals: one-step production of furfuryl alcohol from xylose
Abstract
One-pot production of furfuryl alcohol via xylose dehydration followed by furfural hydrogenation was investigated over a dual catalyst system composed of Pt/SiO2 and sulfated ZrO2 as metal and acid catalysts, respectively. All samples were characterized by XRD, XRF, N2 physisorption, TG-MS and FTIR regarding their most fundamental properties for the studied process. A systematic study is reported on the effects of the reaction temperature, the composition of the binary solvent and the molar ratio between acid and metal sites in the catalyst system. The results revealed the feasibility of the one-step process for furfuryl alcohol synthesis and showed that the occurrence of both acid and metal sites is compulsory in order to promote the dehydration of xylose to furfural and its further hydrogenation to furfuryl alcohol. Selectivity towards furfuryl alcohol was found to be strongly dependent on the solvent, which can inhibit its polymerization to some extent.
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Cellulose has multiple hydroxyl groups on one long chain that form hydrogen bonds with other oxygen atoms on the neighboring chain.
“It has multiple hydroxyl groups on one long chain to form hydrogen bonds with other oxygen atoms on the neighboring chain.40”
From Sustainable hybrid photocatalysts: titania immobilized on carbon materials derived from renewable and biodegradable resources (2016) · cites this paper as [40]
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- Authors
- Perez, R. F., & Fraga, M. A.
- Affiliations
- Instituto Nacional de Tecnologia (BR)
- Corresponding author
- Fraga, Marco A.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014-07-01
- Volume
- 16
- Issue
- 8
- Pages
- 3942
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W1979894525
- Cited by
- 127
- References
- 34
- Citations by year
- 2026: 6 · 2025: 5 · 2024: 9 · 2023: 11 · 2022: 12 · 2021: 10 · 2020: 15 · 2019: 12 · 2018: 15 · 2017: 13 · 2016: 13 · 2015: 6
- FWCI
- 5.53
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Green Chemistry (publishedVersion)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Synthesis and Reactions
- Keywords
- furfuryl alcohol, xylose, furfural hydrogenation, xylose dehydration, Pt/SiO2 catalyst, sulfated zirconia, dual catalyst system, one-pot synthesis, solvent effects
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