Research progress on polyoxometalate-based transition-metal–rare-earth heterometallic derived materials: synthetic strategies, structural overview and functional applications

Hard and Soft Acids and Bases

Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475

Luminescent Functional Metal–Organic Frameworks

Cui, Y., Yue, Y., Qian, G., & Chen, B. (2012) · Chemical Reviews · doi:10.1021/cr200101d · Cited by 5,697

Heteropoly and Isopoly Oxometalates

Pope, M. T. (1983) · Inorganic chemistry concepts · doi:10.1007/978-3-662-12004-0 · Cited by 4,749

Magnetic bistability in a metal-ion cluster

Sessoli, R., Gatteschi, D., Caneschi, A., & Novak, M. A. (1993) · Nature · doi:10.1038/365141a0 · Cited by 4,307

Taking advantage of luminescent lanthanide ions

Bünzli, J.-C. G., & Piguet, C. (2005) · Chemical Society Reviews · doi:10.1039/b406082m · Cited by 3,797

Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines

Pope, M. T., & Müller, A. (1991) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199100341 · Cited by 3,645

Lanthanide luminescence for functional materials and bio-sciences

Eliseeva, S. V., & Bünzli, J.-C. G. (2010) · Chem. Soc. Rev. · doi:10.1039/b905604c · Cited by 3,538

Lanthanide-Based Luminescent Hybrid Materials

Binnemans, K. (2009) · Chemical Reviews · doi:10.1021/cr8003983 · Cited by 3,349

Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials

Gatteschi, D., & Sessoli, R. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200390099 · Cited by 2,808

Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions

Kozhevnikov, I. V. (1998) · Chemical Reviews · doi:10.1021/cr960400y · Cited by 2,758

Heterogeneous Catalysis

Mizuno, N., & Misono, M. (1998) · Chemical Reviews · doi:10.1021/cr960401q · Cited by 2,062

Introduction: PolyoxometalatesMulticomponent Molecular Vehicles To Probe Fundamental Issues and Practical Problems

Hill, C. L. (1998) · Chemical Reviews · doi:10.1021/cr960395y · Cited by 2,032

Polyoxometalates in Medicine

Rhule, J. T., Hill, C. L., Judd, D. A., & Schinazi, R. F. (1998) · Chemical Reviews · doi:10.1021/cr960396q · Cited by 1,892

Electrochemical Properties of Polyoxometalates as Electrocatalysts

Sadakane, M., & Steckhan, E. (1998) · Chemical Reviews · doi:10.1021/cr960403a · Cited by 1,706

Catalytic Chemistry of Heteropoly Compounds

Okuhara, T., Mizuno, N., & Misono, M. (1996) · Advances in Catalysis · doi:10.1016/s0360-0564(08)60041-3 · Cited by 1,646

Magnetism of Lanthanides in Molecular Materials with Transition-Metal Ions and Organic Radicals

Benelli, C., & Gatteschi, D. (2002) · Chemical Reviews · doi:10.1021/cr010303r · Cited by 1,600

Homogeneous catalysis by transition metal oxygen anion clusters

Hill, C. L., & Prosser-McCartha, C. M. (1995) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(95)01141-b · Cited by 1,454

Polyoxometalate-Based Molecular Materials

Coronado, E., & Gómez-García, C. J. (1998) · Chemical Reviews · doi:10.1021/cr970471c · Cited by 1,013

Design of luminescent lanthanide complexes: From molecules to highly efficient photo-emitting materials

Armelao, L., Quici, S., Barigelletti, F., Accorsi, G., Bottaro, G., Cavazzini, M., & Tondello, E. (2010) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2009.07.025 · Cited by 978

Engineering polyoxometalates with emergent properties

Miras, H. N., Yan, J., Long, D.-L., & Cronin, L. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35190k · Cited by 969

Highly Stable Crystalline Catalysts Based on a Microporous Metal−Organic Framework and Polyoxometalates

Sun, C.-Y., Liu, S.-X., Liang, D.-D., Shao, K.-Z., Ren, Y.-H., & Su, Z.-M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja807357r · Cited by 962

Mononuclear Lanthanide Single-Molecule Magnets Based on Polyoxometalates

AlDamen, M. A., Clemente-Juan, J. M., Coronado, E., Martí-Gastaldo, C., & Gaita-Ariño, A. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801659m · Cited by 863

The Role of Hydrothermal Synthesis in Preparative Chemistry

Rabenau, A. (1985) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198510261 · Cited by 853

Near-infrared Emission of Redispersible Er3+, Nd3+, and Ho3+ Doped LaF3 Nanoparticles

Stouwdam, J. W., & van Veggel, F. C. J. M. (2002) · Nano Letters · doi:10.1021/nl025562q · Cited by 800

Polyoxometalate water oxidation catalysts and the production of green fuel

Lv, H., Geletii, Y. V., Zhao, C., Vickers, J. W., Zhu, G., Luo, Z., Song, J., Lian, T., Musaev, D. G., & Hill, C. L. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35292c · Cited by 775

Main-Group Element, Organic, and Organometallic Derivatives of Polyoxometalates

Gouzerh, P., & Proust, A. (1998) · Chemical Reviews · doi:10.1021/cr960393d · Cited by 761

The structure and formula of 12-phosphotungstic acid

Keggin, J. F. (1934) · Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character · doi:10.1098/rspa.1934.0035 · Cited by 624

Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9− and [Ln(β2-SiW11O39)2]13−(LnIII = Tb, Dy, Ho, Er, Tm, and Yb)

AlDamen, M. A., Cardona-Serra, S., Clemente-Juan, J. M., Coronado, E., Gaita-Ariño, A., Martí-Gastaldo, C., Luis, F., & Montero, O. (2009) · Inorganic Chemistry · doi:10.1021/ic801630z · Cited by 502

Chimie Douce Approaches to the Synthesis of Metastable Oxide Materials

Gopalakrishnan, J. (1995) · Chemistry of Materials · doi:10.1021/cm00055a001 · Cited by 488

Present General Status of Understanding of Heteropoly Electrolytes and a Tracing of Some Major Highlights in the History of Their Elucidation

Baker, L. C. W., & Glick, D. C. (1998) · Chemical Reviews · doi:10.1021/cr960392l · Cited by 419

Homogeneous-Phase Electron-Transfer Reactions of Polyoxometalates

Weinstock, I. A. (1998) · Chemical Reviews · doi:10.1021/cr9703414 · Cited by 372

Photosensitized Degradation of Dyes in Polyoxometalate Solutions Versus TiO2 Dispersions under Visible‐Light Irradiation: Mechanistic Implications

Chen, C., Zhao, W., Lei, P., Zhao, J., & Serpone, N. (2004) · Chemistry – A European Journal · doi:10.1002/chem.200305453 · Cited by 303

An Exceptionally Fast Homogeneous Carbon-Free Cobalt-Based Water Oxidation Catalyst

Lv, H., Song, J., Geletii, Y. V., Vickers, J. W., Sumliner, J. M., Musaev, D. G., Kögerler, P., Zhuk, P. F., Bacsa, J., Zhu, G., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5045488 · Cited by 288

Zeolitic Polyoxometalate-Based Metal−Organic Frameworks (Z-POMOFs): Computational Evaluation of Hypothetical Polymorphs and the Successful Targeted Synthesis of the Redox-Active Z-POMOF1

Marleny Rodriguez-Albelo, L., Ruiz-Salvador, A. R., Sampieri, A., Lewis, D. W., Gómez, A., Nohra, B., Mialane, P., Marrot, J., Sécheresse, F., Mellot-Draznieks, C., et al. (2009) · Journal of the American Chemical Society · doi:10.1021/ja905009e · Cited by 279

Rare Earth Coordination Chemistry: Fundamentals and Applications

Huang, C.-H. (2010) · Cited by 264

New Strategies for the Generation of Large Heteropolymetalate Clusters: The β‐B‐SbW9 Fragment as a Multifunctional Unit

Bösing, M., Loose, I., Pohlmann, H., & Krebs, B. (1997) · Chemistry – A European Journal · doi:10.1002/chem.19970030810 · Cited by 262

Polyoxometalate-decorated nanoparticles

Wang, Y., & Weinstock, I. A. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35126a · Cited by 254

Stabilization and immobilization of polyoxometalates in porous coordination polymers through host–guest interactions

Yu, R., Kuang, X.-F., Wu, X.-Y., Lu, C.-Z., & Donahue, J. P. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2009.07.003 · Cited by 247

Lanthanoid Single-Ion Magnets Based on Polyoxometalates with a 5-fold Symmetry: The Series [LnP5W30O110]12– (Ln3+ = Tb, Dy, Ho, Er, Tm, and Yb)

Cardona-Serra, S., Clemente-Juan, J. M., Coronado, E., Gaita-Ariño, A., Camón, A., Evangelisti, M., Luis, F., Martínez-Pérez, M. J., & Sesé, J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305163t · Cited by 246

Chiral polyoxometalate-based materials: From design syntheses to functional applications

Du, D.-Y., Yan, L.-K., Su, Z.-M., Li, S.-L., Lan, Y.-Q., & Wang, E.-B. (2013) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.10.004 · Cited by 235

Polyoxometalates containing late transition and noble metal atoms

Putaj, P., & Lefebvre, F. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2011.01.030 · Cited by 217

A Large, Novel Polyoxotungstate: [AsW65O217(H2O)7]26−

Kortz, U., Savelieff, M. G., Bassil, B. S., & Dickman, M. H. (2001) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20010917)40:18<3384::aid-anie3384>3.0.co;2-o · Cited by 186

Highly Efficient Extraction and Oxidative Desulfurization System Using Na7H2LaW10O36⋅32 H2O in [bmim]BF4 at Room Temperature

Xu, J., Zhao, S., Chen, W., Wang, M., & Song, Y. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201102754 · Cited by 156

PO43−‐Mediated Polyoxometalate Supercluster Assembly

Fang, X., & Kögerler, P. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200802491 · Cited by 144

A Family of 3d-4f Octa-Nuclear [MnIII4LnIII4] Wheels (Ln = Sm, Gd, Tb, Dy, Ho, Er, and Y): Synthesis, Structure, and Magnetism

Li, M., Lan, Y., Ako, A. M., Wernsdorfer, W., Anson, C. E., Buth, G., Powell, A. K., Wang, Z., & Gao, S. W. (2010) · Inorganic Chemistry · doi:10.1021/ic101754g · Cited by 138

Solid state coordination chemistry: two-dimensional oxides constructed from polyoxomolybdate clusters and copper–organoamine subunits

Hagrman, D., Sangregorio, C., O’Connor, C. J., & Zubieta, J. A. (1998) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/a806234j · Cited by 131

Utilizing the Adaptive Polyoxometalate [As2W19O67(H2O)]14– To Support a Polynuclear Lanthanoid-Based Single-Molecule Magnet

Ritchie, C., Speldrich, M., Gable, R. W., Sorace, L., Kögerler, P., & Boskovic, C. (2011) · Inorganic Chemistry · doi:10.1021/ic200366a · Cited by 121

Transition metal ion-substituted polyoxometalates entrapped in polypyrrole as an electrochemical sensor for hydrogen peroxide

Anwar, N., Vagin, M. Y., Laffir, F. R., Armstrong, G., Dickinson, C., & McCormac∥, T. (2011) · The Analyst · doi:10.1039/c1an15665a · Cited by 64

A new series of lanthanoid containing Keggin-type germanotungstates with acetate chelators: [{Ln(CH3COO)GeW11O39(H2O)}2]12− {Ln=EuIII, GdIII, TbIII, DyIII, HoIII, ErIII, TmIII, and YbIII}

Hussain, F., Sandriesser, S., Speldrich, M., & Patzke, G. R. (2010) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2010.11.005 · Cited by 23

Beyond Charge Balance: Counter‐Cations in Polyoxometalate Chemistry

Misra, A., Kozma, K., Streb, C., & Nyman, M. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201905600 · Cited by 482