In situ X-ray pair distribution function analysis of accelerated carbonation of a synthetic calcium–silicate–hydrate gel
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The kinetics of reaction and the local atomic structure of carbonating C–S–H gel are characterised using high-energy synchrotron radiation.
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Although differential PDF traces do not unequivocally demonstrate the existence of amorphous silica, the atomic correlations are fully in line with its presence as previously reported for carbonation of a Portland cement paste.
“In any case, although the differential PDF traces do not allow us to unequivocally demonstrate the existence of amorphous silica, the atomic correlations are fully in line with its presence as previously reported for the carbonation of a Portland cement paste [13,56].”
From X-ray Total Scattering Study of Phases Formed from Cement Phases Carbonation (2021) · cites this paper as [13]
Both low and high Mg carbonated AAS samples show peaks between 3-4 Å in aluminosilica gel voxels not observed in the fumed silica reference, likely due to additional phases in the voxels.
“Both samples show peaks between 3–4 Å not observed in the reference, likely due to the presence of additional phases in the voxels, given that the Ca–T and Ca–Ca peak position at 3.65 Å is present, and some calcium carbonate phases possess Ca–Ca contributions in this region68.”
From Spatially resolved nanostructural analysis of disordered phases in carbonated alkali-activated slag (2025) · cites this paper as [68]
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Natali, M. E., White, C. E., & Bignozzi, M. C. (2016) · Fuel · doi:10.1016/j.fuel.2016.03.017 · Cited by 23 · see citing works
Self-citationDetermination of atomistic deformation of tricalcium silicate paste with high‐volume fly ash
Jee, H., Im, S., Kanematsu, M., Suzuki, H., Morooka, S., Taku, K., Machida, A., & Bae, S. (2020) · Journal of the American Ceramic Society · doi:10.1111/jace.17404 · Cited by 23 · see citing works
Ma, Y., Jacques, D., Jin, M., Ding, S., Liu, Z., Liu, S., Zhang, J., Guan, Q., Zeng, H., Zhao, H., et al. (2026) · Cement and Concrete Composites · doi:10.1016/j.cemconcomp.2026.106551 · Cited by 22 · see citing works
Claret, F., Grangeon, S., Loschetter, A., Tournassat, C., Nolf, W. D., Harker, N., Boulahya, F., Gaboreau, S., Linard, Y., Bourbon, X., et al. (2018) · IUCrJ · doi:10.1107/s205225251701836x · Cited by 22 · see citing works
Rekhtina, M., Pozzo, A. D., Stoian, D. C., Armutlulu, A., Donat, F., Blanco, M. V., Wang, Z., Willinger, M., Fedorov, A., Abdala, P. M., et al. (2020) · Nanoscale · doi:10.1039/d0nr01760d · Cited by 22 · see citing works
Gong, K., & White, C. E. (2022) · Cement and Concrete Research · doi:10.1016/j.cemconres.2021.106642 · Cited by 21 · see citing works
Self-citationStructure and properties of clay ceramics for thermal energy storage
Nigay, P., Nzihou, A., White, C. E., & Soboyejo, W. O. (2017) · Journal of the American Ceramic Society · doi:10.1111/jace.15014 · Cited by 20 · see citing works
Self-citationSystematic review of physical, mechanical and durability performances of metakaolin concrete
Geu, M. J., Zhuge, Y., Ma, X., & Pham, T. M. (2025) · Applied Clay Science · doi:10.1016/j.clay.2025.108048 · Cited by 18 · see citing works
Caneda‐Martínez, L., Frı́as, M., Sánchez-Montero, J., Rebolledo, N., Flores, E., & Medina, C. (2022) · Cement and Concrete Composites · doi:10.1016/j.cemconcomp.2022.104608 · Cited by 18 · see citing works
Chloride ion binding in cementitious materials: A review of influencing factors and control methods
Lv, J., Li, D., Yang, X., Rong, H., Xian, C., Zhang, Z., Huang, W., & Li, S. (2025) · Case Studies in Construction Materials · doi:10.1016/j.cscm.2024.e04201 · Cited by 18 · see citing works
Davolio, M., Muciaccia, G., & Ferrara, L. (2025) · Cleaner Materials · doi:10.1016/j.clema.2025.100292 · Cited by 18 · see citing works
Cao, H., Liang, Z., Peng, X., Cai, X., Wang, K., Wang, H., & Lyu, Z. (2022) · Coatings · doi:10.3390/coatings12020209 · Cited by 18 · see citing works
Elahpour, N., Niesner, I. C. C., Bossard, C., Abdellaoui, N., Montouillout, V., Fayon, F., Taviot‐Guého, C., Frankenbach-Désor, T., Crispin, A., Khosravani, P., et al. (2023) · Cells · doi:10.3390/cells12131759 · Cited by 15 · see citing works
X-ray Total Scattering Study of Phases Formed from Cement Phases Carbonation
Cuesta, A., De la Torre, A. G., & Aranda, M. A. G. (2021) · Minerals · doi:10.3390/min11050519 · Cited by 14 · see citing works
“In a second work from the same authors [13], in situ PDF was also employed to investigate the changes during the accelerated carbonation of synthetic C-S-H gel.”
BackgroundResultResearch progress on carbon dioxide curing of cementitious materials: a review
Xie, F., Zhou, D., & Zhang, M. (2025) · Canadian Journal of Civil Engineering · doi:10.1139/cjce-2024-0425 · Cited by 14 · see citing works
Valorisation of Recycled Cement Paste: Feasibility of a Short-Duration Carbonation Process
Silva, A., Nogueira, R., Bogas, J. A., Abrantes, J. C. C., Wawrzyńczak, D., Ściubidło, A., & Majchrzak‐Kucęba, I. (2022) · Materials · doi:10.3390/ma15176001 · Cited by 14 · see citing works
Zanovello, M., John, V. M., White, C. E., & Angulo, S. C. (2024) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.4c06567 · Cited by 13 · see citing works
Self-citationLocal structure determination using total scattering data
Billinge, S. J. L., Skjærvø, S. H., Terban, M. W., Tao, S., Yang, L., Rakita, Y., & Frandsen, B. A. (2021) · Elsevier eBooks · doi:10.1016/b978-0-12-823144-9.00040-6 · Cited by 13 · see citing works
Liao, H., Ju, Y., Lyu, H., Liu, T., Han, D., & Li, Y. (2024) · Developments in the Built Environment · doi:10.1016/j.dibe.2024.100397 · Cited by 10 · see citing works
Bernal, I. M. R., Aranda, M. Á. G., Santacruz, I., la Torre, Á. G. D., & Cuesta, A. (2022) · Journal of Sustainable Cement-Based Materials · doi:10.1080/21650373.2022.2117248 · Cited by 9 · see citing works
Utilizing Ground Granulated Blast Furnace Slag during Carbon Sequestration in Concrete
Saikia, S. K., Rajput, A. S., & Saini, K. (2024) · Journal of Materials in Civil Engineering · doi:10.1061/jmcee7.mteng-18542 · Cited by 9 · see citing works
Controlled Metal Oxide and Porous Carbon Templation Using Metal-Organic Frameworks
Day, G. S., Drake, H. F., Contreras‐Ramirez, A., Ryder, M. R., Page, K. L., & Zhou, H.-C. “. (2021) · Crystal Growth & Design · doi:10.1021/acs.cgd.0c01596 · Cited by 8 · see citing works
Glawe, C., & Raupach, M. (2024) · Magazine of Concrete Research · doi:10.1680/jmacr.24.00026 · Cited by 8 · see citing works
Kole, K. K., Gautham, S., Khan, P., Dey, N., Dasgupta, K., Mandal, A. K., Anoop, M. B., Ghosh, J., & Sasmal, S. (2024) · Journal of Building Engineering · doi:10.1016/j.jobe.2024.110804 · Cited by 8 · see citing works
Synchrotron pair distribution function analyses of ye’elimite-based pastes
Cuesta, A., Zea-Garcia, J. D., De la Torre, A. G., Santacruz, I., & Aranda, M. A. G. (2019) · Advances in Cement Research · doi:10.1680/jadcr.18.00097 · Cited by 7 · see citing works
Surface treatment of inorganic modifier for improving carbonation resistance of geopolymers
Li, X., & Li, Z. (2023) · Construction and Building Materials · doi:10.1016/j.conbuildmat.2023.132748 · Cited by 7 · see citing works
Spatially resolved nanostructural analysis of disordered phases in carbonated alkali-activated slag
McCaslin, E. R., James, M. C., Almer, J., Cai, Z., Kenesei, P., Park, J.-S., & White, C. E. (2025) · Nature Communications · doi:10.1038/s41467-025-67179-5 · Cited by 6 · see citing works
“T and Ca – Ca peak position at 3.65Å is present, and some calcium carbonate phases possess Ca – Ca contributions in this region 68 .”
Self-citationEffect of fly ash on the atomic scale structure of C–S–H during Portland cement hydration
Kole, K. K., Gautham, S., Khan, P., Biswas, R. K., Dasgupta, K., Mandal, A. K., Anoop, M. B., Ghosh, J., & Sasmal, S. (2023) · Magazine of Concrete Research · doi:10.1680/jmacr.22.00327 · Cited by 6 · see citing works
Strength Recovery of Thermally Damaged High-Performance Concrete during Recuring
Li, Y., Wang, H., & Lou, H. (2024) · Materials · doi:10.3390/ma17143531 · Cited by 6 · see citing works
Durability of concrete prepared with low-carbon binders: Perspectives and insights
Machner, A., Suraneni, P., WEERDT, K. D., Krüger, M. E., Wilson, W., & Isgor, O. B. (2026) · Cement and Concrete Research · doi:10.1016/j.cemconres.2026.108273 · Cited by 5 · see citing works
Alventosa, K. M. L., & White, C. E. (2024) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.3c06653 · Cited by 5 · see citing works
Self-citationQoku, E., Reuschle, D. A., Fitzgibbons, T. C., Wilkinson, A. P., & Kurtis, K. E. (2025) · Cement and Concrete Research · doi:10.1016/j.cemconres.2025.107915 · Cited by 4 · see citing works
Insights into the nano- and microstructures of cementitious materials using synchrotron X-rays
Aranda, M. Á. G., la Torre, Á. G. D., Bernal, S. A., & Provis, J. L. (2026) · Cement and Concrete Research · doi:10.1016/j.cemconres.2026.108150 · Cited by 4 · see citing works
Exploration of the Composition and Microstructure of the Historic Concrete Material in Shanghai
Du, Q., Li, Y., Qiu, B., Ren, L., & He, X. (2024) · International Journal of Architectural Heritage · doi:10.1080/15583058.2024.2429609 · Cited by 3 · see citing works
Cagnon, B., Gin, S., Cabié, M., & Daval, D. (2024) · Journal of Nuclear Materials · doi:10.1016/j.jnucmat.2024.155426 · Cited by 2 · see citing works
Concrete Carbonation of Deep Burial Storage Constructions under Model Aging Conditions
Medvedev, V., Pustovgar, A. P., Олегович, А. А., & Adamtsevich, L. (2023) · Buildings · doi:10.3390/buildings14010008 · Cited by 2 · see citing works
Accumulators for the Capture of Heavy Metals in Thermal Conversion Systems
Nigay, P., Nzihou, A., White, C. E., & Soboyejo, W. O. (2018) · Journal of Environmental Engineering · doi:10.1061/(asce)ee.1943-7870.0001469 · Cited by 2 · see citing works
Self-citationReliability of pair distribution function analysis in in situ experiments
Stubkjær, R. B., Kløve, M. N., Bertelsen, A. D., Borup, A. B., Roelsgaard, M., & Iversen, B. B. (2025) · Journal of Applied Crystallography · doi:10.1107/s1600576725001694 · Cited by 1 · see citing works
Jee, H., & Garg, N. (2026) · Journal of Synchrotron Radiation · doi:10.1107/s1600577526006776 · Cited by 1 · see citing works
In situ scattering studies of material formation during wet-chemical syntheses
Skjærvø, S. L., Juelsholt, M., & Jensen, K. M. Ø. (2021) · Elsevier eBooks · doi:10.1016/b978-0-12-823144-9.00023-6 · Cited by 1 · see citing works
Carbonation of cement-based construction waste
Mohamed, A. O., Gamal, M. M. E., Hameedi, S. M., & Paleologos, E. K. (2023) · Elsevier eBooks · doi:10.1016/b978-0-12-823418-1.00004-4 · Cited by 1 · see citing works
Zhao, P., Duan, H., Zhang, Y., Shen, Y., Li, X., Shen, H., Zhu, W., Liu, G., & Pang, B. (2024) · Case Studies in Construction Materials · doi:10.1016/j.cscm.2024.e04055 · Cited by 1 · see citing works
Molecular Dynamics Simulation of Structural Properties of Hydrated Tobermorite
Abzaev, Y. A., Korobkov, S. V., & Gnyrya, A. I. (2023) · Materials science forum · doi:10.4028/p-29j3w2 · Cited by 1 · see citing works
- Authors
- Morandeau, A. E., & White, C. E.
- Affiliations
- Princeton University (US)
- Corresponding author
- White, Claire E.
- ORCID
- White, Claire E.
- Venue
- Journal of Materials Chemistry A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2015
- Volume
- 3
- Issue
- 16
- Pages
- 8597-8605
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W2082957664
- Cited by
- 107
- References
- 43
- Citations by year
- 2026: 8 · 2025: 7 · 2024: 14 · 2023: 13 · 2022: 13 · 2021: 14 · 2020: 7 · 2019: 6 · 2018: 10 · 2017: 8 · 2016: 6 · 2015: 1
- FWCI
- 13.78
- Type
- journal article
- Language
- en
- Open access
- green
- www.osti.gov
- Locations
- Journal of Materials Chemistry A (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- Royal Society
- Royal Society of Chemistry
- Office of Science
- Argonne National Laboratory
- Topics
- Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Keywords
- carbonation, calcium silicate hydrate, accelerated carbonation, reaction kinetics, local atomic structure, high-energy synchrotron radiation, cement hydration products
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