Cited by 108Concrete and Cement Materials ResearchCO2 Sequestration and Geologic InteractionsCalcium Carbonate Crystallization and Inhibition

In situ X-ray pair distribution function analysis of accelerated carbonation of a synthetic calcium–silicate–hydrate gel

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Morandeau, Antoine E., White, Claire E.·2015·Journal of Materials Chemistry A

Abstract

The kinetics of reaction and the local atomic structure of carbonating C–S–H gel are characterised using high-energy synchrotron radiation.

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Crossref · 10.1039/c5ta00348b

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43 of 43 references verified0 citation errors · 0 not checkable

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  • Although differential PDF traces do not unequivocally demonstrate the existence of amorphous silica, the atomic correlations are fully in line with its presence as previously reported for carbonation of a Portland cement paste.

    “In any case, although the differential PDF traces do not allow us to unequivocally demonstrate the existence of amorphous silica, the atomic correlations are fully in line with its presence as previously reported for the carbonation of a Portland cement paste [13,56].”
  • Both low and high Mg carbonated AAS samples show peaks between 3-4 Å in aluminosilica gel voxels not observed in the fumed silica reference, likely due to additional phases in the voxels.

    “Both samples show peaks between 3–4 Å not observed in the reference, likely due to the presence of additional phases in the voxels, given that the Ca–T and Ca–Ca peak position at 3.65 Å is present, and some calcium carbonate phases possess Ca–Ca contributions in this region68.”

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Authors
Morandeau, A. E., & White, C. E.
Affiliations
Princeton University (US)
Corresponding author
White, Claire E.
Venue
Journal of Materials Chemistry A
Published
2015
Volume
3
Issue
16
Pages
8597-8605
ISSN
  • 2050-7488 (ISSN-L)
  • 2050-7496
OpenAlex
W2082957664
Cited by
107
References
43
Citations by year
2026: 8 · 2025: 7 · 2024: 14 · 2023: 13 · 2022: 13 · 2021: 14 · 2020: 7 · 2019: 6 · 2018: 10 · 2017: 8 · 2016: 6 · 2015: 1
FWCI
13.78
Type
journal article
Language
en
Open access
Locations
  • Journal of Materials Chemistry A (publishedVersion)
  • OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
Funders
  • Royal Society
  • Royal Society of Chemistry
  • Office of Science
  • Argonne National Laboratory
Topics
  • Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
  • Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
  • Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
Keywords
carbonation, calcium silicate hydrate, accelerated carbonation, reaction kinetics, local atomic structure, high-energy synchrotron radiation, cement hydration products

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