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Porphyrin based push–pull conjugates as donors for solution-processed bulk heterojunction solar cells: a case of metal-dependent power conversion efficiency
Abstract
We demonstrate here the effect of metals in the porphyrin core of a PBI–porphyrin conjugate on the power conversion efficiency.
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PCE values for C24(Ni), C25(Cu) and C26(Zn) were 4.51%, 5.42% and 6.18%, with Jsc of 9.34, 10.13 and 12.25 mA cm−2, respectively.
“The PCE values were found to be 4.51%, 5.42% and 6.18% with a J sc of 9.34 mA cm 2 , 10.13 mA cm 2 and 12.25 mA cm 2 , respectively, for C24 (Ni), C25 (Cu) and C26 (Zn).”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [79]
The C26(Zn)-based device showed a relatively lower Voc due to its high-lying HOMO.
“However, the C26 (Zn) based device showed a relatively lower V oc due to its high-lying HOMO.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [79]
All devices showed similar electron mobility, but the C26(Zn)-based device showed a higher hole mobility compared to the others.
“All devices showed similar electronmobility, but the C26 (Zn) based device showed a higher holemobility compared to the others.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [79]
Low energy loss is another promising feature of C26(Zn).
“Low energy loss is another promising feature of C26 (Zn).”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [79]
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A–π–D–π–A based porphyrin for solution processed small molecule bulk heterojunction solar cells
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Cited by
Sorted by citations
Recent progress in porphyrin-based materials for organic solar cells
Mahmood, A., Hu, J.-Y., Xiao, B., Tang, A., Wang, X., & Zhou, E. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06392c · Cited by 311
Metadata
- Authors
- Mishra, R., Regar, R., Singhal, R., Panini, P., Sharma, G. D., & Sankar, J.
- Affiliations
- Indian Institute of Science Education and Research, Bhopal (IN)
- Malaviya National Institute of Technology Jaipur (IN)
- LNM Institute of Information Technology (IN)
- Corresponding author
- Sharma, Ganesh D.
- Sankar, Jeyaraman
- Venue
- Journal of Materials Chemistry A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2017
- Volume
- 5
- Issue
- 30
- Pages
- 15529-15533
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W2734451626
- Cited by
- 27
- References
- 4
- Citations by year
- 2025: 4 · 2024: 1 · 2023: 3 · 2022: 1 · 2021: 3 · 2020: 2 · 2019: 9 · 2018: 4
- FWCI
- 1.71
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry A (publishedVersion)
- Funders
- Science and Engineering Research Board (EMR/2016/005768)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
- Keywords
- porphyrins, donor materials, bulk heterojunction solar cells, solution-processed solar cells, metal substitution, power conversion efficiency
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