Approaches for measuring the surface areas of metal oxide electrocatalysts for determining their intrinsic electrocatalytic activity

What are batteries, fuel cells, and supercapacitors?

Winter, M., & Brodd, R. J. (2004) · Chemical Reviews · doi:10.1021/cr020730k · Cited by 7,389

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction

McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026

A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles

Suntivich, J., May, K. J., Gasteiger, H. A., Goodenough, J. B., & Shao-Horn, Y. (2011) · Science · doi:10.1126/science.1212858 · Cited by 5,441

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices

McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145

Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation

Trotochaud, L., Young, S. L., Ranney, J. K., & Boettcher, S. W. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502379c · Cited by 3,588

Synthesis and Activities of Rutile IrO2 and RuO2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions

Lee, Y., Suntivich, J., May, K. J., Perry, E. E., & Shao-Horn, Y. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz2016507 · Cited by 3,534

Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries

Suntivich, J., Gasteiger, H. A., Yabuuchi, N., Nakanishi, H., Goodenough, J. B., & Shao-Horn, Y. (2011) · Nature Chemistry · doi:10.1038/nchem.1069 · Cited by 2,904

Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution

Grimaud, A., Diaz-Morales, O., Han, B., Hong, W. T., Lee, Y.-L., Giordano, L., Stoerzinger, K. A., Koper, M. T. M., & Shao-Horn, Y. (2017) · Nature Chemistry · doi:10.1038/nchem.2695 · Cited by 2,530

A highly active and stable IrO x /SrIrO 3 catalyst for the oxygen evolution reaction

Seitz, L. C., Dickens, C. F., Nishio, K., Hikita, Y., Montoya, J., Doyle, A., Kirk, C., Vojvodic, A., Hwang, H. Y., Norskov, J. K., et al. (2016) · Science · doi:10.1126/science.aaf5050 · Cited by 2,196

Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis

Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089

Real surface area measurements in electrochemistry

Trasatti, S., & Petrii, O. A. (1991) · Pure and Applied Chemistry · doi:10.1351/pac199163050711 · Cited by 1,832

Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution

Grimaud, A., May, K. J., Carlton, C. E., Lee, Y.-L., Risch, M., Hong, W. T., Zhou, J., & Shao-Horn, Y. (2013) · Nature Communications · doi:10.1038/ncomms3439 · Cited by 1,629

A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation

Gorlin, Y., & Jaramillo, T. F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104587v · Cited by 1,566

Materials for solar fuels and chemicals

Montoya, J. H., Seitz, L. C., Chakthranont, P., Vojvodic, A., Jaramillo, T. F., & Nørskov, J. K. (2017) · Nature Materials · doi:10.1038/nmat4778 · Cited by 1,566

Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution

Trotochaud, L., Ranney, J. K., Williams, K. N., & Boettcher, S. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja307507a · Cited by 1,548

Instability of Pt∕C Electrocatalysts in Proton Exchange Membrane Fuel Cells

Ferreira, P. J., la O’, G. J., Shao-Horn, Y., Morgan, D., Makharia, R., Kocha, S., & Gasteiger, H. A. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.2050347 · Cited by 1,491

Just a Dream—or Future Reality?

Gasteiger, H. A., & Marković, N. M. (2009) · Science · doi:10.1126/science.1172083 · Cited by 1,477

Recommended Practices and Benchmark Activity for Hydrogen and Oxygen Electrocatalysis in Water Splitting and Fuel Cells

Wei, C., Rao, R. R., Peng, J., Huang, B., Stephens, I. E. L., Risch, M., Xu, Z. J., & Shao‐Horn, Y. (2019) · Advanced Materials · doi:10.1002/adma.201806296 · Cited by 1,364

Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces

Sheng, W., Myint, M., Chen, J. G., & Yan, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00045a · Cited by 1,202

Understanding the electrocatalysis of oxygen reduction on platinum and its alloys

Stephens, I. E. L., Bondarenko, A. S., Grønbjerg, U., Rossmeisl, J., & Chorkendorff, I. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03590a · Cited by 1,176

Characterization of High‐Surface‐Area Electrocatalysts Using a Rotating Disk Electrode Configuration

Schmidt, T. J., Gasteiger, H. A., Stäb, G. D., Urban, P. M., Kolb, D. M., & Behm, R. J. (1998) · Journal of The Electrochemical Society · doi:10.1149/1.1838642 · Cited by 1,131

Underpotential Deposition at Single Crystal Surfaces of Au, Pt, Ag and Other Materials

Herrero, E., Buller, L. J., & Abruña, H. D. (2001) · Chemical Reviews · doi:10.1021/cr9600363 · Cited by 934

Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy

Zheng, J., Sheng, W., Zhuang, Z., Xu, B., & Yan, Y. (2016) · Science Advances · doi:10.1126/sciadv.1501602 · Cited by 863

Cations in Octahedral Sites: A Descriptor for Oxygen Electrocatalysis on Transition‐Metal Spinels

Wei, C., Feng, Z., Scherer, G. G., Barber, J., Shao‐Horn, Y., & Xu, Z. J. (2017) · Advanced Materials · doi:10.1002/adma.201606800 · Cited by 810

Benchmarking nanoparticulate metal oxide electrocatalysts for the alkaline water oxidation reaction

Jung, S., McCrory, C. C. L., Ferrer, I. M., Peters, J. C., & Jaramillo, T. F. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta07586f · Cited by 600

Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides

Hong, W. T., Stoerzinger, K. A., Lee, Y.-L., Giordano, L., Grimaud, A., Johnson, A. M., Hwang, J., Crumlin, E. J., Yang, W., & Shao-Horn, Y. (2017) · Energy & Environmental Science · doi:10.1039/c7ee02052j · Cited by 599

Measurement Techniques for the Study of Thin Film Heterogeneous Water Oxidation Electrocatalysts

Stevens, M. B., Enman, L. J., Batchellor, A. S., Cosby, M. R., Vise, A. E., Trang, C. D. M., & Boettcher, S. W. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02796 · Cited by 586

Orientation-Dependent Oxygen Evolution Activities of Rutile IrO2and RuO2

Stoerzinger, K. A., Qiao, L., Biegalski, M. D., & Shao-Horn, Y. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz500610u · Cited by 582

Covalency-reinforced oxygen evolution reaction catalyst

Yagi, S., Yamada, I., Tsukasaki, H., Seno, A., Murakami, M., Fujii, H., Chen, H., Umezawa, N., Abe, H., Nishiyama, N., et al. (2015) · Nature Communications · doi:10.1038/ncomms9249 · Cited by 545

Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition

Zhou, S., Miao, X., Zhao, X., Ma, C., Qiu, Y., Hu, Z., Zhao, J., Shi, L., & Zeng, J. (2016) · Nature Communications · doi:10.1038/ncomms11510 · Cited by 508

Electrochemical Methods of Real Surface Area Determination of Noble Metal Electrodes – an Overview

Łukaszewski, M., Soszko, M., & Czerwiński, A. (2016) · International Journal of Electrochemical Science · doi:10.20964/2016.06.71 · Cited by 476

Recent Insights into Manganese Oxides in Catalyzing Oxygen Reduction Kinetics

Stoerzinger, K. A., Risch, M., Han, B., & Shao-Horn, Y. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01444 · Cited by 440

Determination of the Platinum and Ruthenium Surface Areas in Platinum−Ruthenium Alloy Electrocatalysts by Underpotential Deposition of Copper. I. Unsupported Catalysts

Green, C. L., & Kucernak, A. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0131931 · Cited by 423

The Effect of Size on the Oxygen Electroreduction Activity of Mass‐Selected Platinum Nanoparticles

Perez‐Alonso, F. J., McCarthy, D. N., Nierhoff, A., Hernandez‐Fernandez, P., Strebel, C., Stephens, I. E. L., Nielsen, J. H., & Chorkendorff, I. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201200586 · Cited by 388

Impact of Surface Area in Evaluation of Catalyst Activity

Sun, S., Li, H., & Xu, Z. J. (2018) · Joule · doi:10.1016/j.joule.2018.05.003 · Cited by 360

Optimizing nanoparticle perovskite for bifunctional oxygen electrocatalysis

Jung, J.-I., Risch, M., Park, S., Kim, M. G., Nam, G., Jeong, H.-Y., Shao-Horn, Y., & Cho, J. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03124a · Cited by 338

The Comprehensive Understanding of as an Evaluation Parameter for Electrochemical Water Splitting

Wei, C., & Xu, Z. J. (2018) · Small Methods · doi:10.1002/smtd.201800168 · Cited by 290

Pt5Gd as a Highly Active and Stable Catalyst for Oxygen Electroreduction

Escudero-Escribano, M., Verdaguer-Casadevall, A., Malacrida, P., Grønbjerg, U., Knudsen, B. P., Jepsen, A. K., Rossmeisl, J., Stephens, I. E. L., & Chorkendorff, I. (2012) · Journal of the American Chemical Society · doi:10.1021/ja306348d · Cited by 271

Suppressing Ion Transfer Enables Versatile Measurements of Electrochemical Surface Area for Intrinsic Activity Comparisons

Yoon, Y., Yan, B., & Surendranath, Y. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10966 · Cited by 225

Dual role of carbon in the catalytic layers of perovskite/carbon composites for the electrocatalytic oxygen reduction reaction

Poux, T., Napolskiy, F. S., Dintzer, T., Kéranguéven, G., Istomin, S. Y., Tsirlina, G. A., Antipov, E. V., & Savinova, E. R. (2012) · Catalysis Today · doi:10.1016/j.cattod.2012.04.046 · Cited by 195

Inverse spinel NiFeAlO4 as a highly active oxygen evolution electrocatalyst: promotion of activity by a redox-inert metal ion

Chen, J. Y. C., Miller, J. T., Gerken, J. B., & Stahl, S. S. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43811b · Cited by 186

Oxygen electrocatalysis on (001)-oriented manganese perovskite films: Mn valency and charge transfer at the nanoscale

Stoerzinger, K. A., Risch, M., Suntivich, J., Lu, W., Zhou, J., Biegalski, M. D., Christen, H. M., Ariando, A., Venkatesan, T., & Shao‐Horn, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40321a · Cited by 157

Composite Electrode Boosts the Activity of Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3-δ Perovskite and Carbon toward Oxygen Reduction in Alkaline Media

Fabbri, E., Mohamed, R., Levecque, P. B. J., Conrad, O., Kötz, R., & Schmidt, T. J. (2014) · ACS Catalysis · doi:10.1021/cs400903k · Cited by 126

Highly Active Epitaxial La(1–x)SrxMnO3 Surfaces for the Oxygen Reduction Reaction: Role of Charge Transfer

Stoerzinger, K. A., Lü, W., Li, C., et al. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b00439 · Cited by 126

Rotating Ring–Disk Electrode Study of Oxygen Evolution at a Perovskite Surface: Correlating Activity to Manganese Concentration

Scholz, J., Risch, M., Stoerzinger, K. A., Wartner, G., Shao‐Horn, Y., & Jooß, C. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b07654 · Cited by 111

Electrocatalysis of Perovskites: The Influence of Carbon on the Oxygen Evolution Activity

Mohamed, R., Cheng, X., Fabbri, E., Levecque, P. B. J., Kötz, R., Conrad, O., & Schmidt, T. J. (2015) · Journal of The Electrochemical Society · doi:10.1149/2.0861506jes · Cited by 106

Quick Determination of Electroactive Surface Area of Some Oxide Electrode Materials

Watzele, S., & Bandarenka, A. S. (2016) · Electroanalysis · doi:10.1002/elan.201600178 · Cited by 84

Revealing the Dominant Chemistry for Oxygen Reduction Reaction on Small Oxide Nanoparticles

Zhou, Y., Xi, S., Wang, J., Sun, S., Wei, C., Feng, Z., Du, Y., & Xu, Z. J. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b03864 · Cited by 72

Oxygen evolution reaction electrocatalysis on SrIrO 3 grown using molecular beam epitaxy

Tang, R., Nie, Y., Kawasaki, J. K., Kuo, D.-Y., Petretto, G., Hautier, G., Rignanese, G., Shen, K., Schlom, D. G., & Suntivich, J. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta09530a · Cited by 69

A review on fundamentals for designing oxygen evolution electrocatalysts

Song, J., Wei, C., Huang, Z.-F., Liu, C., Zeng, L., Wang, X., & Xu, Z. J. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00607a · Cited by 2,936

Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting

Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874

Electrochemical oxidation of biomass derived 5-hydroxymethylfurfural (HMF): pathway, mechanism, catalysts and coupling reactions

Yang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539

Water electrolysis

Shih, A. J., Monteiro, M. C. O., Dattila, F., Pavesi, D., Philips, M., da Silva, A. H. M., Vos, R. E., Ojha, K., Park, S., van der Heijden, O., et al. (2022) · Nature Reviews Methods Primers · doi:10.1038/s43586-022-00164-0 · Cited by 521

The Determination of Electrochemical Active Surface Area and Specific Capacity Revisited for the System MnOx as an Oxygen Evolution Catalyst

Connor, P., Schuch, J., Kaiser, B., & Jaegermann, W. (2020) · Zeitschrift für Physikalische Chemie · doi:10.1515/zpch-2019-1514 · Cited by 351