Metal-catalyzed regiodivergent organic reactions

Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides

Tornøe, C. W., Christensen, C., & Meldal, M. (2002) · The Journal of Organic Chemistry · doi:10.1021/jo011148j · Cited by 8,696

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

Lyons, T. W., & Sanford, M. S. (2010) · Chemical Reviews · doi:10.1021/cr900184e · Cited by 6,119

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

Yeung, C. S., & Dong, V. M. (2011) · Chemical Reviews · doi:10.1021/cr100280d · Cited by 3,857

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

Colby, D. A., Bergman, R. G., & Ellman, J. A. (2010) · Chemical Reviews · doi:10.1021/cr900005n · Cited by 3,682

Aryl−Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction

Hassan, J., Sévignon, M., Gozzi, C., Schulz, E., & Lemaire, M. (2002) · Chemical Reviews · doi:10.1021/cr000664r · Cited by 3,663

Asymmetric Transition-Metal-Catalyzed Allylic Alkylations: Applications in Total Synthesis

Trost, B. M., & Crawley, M. L. (2003) · Chemical Reviews · doi:10.1021/cr020027w · Cited by 2,845

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

Arockiam, P. B., Bruneau, C., & Dixneuf, P. H. (2012) · Chemical Reviews · doi:10.1021/cr300153j · Cited by 2,743

Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

Müller, T. E., Hultzsch, K. C., Yus, M., Foubelo, F., & Tada, M. (2008) · Chemical Reviews · doi:10.1021/cr0306788 · Cited by 2,090

Applied Hydroformylation

Franke, R., Selent, D., & Börner, A. (2012) · Chemical Reviews · doi:10.1021/cr3001803 · Cited by 1,668

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

Neufeldt, S. R., & Sanford, M. S. (2012) · Accounts of Chemical Research · doi:10.1021/ar300014f · Cited by 1,360

Ruthenium-Catalyzed Cycloaddition of Alkynes and Organic Azides

Zhang, L., Chen, X., Xue, P., Sun, H. H. Y., Williams, I. D., Sharpless, K. B., Fokin, V. V., & Jia, G. (2005) · Journal of the American Chemical Society · doi:10.1021/ja054114s · Cited by 1,120

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

Hartwig, J. F. (2012) · Accounts of Chemical Research · doi:10.1021/ar200206a · Cited by 1,074

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

Liu, C., Yuan, J., Gao, M., Tang, S., Li, W., Shi, R., & Lei, A. (2015) · Chemical Reviews · doi:10.1021/cr500431s · Cited by 1,060

Efficient, Selective, and Recyclable Palladium Catalysts in Carbon−Carbon Coupling Reactions

Molnár, Á. (2011) · Chemical Reviews · doi:10.1021/cr100355b · Cited by 1,042

The Catalytic Cross-Coupling of Unactivated Arenes

Stuart, D. R., & Fagnou, K. (2007) · Science · doi:10.1126/science.1141956 · Cited by 1,018

Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions

Hashimoto, T., & Maruoka, K. (2015) · Chemical Reviews · doi:10.1021/cr5007182 · Cited by 1,018

Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation

Bart, S. C., Lobkovsky, E. B., & Chirik, P. J. (2004) · Journal of the American Chemical Society · doi:10.1021/ja046753t · Cited by 843

Ruthenium-Catalyzed Azide−Alkyne Cycloaddition: Scope and Mechanism

Boren, B. C., Narayan, S., Rasmussen, L. K., Zhang, L., Zhao, H., Lin, Z., Jia, G., & Fokin, V. V. (2008) · Journal of the American Chemical Society · doi:10.1021/ja0749993 · Cited by 829

The catalytic hydroamination of alkynes

Pohlki, F., & Doye, S. (2003) · Chemical Society Reviews · doi:10.1039/b200386b · Cited by 710

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

Tondreau, A. M., Atienza, C. C. H., Weller, K. J., Nye, S. A., Lewis, K. M., Delis, J. G. P., & Chirik, P. J. (2012) · Science · doi:10.1126/science.1214451 · Cited by 556

Stereodivergent Catalysis

Beletskaya, I. P., Nájera, C., & Yus, M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00561 · Cited by 530

Catalytic Selective Synthesis

Mahatthananchai, J., Dumas, A. M., & Bode, J. W. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201201787 · Cited by 480

Catalysis by transition metal complexes of alkene silylation–recent progress and mechanistic implications

Marciniec, B. (2005) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.02.025 · Cited by 469

Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes

Gorelsky, S. I., Lapointe, D., & Fagnou, K. (2012) · The Journal of Organic Chemistry · doi:10.1021/jo202342q · Cited by 438

Mild Aerobic Oxidative Palladium (II) Catalyzed C−H Bond Functionalization: Regioselective and Switchable C−H Alkenylation and Annulation of Pyrroles

Beck, E. M., Grimster, N. P., Hatley, R., & Gaunt, M. J. (2006) · Journal of the American Chemical Society · doi:10.1021/ja058141u · Cited by 365

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

Jang, H., Zhugralin, A. R., Lee, Y., & Hoveyda, A. H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2007643 · Cited by 328

Catalytic Carbonylation Reactions

(2006) · Topics in Organometallic Chemistry · doi:10.1007/b105253 · Cited by 304

Regioselection and Enantioselection in Organolanthanide-Catalyzed Olefin Hydrosilylation. A Kinetic and Mechanistic Study

Fu, P.-F., Brard, L., Li, Y., & Marks, T. J. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00132a015 · Cited by 296

Full Selectivity Control in Cobalt(III)‐Catalyzed C−H Alkylations by Switching of the C−H Activation Mechanism

Zell, D., Bursch, M., Müller, V., Grimme, S., & Ackermann, L. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201704196 · Cited by 277

Advancements in the mechanistic understanding of the copper-catalyzed azide–alkyne cycloaddition

Berg, R., & Straub, B. F. (2013) · Beilstein Journal of Organic Chemistry · doi:10.3762/bjoc.9.308 · Cited by 240

High-Precision Catalysts: Regioselective Hydroformylation of Internal Alkenes by Encapsulated Rhodium Complexes

Kuil, M., Soltner, T., van Leeuwen, P. W. N. M., & Reek, J. N. H. (2006) · Journal of the American Chemical Society · doi:10.1021/ja063294i · Cited by 211

Palladium-Catalyzed Regio- and Enantioselective Synthesis of Allylic Amines Featuring Tetrasubstituted Tertiary Carbons

Cai, A., Guo, W., Martínez-Rodríguez, L., & Kleij, A. W. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08841 · Cited by 207

Iridium-catalyzed hydroboration of alkenes with pinacolborane

Yamamoto, Y., Fujikawa, R., Umemoto, T., & Miyaura, N. (2004) · Tetrahedron · doi:10.1016/j.tet.2004.09.014 · Cited by 200

Intermolecular Hydroamination of Terminal Alkynes Catalyzed by Organoactinide Complexes. Scope and Mechanistic Studies

Straub, T. S., Haskel, A., Gueta-Neyroud, T., Kapon, M., Botoshansky, M., & Eisen, M. S. (2001) · Organometallics · doi:10.1021/om010434i · Cited by 182

Ruthenium‐Catalyzed Cycloaddition of Nitrile Oxides and Alkynes: Practical Synthesis of Isoxazoles

Grecian, S., & Fokin, V. V. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200801920 · Cited by 180

The scope and mechanism of palladium-catalysed Markovnikov alkoxycarbonylation of alkenes

Li, H., Dong, K., Jiao, H., Neumann, H., Jackstell, R., & Beller, M. (2016) · Nature Chemistry · doi:10.1038/nchem.2586 · Cited by 180

Highly Ligand-Controlled Regioselective Pd-Catalyzed Aminocarbonylation of Styrenes with Aminophenols

Xu, T., Sha, F., & Alper, H. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b03161 · Cited by 171

Regiocontrolled Ru-catalyzed addition of carboxylic acids to alkynes: practical protocols for the synthesis of vinyl estersWe thank Prof. Dr. M. T. Reetz for generous support and constant encouragement, and gratefully acknowledge the DFG, the FCI, and the BMBF for financial support.

Gooßen, L. J., Paetzold, J., & Koley, D. (2003) · Chemical Communications · doi:10.1039/b211277a · Cited by 155

Regiodivergent Catalysis: A Powerful Tool for Selective Catalysis

Funken, N., Zhang, Y., & Gansäuer, A. (2016) · Chemistry - A European Journal · doi:10.1002/chem.201603993 · Cited by 144

Ligand‐Controlled Regiodivergent Pathways of Rhodium(III)‐Catalyzed Dihydroisoquinolone Synthesis: Experimental and Computational Studies of Different Cyclopentadienyl Ligands

Wodrich, M. D., Ye, B., Gonthier, J. F., Corminbœuf, C., & Cramer, N. (2014) · Chemistry - A European Journal · doi:10.1002/chem.201404515 · Cited by 136

Unlocking the N2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Xu, K., Thieme, N., & Breit, B. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403682 · Cited by 135

Mechanistic Origin of Ligand‐Controlled Regioselectivity in Pd‐Catalyzed CH Activation/Arylation of Thiophenes

Tang, S., Guo, Q., & Fu, Y. (2011) · Chemistry - A European Journal · doi:10.1002/chem.201101587 · Cited by 130

Ligand Steric Contours To Understand the Effects of N -Heterocyclic Carbene Ligands on the Reversal of Regioselectivity in Ni-Catalyzed Reductive Couplings of Alkynes and Aldehydes

Liu, P., Montgomery, J., & Houk, K. N. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202007s · Cited by 127

Iridium‐Catalyzed CH Activation versus Directed ortho Metalation: Complementary Borylation of Aromatics and Heteroaromatics

Hurst, T. E., Macklin, T. K., Becker, M., Hartmann, E., Kügel, W., Salle, J. P., Batsanov, A. S., Marder, T. B., & Snieckus, V. A. (2010) · Chemistry - A European Journal · doi:10.1002/chem.201000401 · Cited by 114

Pd-Catalyzed Hydroborylation of Alkynes: A Ligand Controlled Regioselectivity Switch for the Synthesis of α- or β-Vinylboronates

Ojha, D. P., & Prabhu, K. R. (2016) · Organic Letters · doi:10.1021/acs.orglett.5b03416 · Cited by 101

Regiocontrolled Palladium-Catalyzed Arylative Cyclizations of Alkynols

Fujino, D., Yorimitsu, H., & Osuka, A. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5029028 · Cited by 98

Use of organolanthanides in the catalytic intermolecular hydrophosphination and hydroamination of multiple C–C bonds

Trifonov, A. A., Basalov, I. V., & Kissel, A. A. (2016) · Dalton Transactions · doi:10.1039/c6dt03913h · Cited by 92

Ligand-Tuned Regioselectivity of a Cobalt-Catalyzed Diels−Alder Reaction. A Theoretical Study

Mörschel, P., Janikowski, J., Hilt, G., & Frenking, G. (2008) · Journal of the American Chemical Society · doi:10.1021/ja078242n · Cited by 88

Rhodium-Catalyzed Selective anti-Markovnikov Addition of Carboxylic Acids to Alkynes

Lumbroso, A., Vautravers, N. R., & Breit, B. (2010) · Organic Letters · doi:10.1021/ol102365e · Cited by 78

Switchable Reactivity of Acylated α, β-Dehydroamino Ester in the Friedel−Crafts Alkylation of Indoles by Changing the Lewis Acid

Angelini, E., Balsamini, C., Bartoccini, F., Lucarini, S., & Piersanti, G. (2008) · The Journal of Organic Chemistry · doi:10.1021/jo800881u · Cited by 76

A Highly Active and Air-Stable Ruthenium Complex for the Ambient Temperature Anti-Markovnikov Reductive Hydration of Terminal Alkynes

Zeng, M., Li, L., & Herzon, S. B. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501738a · Cited by 69

Aromatic Osmacyclopropenefuran Bicycles and Their Relevance for the Metal‐Mediated Hydration of Functionalized Allenes

Batuecas, M. T., Castro-Rodrigo, R., Esteruelas, M. A., Garcı́a-Yebra, C., López, A. M., & Oñate, E. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201606839 · Cited by 63

Selective Formation of 1,4-Disubstituted Triazoles from Ruthenium-Catalyzed Cycloaddition of Terminal Alkynes and Organic Azides: Scope and Reaction Mechanism

Liu, P. N., Li, J., Su, F., Ju, K. D., Zhang, L., Shi, C., Sung, H. H. Y., Williams, I. D., Fokin, V. V., Lin, Z., et al. (2012) · Organometallics · doi:10.1021/om300513w · Cited by 58

Carbonyl Imines from Oxaziridines: Generation and Cycloaddition of NOC Dipoles

Partridge, K. M., Guzei, I. A., & Yoon, T. P. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200905801 · Cited by 50

Solvent‐Switchable Regioselective Synthesis of Aurones and Flavones Using Palladium‐Supported Amine‐Functionalized Montmorillonite as a Heterogeneous Catalyst

Chavan, S. P., Varadwaj, G. B. B., Parida, K. M., & Bhanage, B. M. (2016) · ChemCatChem · doi:10.1002/cctc.201600549 · Cited by 34

Metal-Controlled, Regioselective, Direct Intermolecular α- or γ-Amination with Azodicarboxylates

Fu, X. H., Bai, H., Zhu, G.-D., Huang, Y., & Zhang, S. (2018) · Organic Letters · doi:10.1021/acs.orglett.8b01183 · Cited by 29

Hydroelementation of Unsaturated C–C Bonds Catalyzed by Metal Scorpionate Complexes

Wathier, M., & Love, J. A. (2016) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201501272 · Cited by 27

A DFT Study on Palladium and Nickel-Catalyzed Regioselective and Stereoselective Hydrosilylation of 1,3-Disubstituted Allenes

Xie, H., Kuang, J., Wang, L., Li, Y., Huang, L., Fan, T., Lei, Q., & Fang, W. (2017) · Organometallics · doi:10.1021/acs.organomet.7b00495 · Cited by 26

Mechanistic Insight into the Copper‐Catalyzed Regiodivergent Silacarboxylation of Allenes with CO 2

Yuan, R., Hu, R. H., & Fu, G. (2016) · Chemistry - An Asian Journal · doi:10.1002/asia.201600739 · Cited by 15

A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective ligation of azides and terminal alkynes

Rostovtsev, V. V., Green, L. G., Fokin, V. V., & Sharpless, K. B. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020715)41:14<2596::aid-anie2596>3.0.co;2-4

Biocatalysis with Laccases: An Updated Overview

Bassanini, I., Ferrandi, E. E., Riva, S., & Monti, D. (2020) · Catalysts · doi:10.3390/catal11010026 · Cited by 139