High efficiency electrochemical reduction of CO 2 beyond the two-electron transfer pathway on grain boundary rich ultra-small SnO 2 nanoparticles
Abstract
Grain boundary rich ultra-small SnO 2 nanoparticles exhibited high total FEs towards electrochemical reduction of CO 2 with products beyond CO and HCOO − .
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In gas phase systems, catalysts that have poor CO2RR selectivity in liquid phase electrolyzers (Pt, Fe, Fe-Co, Pt-Ru, etc.) can produce methanol, isopropanol, and >C5 long chain products, although in small quantities.
“Researchers have also used catalysts that have poor CO2RR selectivity in liquid phase electrolyzers (Pt, Fe, Fe-Co, Pt-Ru, etc.) to produce products not typically observed in other flow cell systems, such as methanol, [146][147][148][149] isopropanol, [150,151] and >C5 long chain products, although in small quantities.[152,153]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [151]
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Self-citation
- Authors
- Liang, C., Kim, B., Yang, S., Yang Liu, Y. L., Francisco Woellner, C., Li, Z., Vajtai, R., Yang, W., Wu, J., Kenis, P. J. A., & Ajayan, P. M.
- Affiliations
- University of Akron (US)
- Kyushu University (JP)
- Oak Ridge National Laboratory (US)
- College of Polymer Science and Engineering
- Department of Materials Science and Nano Engineering
- Rice University (US)
- University of Cincinnati (US)
- Corresponding author
- Yang, Wei
- Wu, Jingjie
- Kenis, Paul J. A.
- Ajayan, Pulickel M.
- ORCID
- Venue
- Journal of Materials Chemistry A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2018
- Volume
- 6
- Issue
- 22
- Pages
- 10313-10319
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W2801064149
- Cited by
- 124
- References
- 57
- Citations by year
- 2026: 7 · 2025: 19 · 2024: 12 · 2023: 16 · 2022: 13 · 2021: 17 · 2020: 22 · 2019: 15 · 2018: 3
- FWCI
- 3.29
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry A (publishedVersion)
- Funders
- China Scholarship Council
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- electrochemical CO2 reduction, formate selectivity, formate production
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