Tailor-made block copolymers of l -, d - and rac -lactides and ε-caprolactone via one-pot sequential ring opening polymerization by pyridylamidozinc( ii ) catalysts
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New 3-coordinated Zn ROP catalysts afford lactide stereo-block copolymers with variable block lengths and steric structures and diblock ε-caprolactone-lactide copolymers at room temperature and in short reaction times.
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- Keram M. Ma H. Appl. Organomet. Chem. 2017 31 e3893 10.1002/aoc.3893 · DOI
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- Authors
- D'Auria, I., D'Alterio, M. C., Tedesco, C., & Pellecchia, C.
- Affiliations
- Dipartimento di Chimica e Biologia “A. Zambelli”
- Dipartimento di Scienze Chimiche
- University of Salerno (IT)
- Corresponding author
- Pellecchia, Claudio
- Venue
- RSC Advances
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2019
- Volume
- 9
- Issue
- 56
- Pages
- 32771-32779
- ISSN
- 2046-2069 (ISSN-L)
- PMC
- PMC9073191
- OpenAlex
- W2980297288
- Cited by
- 40
- References
- 55
- Citations by year
- 2026: 3 · 2025: 6 · 2024: 6 · 2023: 7 · 2022: 9 · 2021: 5 · 2020: 4
- FWCI
- 1.28
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- RSC Advances (publishedVersion, cc-by-nc)
- PubMed Central (publishedVersion, cc-by-nc)
- PubMed (publishedVersion)
- Funders
- Fondazione Cariplo (B42F17000080005)
- Università degli Studi di Salerno
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Keywords
- block copolymers, lactide, ε-caprolactone, ring-opening polymerization, stereoblock copolymers, L-lactide, D-lactide, rac-lactide, diblock copolymers
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