Cited by 5biodegradable polymer synthesis and propertiesOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysis

Theoretical insight into the opposite redox activity of iron complexes toward the ring opening polymerization of lactide and epoxide

Xu, Xiaowei, Lu, Han, Luo, Gen, Kang, Xiaohui, Luo, Yi·2021·Inorganic Chemistry Frontiers

Abstract

The origin of opposite reactivity in the ring-opening polymerization of lactide (LA) and cyclohexene oxide (CHO) catalyzed by redox-switchable bis(imino)pyridine iron complexes has been computationally elucidated.

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Crossref · 10.1039/d0qi01306d

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55 of 55 references verified0 citation errors · 0 not checkable

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Authors
Xu, X., Lu, H., Luo, G., Kang, X., & Luo, Y.
Affiliations
  • Dalian University of Technology (CN)
  • State Key Laboratory of Fine Chemicals
  • Anhui University (CN)
  • Dalian Medical University (CN)
Corresponding author
Luo, Yi
Venue
Inorganic Chemistry Frontiers
Published
2021
Volume
8
Issue
4
Pages
1005-1014
ISSN
  • 2052-1545 (ISSN-L)
  • 2052-1553
OpenAlex
W3112135171
Cited by
5
References
55
Citations by year
2023: 3 · 2022: 1 · 2021: 1
FWCI
0.33
Type
journal article
Language
en
Open access
closed
Locations
Inorganic Chemistry Frontiers (publishedVersion)
Funders
National Natural Science Foundation of China (21674014, 21704011, U1862115)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
Keywords
ring-opening polymerization, lactide, cyclohexene oxide, polymerization mechanism, computational chemistry

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