Theoretical insight into the opposite redox activity of iron complexes toward the ring opening polymerization of lactide and epoxide
Abstract
The origin of opposite reactivity in the ring-opening polymerization of lactide (LA) and cyclohexene oxide (CHO) catalyzed by redox-switchable bis(imino)pyridine iron complexes has been computationally elucidated.
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Comparatively little research has been directed at using inexpensive iron catalysts for effective ROP reactions.
“Still, comparatively little research has been directed at using inexpensive iron catalysts for effective ROP reactions.”
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- Authors
- Xu, X., Lu, H., Luo, G., Kang, X., & Luo, Y.
- Affiliations
- Dalian University of Technology (CN)
- State Key Laboratory of Fine Chemicals
- Anhui University (CN)
- Dalian Medical University (CN)
- Corresponding author
- Luo, Yi
- Venue
- Inorganic Chemistry Frontiers
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2021
- Volume
- 8
- Issue
- 4
- Pages
- 1005-1014
- ISSN
- 2052-1545 (ISSN-L)
- 2052-1553
- OpenAlex
- W3112135171
- Cited by
- 5
- References
- 55
- Citations by year
- 2023: 3 · 2022: 1 · 2021: 1
- FWCI
- 0.33
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Inorganic Chemistry Frontiers (publishedVersion)
- Funders
- National Natural Science Foundation of China (21674014, 21704011, U1862115)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- ring-opening polymerization, lactide, cyclohexene oxide, polymerization mechanism, computational chemistry
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