Vortex-assisted natural deep eutectic solvent dispersive liquid–liquid microextraction based on the solidification of a floating organic drop for the determination of benzoic acid and sorbic acid in condiments

Zhu, Xiaoming; Geng, Shuwen; Wen, Tao; Qin, Feng; Zhao, Longshan

doi:10.1039/d1ay01218e

Cited by 12Analytical chemistry methods developmentIonic liquids properties and applicationsAnalytical Chemistry and Chromatography

Vortex-assisted natural deep eutectic solvent dispersive liquid–liquid microextraction based on the solidification of a floating organic drop for the determination of benzoic acid and sorbic acid in condiments

Zhu, Xiaoming, Geng, Shuwen, Wen, Tao, Qin, Feng, Zhao, Longshan·2021·Analytical Methods

DOI 10.1039/d1ay01218e

Open this paper in CoChat — free account

Abstract

Schematic diagram of VA-DLLME-SFO procedure.

Integrity signals

Registry

Crossref · 10.1039/d1ay01218e

Cites

32 of 32 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Dispersers can be replaced by greener deep eutectic solvents [33], surfactants can act as dispersers, or the process can be conducted through several mechanical dispersion methods such as ultrasound [49], vortex [72], air [38], or magnetic stirring.
“Dispersers can be replaced by greener deep eutectic solvents [33], surfactants can act as dispersers, or the process can be conducted through several mechanical dispersion methods such as ultrasound [49], vortex [72], air [38], or magnetic stirring.”
From Deep Eutectic Solvents as Promising Green Solvents in Dispersive Liquid–Liquid Microextraction Based on Solidification of Floating Organic Droplet: Recent Applications, Challenges and Future Perspectives (2021) · cites this paper as [72]

Extraction of phenolic compounds from olive pomace by using natural deep eutectic solvents and innovative extraction techniques
Chanioti, S., & Tzia, C. (2018) · Innovative Food Science & Emerging Technologies · doi:10.1016/j.ifset.2018.07.001 · Cited by 340 · see citing works
Natural deep eutectic solvents-mediated extractions: the way forward for sustainable analytical developments
Fernández, M. D. L. Á., Boiteux, J., Espino, M., Gomez, F. J. V., & Silva, M. F. (2018) · Analytica Chimica Acta · doi:10.1016/j.aca.2018.07.059 · Cited by 307 · see citing works
Modeling the Physicochemical Properties of Natural Deep Eutectic Solvents
Kovács, A., Neyts, E. C., Cornet, I., Wijnants, M., & Billen, P. (2020) · ChemSusChem · doi:10.1002/cssc.202000286 · Cited by 191 · see citing works
Solidification of floating organic droplet in dispersive liquid-liquid microextraction as a green analytical tool
Mansour, F. R., & Danielson, N. D. (2017) · Talanta · doi:10.1016/j.talanta.2017.03.084 · Cited by 178 · see citing works
Evaluation of fatty acid/alcohol-based hydrophobic deep eutectic solvents as media for extracting antibiotics from environmental water
Tang, W., Dai, Y., & Row, K. H. (2018) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-018-1346-6 · Cited by 148 · see citing works
Dispersive liquid–liquid microextraction method based on solidification of floating organic droplet for the determination of triazine herbicides in water and sugarcane samples
Sanagi, M. M., Abbas, H. H., Ibrahim, W. A. W., & Aboul-Enien, H. Y. (2012) · Food Chemistry · doi:10.1016/j.foodchem.2012.01.036 · Cited by 112 · see citing works
Simultaneous determination of preservatives in beverages, vinegar, aqueous sauces, and quasi-drug drinks by stir-bar sorptive extraction (SBSE) and thermal desorption GC–MS
Ochiai, N., Sasamoto, K., Takino, M., Yamashita, S., Daishima, S., Heiden, A. C., & Hoffmann, A. (2002) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-002-1257-3 · Cited by 98 · see citing works
HPLC and LC–MS/MS methods for determination of sodium benzoate and potassium sorbate in food and beverages: Performances of local accredited laboratories via proficiency tests in Turkey
Gören, A. C., Bilsel, G., Şimşek, A., Bílsel, M., Akçadağ, F., Topal, K., & Ozgen, H. (2014) · Food Chemistry · doi:10.1016/j.foodchem.2014.11.094 · Cited by 94 · see citing works
Eco-friendly ultrasonic assisted liquid–liquid microextraction method based on hydrophobic deep eutectic solvent for the determination of sulfonamides in fruit juices
Ji, Y., Meng, Z., Zhao, J., Zhao, H., & Zhao, L. (2020) · Journal of Chromatography A · doi:10.1016/j.chroma.2019.460520 · Cited by 89 · see citing works
Self-citation
Ultra-rapid, enhanced and eco-friendly extraction of four main flavonoids from the seeds of Oroxylum indicum by deep eutectic solvents combined with tissue-smashing extraction
Yin, X.-S., Zhong, Z., Bian, G.-L., Cheng, X.-J., & Li, D. (2020) · Food Chemistry · doi:10.1016/j.foodchem.2020.126555 · Cited by 78 · see citing works
Simultaneous determination of sorbic and benzoic acids in food dressing by headspace solid-phase microextraction and gas chromatography
Dong, C., Mei, Y., & Chen, L. (2006) · Journal of Chromatography A · doi:10.1016/j.chroma.2006.04.006 · Cited by 75 · see citing works
Development of an RP-HPLC method for the simultaneous determination of benzoic acid, sorbic acid, natamycin and lysozyme in hard and pasta filata cheeses
Guarino, C., Fuselli, F., Mantia, A. L., & Longo, L. (2011) · Food Chemistry · doi:10.1016/j.foodchem.2011.01.086 · Cited by 69 · see citing works
Determination of Bisphenol A in Food and Environmental Samples Using Combined Solid-Phase Extraction–Dispersive Liquid–Liquid Microextraction with Solidification of Floating Organic Drop Followed by HPLC
Sadeghi, M., Nematifar, Z., Fattahi, N., Pirsaheb, M., & Shamsipur, M. (2015) · Food Analytical Methods · doi:10.1007/s12161-015-0357-6 · Cited by 66 · see citing works
Determination of hormones, a plasticizer, preservatives, perfluoroalkylated compounds, and a flame retardant in water samples by ultrasound-assisted dispersive liquid–liquid microextraction based on the solidification of a floating organic drop
Martín, J., Santos, J. L., Aparicio, I., & Alonso, E. (2015) · Talanta · doi:10.1016/j.talanta.2015.04.089 · Cited by 62 · see citing works
Hydrophobic borneol-based natural deep eutectic solvents as a green extraction media for air-assisted liquid-liquid micro-extraction of warfarin in biological samples
Majidi, S. M., & Hadjmohammadi, M. R. (2020) · Journal of Chromatography A · doi:10.1016/j.chroma.2020.461030 · Cited by 62 · see citing works
A green and simple procedure based on deep eutectic solvents for the extraction of phthalates from beverages
Santana‐Mayor, Á., Socas‐Rodríguez, B., Rodríguez‐Ramos, R., & Rodríguez‐Delgado, M. Á. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.125798 · Cited by 60 · see citing works
A simple and rapid method for simultaneous determination of benzoic and sorbic acids in food using in-tube solid-phase microextraction coupled with high-performance liquid chromatography
Yi, W., Wang, Y., & Feng, Y. (2007) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-007-1395-8 · Cited by 54 · see citing works
Determination of phthalates in food simulants and liquid samples using ultrasound-assisted dispersive liquid–liquid microextraction followed by solidification of floating organic drop
Pérez‐Outeiral, J., Millán, E., & García-Arrona, R. (2015) · Food Control · doi:10.1016/j.foodcont.2015.10.016 · Cited by 46 · see citing works
A simple and highly-available microextraction of benzoic and sorbic acids in beverages and soy sauce samples for high performance liquid chromatography with ultraviolet detection
Timofeeva, I. I., Kanashina, D., Stepanova, K., & Bulatov, A. V. (2018) · Journal of Chromatography A · doi:10.1016/j.chroma.2018.12.030 · Cited by 39 · see citing works
Simultaneous determination of some food additives in soft drinks and other liquid foods by flow injection on-line dialysis coupled to high performance liquid chromatography
Kritsunankul, O., & Jakmunee, J. (2011) · Talanta · doi:10.1016/j.talanta.2011.02.045 · Cited by 38 · see citing works
Analysis of six preservatives in beverages using hydrophilic deep eutectic solvent as disperser in dispersive liquid-liquid microextraction based on the solidification of floating organic droplet
Bian, Y., Wang, Y., Yu, J., Zheng, S., Qin, F., & Zhao, L. (2021) · Journal of Pharmaceutical and Biomedical Analysis · doi:10.1016/j.jpba.2021.113889 · Cited by 38 · see citing works
Self-citation
An environment-friendly procedure for the high performance liquid chromatography determination of benzoic acid and sorbic acid in soy sauce
Ding, M., Peng, J., Ma, S.-L., & Zhang, Y. (2015) · Food Chemistry · doi:10.1016/j.foodchem.2015.03.025 · Cited by 37 · see citing works
Direct quantitation of the preservatives benzoic and sorbic acid in processed foods using derivative spectrophotometry combined with micro dialysis
Fujiyoshi, T., Ikami, T., Kikukawa, K., Kobayashi, M., Takai, R., Kozaki, D., & Yamamoto, A. (2017) · Food Chemistry · doi:10.1016/j.foodchem.2017.07.108 · Cited by 37 · see citing works
A novel RP‐HPLC method for simultaneous determination of potassium sorbate and sodium benzoate in soft drinks using C18‐bonded monolithic silica column
Can, N. Ö., Arlı, G., & Lafci, Y. (2011) · Journal of Separation Science · doi:10.1002/jssc.201100172 · Cited by 35 · see citing works
Sensitive determination of organic acid preservatives in juices and soft drinks treated by monolith-based stir cake sorptive extraction and liquid chromatography analysis
Lin, F., Nong, S., Huang, X., & Yuan, D. (2013) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-012-6646-7 · Cited by 27 · see citing works
A modified quick, easy, cheap, effective, rugged, and safe method with hydrophobic natural deep eutectic solvent as extractant and analyte protectant for analyzing pyrethroid residues in tomatoes
Ye, X., Ye, B., Xu, J., Fang, M., Dong, D., Wu, C., Lin, X., Hu, Y., Cao, X., & Mo, W. (2020) · Journal of Separation Science · doi:10.1002/jssc.202000547 · Cited by 24 · see citing works
Dispersive liquid-liquid microextraction for a rapid determination of glyoxal in alcoholic beverages
Rodríguez‐Cáceres, M. I., Palomino‐Vasco, M., Mora-Díez, N. M., & Acedo-Valenzuela, M. I. (2017) · Talanta · doi:10.1016/j.talanta.2017.03.031 · Cited by 19 · see citing works
Sorbate and benzoate in Turkish retail foodstuffs
Ulca, P., Atamer, B., Keskin, M., & Şenyuva, H. Z. (2013) · Food Additives and Contaminants Part B · doi:10.1080/19393210.2013.795609 · Cited by 17 · see citing works
Determination of preservatives in soft drinks by capillary electrophoresis with ionic liquids as the electrolyte additives
Sun, B., Qi, L., & Wang, M. (2014) · Journal of Separation Science · doi:10.1002/jssc.201400444 · Cited by 16 · see citing works
Optimization of a methodology for the simultaneous determination of deltamethrin, permethrin and malathion in stored wheat samples using dispersive liquid–liquid microextraction with solidification of floating organic drop and HPLC-UV
Pirsaheb, M., Rezaei, M., Fattahi, N., Karami, M., Sharafi, K., & Ghaffari, H. R. (2017) · Journal of Environmental Science and Health Part B · doi:10.1080/03601234.2017.1330078 · Cited by 16 · see citing works
Optimized Dispersive Liquid–Liquid Microextraction Method and High Performance Liquid Chromatography with Ultraviolet Detection for Simultaneous Determination of Sorbic and Benzoic Acids and Evaluation of Contamination of These Preservatives in Iranian Foods
Javanmardi, F., Arefhosseini, S. R., Ansarin, M., & Nemati, M. (2015) · Journal of AOAC International · doi:10.5740/jaoacint.14-260 · Cited by 14 · see citing works
Application of dispersive liquid–liquid microextraction based on solidification of floating organic drop for the determination of extractables from pharmaceutical packaging materials
Sun, X., Xing, X., & Du, Z. (2019) · Talanta · doi:10.1016/j.talanta.2019.120540 · Cited by 13 · see citing works

Flagged first, then by citations

Sorted by citations

Applications of (natural) deep eutectic solvents in liquid phase microextraction: A review
Mansour, F. R., Bedair, A., Hamed, M., Magdy, G., Ali, I., & Locatelli, M. (2024) · Microchemical Journal · doi:10.1016/j.microc.2024.110178 · Cited by 107 · see citing works
Research Progress on the Preparation and Action Mechanism of Natural Deep Eutectic Solvents and Their Application in Food
Wu, K., Ren, J., Wang, Q., Nuerjiang, M., Xia, X., & Bian, C. (2022) · Foods · doi:10.3390/foods11213528 · Cited by 106 · see citing works
Recent advances in dispersion strategies for dispersive liquid–liquid microextraction from green chemistry perspectives
El‐Deen, A. K., Elmansi, H., Belal, F. F., & Magdy, G. (2023) · Microchemical Journal · doi:10.1016/j.microc.2023.108807 · Cited by 82 · see citing works
A review on recent applications of deep eutectic solvents in microextraction techniques for the analysis of biological matrices
de Andrade, D. C., Monteiro, S. A., & Merib, J. (2022) · Advances in Sample Preparation · doi:10.1016/j.sampre.2022.100007 · Cited by 79 · see citing works
Insights on the potential of natural deep eutectic solvents (NADES) to fine-tune durian seed gum for use as edible food coating
Fang, X., Li, Y., Kua, Y. L., Chew, Z. L., Gan, S., Tan, K. W., Lee, T. Z. E., Cheng, W. K., & Lau, H. L. N. (2022) · Food Hydrocolloids · doi:10.1016/j.foodhyd.2022.107861 · Cited by 62 · see citing works
Deep Eutectic Solvents as Promising Green Solvents in Dispersive Liquid–Liquid Microextraction Based on Solidification of Floating Organic Droplet: Recent Applications, Challenges and Future Perspectives
El-Deen, A. K., & Shimizu, K. (2021) · Molecules · doi:10.3390/molecules26237406 · Cited by 58 · see citing works
“Dispersers can be replaced by greener deep eutectic solvents [33], surfactants can act as dispersers, or the process can be conducted through several mechanical dispersion methods such as ultrasound [49], vortex [72], air [38], or magnetic stirring.”
Background
Deep eutectic solvents in food contaminants detection: Characteristics, interaction mechanism and application advances from extracting to other roles
Wang, P., & Liu, C. (2025) · Food Chemistry · doi:10.1016/j.foodchem.2025.143521 · Cited by 34 · see citing works
Sensitive Method for Determination of Benzoic Acid in Beverages and Food Samples Using Air–Assisted Hydrophobic Deep Eutectic Solvent-Based Dispersive Liquid-Liquid Microextraction
Altunay, N., Lanjwani, M. F., Haq, H. U., Tuzen, M., & Elik, A. (2024) · Sustainable Chemistry and Pharmacy · doi:10.1016/j.scp.2024.101464 · Cited by 27 · see citing works
Advancements in deep eutectic solvent-based membranes for the extraction, separation, and preconcentration of organic compounds
Sani, N. F. A., Ramadhan, R., Yahaya, N., Ghadzi, S. M. S., Mohamed, A. H., Kamaruzaman, S., Ibrahim, W. N. W., Hanapi, N. S. M., & Zain, N. N. M. (2025) · Advances in Sample Preparation · doi:10.1016/j.sampre.2025.100181 · Cited by 10 · see citing works
Rapid analysis of triazine herbicides in fruit juices using evaporation-assisted dispersive liquid–liquid microextraction with solidification of floating organic droplets and HPLC-DAD
Wu, B., Niu, Y., Bi, X., Wang, X., Jia, L., & Jing, X. (2022) · Analytical Methods · doi:10.1039/d1ay02130c · Cited by 9 · see citing works
Innovative Analytical Approaches for Food Preservatives: From Advanced Detection to Data-Driven Interpretation
Mhamdi, L., Saidi, H., Darej, C., Ishtiaq, U., M’Hamdi, H., Joly, N., Vian, M. A., M’Hamdi, N., & Martin, P. (2026) · Springer eBooks · doi:10.1007/978-3-032-17268-6_10 · Cited by 3 · see citing works
Eco-friendly vortex-assisted microextraction using facemask substrate and amine solvents for simultaneous determination of some of food preservatives
Arabkhani, B., Goudarzi, N., & Chamjangali, M. A. (2025) · Journal of Food Measurement & Characterization · doi:10.1007/s11694-025-03897-0

Shaker-Assisted Liquid–Liquid Microextraction Followed by Solidification of Floating Organic Droplet and Back-Extraction Procedure besides Partial Least Squares Regression for Simultaneous Spectrophotometric Determination of Benzoic Acid and Sorbic Acid
Dastyar, H., Ghoreishi, S. M., & Ghani, M. (2022) · Polycyclic aromatic compounds · doi:10.1080/10406638.2022.2039226 · Cited by 4 · see citing works
A highly efficient vortex-assisted liquid–liquid microextraction based on natural deep eutectic solvent for the determination of Sudan I in food samples
Liu, W., Zong, B., Wang, X., Cai, J., & Yu, J. (2019) · RSC Advances · doi:10.1039/c9ra01405e · Cited by 51 · see citing works
Optimized Dispersive Liquid–Liquid Microextraction and Determination of Sorbic Acid and Benzoic Acid in Beverage Samples by Gas Chromatography
Kokya, T. A., Farhadi, K., & Kalhori, A. (2011) · Food Analytical Methods · doi:10.1007/s12161-011-9245-x · Cited by 37 · see citing works
Determination of Benzoic Acid and Sorbic Acid in Sauce Samples by Molecular Complex-based Dispersive Liquid-liquid Microextraction Coupled to High Performance Liquid Chromatography
Yu-Qi, F. (2013) · Journal of Analytical Science
Determination of benzoic acid and sorbic acid in peanut butter by solid-phase dispersive extraction coupled with High Performance Liquid Chromatography
Lin, S. (2011) · Zhongguo tiaoweipin

Authors: Zhu, X., Geng, S., Wen, T., Qin, F., & Zhao, L.
Affiliations: Shenyang Pharmaceutical University (CN)
Shenyang Center for Disease Control and Prevention (CN)
Corresponding author: Qin, Feng
Zhao, Longshan
ORCID: Zhu, Xiaoming
Wen, Tao
Qin, Feng
Zhao, Longshan
Venue: Analytical Methods
Publisher: Royal Society of Chemistry (RSC)
Published: 2021
Volume: 13
Issue: 40
Pages: 4805-4813
ISSN: 1759-9660 (ISSN-L)
1759-9679
DOI: 10.1039/d1ay01218e
OpenAlex: W3198891617
Cited by: 12
References: 32
Citations by year: 2026: 1 · 2025: 3 · 2024: 2 · 2023: 1 · 2022: 4 · 2021: 1
FWCI: 1.00
Type: journal article
Language: en
Open access: closed
Licence: rsc.li/journals-terms-of-use (am, 607 d)
Locations: Analytical Methods (publishedVersion)
PubMed (publishedVersion)
Funders: Shenyang Pharmaceutical University (ZQN2016011)
Department of Education of Liaoning Province (2020LZD02)
Topics: Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
Physical Sciences › Chemistry › Spectroscopy › Analytical Chemistry and Chromatography
Keywords: vortex-assisted dispersive liquid-liquid microextraction, natural deep eutectic solvents, benzoic acid, sorbic acid, preservatives, condiments, ketchup, instant noodles, food additive analysis
MeSH terms: Condiments, Solvents, Sorbic Acid, Benzoic Acid, Liquid Phase Microextraction

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Vortex-assisted natural deep eutectic solvent dispersive liquid–liquid microextraction based on the solidification of a floating organic drop for the determination of benzoic acid and sorbic acid in condiments

Abstract

Integrity signals

Claims the paper makes

Claims other papers make about this one

Cites

Cited by

Related

Record

About these checks