Conversion of faujasites to high-silica chabazite SSZ-13 in the presence of N,N,N-trimethyl-1-adamantammonium iodide
Abstract
The hydrothermal synthetic conversion of aluminium-rich zeolites to organo-zeolites in the presence of N,N,N-trimethyl-1-adamantammonium cations is now extended to the faujasite system. Rates of conversion are seen to be dramatically affected by various treatments of the FAU (faujasite) zeolites. Rates are depressed by steaming FAU zeolites, by ion-exchanging them with unreactive organic cations, or by silylating the surface of the zeolite. Surprisingly, the inhibition is removed by calcining away the organosilyl groups. For a reactive FAU zeolite (Y-62), the extent of conversion was proportional to organo-cation content, with other variables fixed; rates of conversion were also related to hydroxide ion concentration at the start of reaction.
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Zeolite interconversion takes place in gels where the silica source is replaced by a parent zeolite which shares common building units with the target zeolite, e.g., transformation of faujasite into chabazite.
“Zeolite interconversion takes place in gels, where the silica source is replaced by a parent zeolite which shares common building units with the target zeolite, an example of which is the transformation of faujasite into chabazite.121−123”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [122]
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Wang, L., Zhu, D., Wang, J., Cui, W., Han, J., Li, B., Fan, D., Tian, P., & Liu, Z. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta01452h · Cited by 40 · see citing works
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de Moura, P. A. S., Rodríguez‐Aguado, E., Maia, D. A. S., de Melo, D. C., Singh, R. M., Valencia, S., Webley, P. A., Rey, F., Bastos-Neto, M., Rodrı́guez-Castellón, E., et al. (2021) · Catalysis Today · doi:10.1016/j.cattod.2021.11.042 · Cited by 40 · see citing works
- Authors
- Zones, S. I.
- Corresponding author
- Zones, S. I.
- ORCID
- Zones, S. I.
- Venue
- Journal of the Chemical Society, Faraday Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1991
- Volume
- 87
- Issue
- 22
- Pages
- 3709
- ISSN
- 0956-5000 (ISSN-L)
- 1364-5455
- OpenAlex
- W2098720526
- Cited by
- 219
- References
- 8
- Citations by year
- 2026: 4 · 2025: 6 · 2024: 9 · 2023: 11 · 2022: 13 · 2021: 28 · 2020: 16 · 2019: 14 · 2018: 21 · 2017: 17 · 2016: 6 · 2015: 14 · 2014: 15 · 2013: 9 · 2012: 7
- FWCI
- 0.83
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the Chemical Society Faraday Transactions (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Physical Sciences › Materials Science › Biomaterials › Clay minerals and soil interactions
- Keywords
- faujasite, SSZ-13, chabazite, zeolite conversion, hydrothermal synthesis, ion exchange, silylation, calcination, hydroxide ion concentration
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