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Descriptors for fluorotelomere alcohols. Calculation of physicochemical properties
Abstract
Abraham model solute descriptors are calculated for several environmentally important fluorotelomer alcohols from published partition coefficient and solubility data. The various descriptors all show a gradual trend from 1:2FTOH to 8:2FTOH. The maximum deviation from self-consistent values is 0.19 log units in the calculations on vapour pressure (concentration in air) and solubility in water (concentration in water).
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Endo and Goss recalibrated the solute descriptors for FTOHs, which were evaluated again by Abraham and Acree.
“Later, Endo and Goss9 recalibrated the solute descriptors for FTOHs, which were evaluated again by Abraham and Acree.12”
From Intermolecular Interactions, Solute Descriptors, and Partition Properties of Neutral Per- and Polyfluoroalkyl Substances (PFAS) (2023) · cites this paper as [12]
Previous studies have shown that A values for 4:2, 6:2, and 8:2 FTOHs are higher than those of nonfluorinated alkyl alcohols and that B has the opposite relationship.
“previous studies have shown that A values for 4:2, 6:2, and 8:2 FTOHs are higher than those of nonfluorinated alkyl alcohols and that B has the opposite relationship.9,11,12”
From Intermolecular Interactions, Solute Descriptors, and Partition Properties of Neutral Per- and Polyfluoroalkyl Substances (PFAS) (2023) · cites this paper as [12]
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Cited by
Sorted by citations
Endo, S. (2023) · Environmental Science & Technology · doi:10.1021/acs.est.3c07503 · Cited by 48
Metadata
- Authors
- Abraham, M. H., & Acree, W. E.
- Venue
- Physics and Chemistry of Liquids
- Publisher
- Informa UK Limited
- Published
- 2021-02-21
- Volume
- 59
- Issue
- 6
- Pages
- 932-937
- ISSN
- 0031-9104
- 1029-0451
- Cited by
- 6
- References
- 0
- Language
- en
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