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Determination of Trace Elements in Vegetable Oils and Biodiesel by Atomic Spectrometric Techniques—A Review
Abstract
The determination of trace elements in edible oils and biodiesel using atomic spectrometric methods is reviewed. Problems related to sample pretreatment for appropriate sample introduction and calibration are addressed as well as the strategies to overcome them. Recent trends aimed at simplifying sample manipulation are presented. The applications and scope of atomic absorption spectrometry (AAS), flame optical emission spectrometry (F-OES), inductively coupled plasma–optical emission spectrometry (ICP-OES), and inductively coupled plasma–mass spectrometry (ICP-MS) techniques for the determination of trace metals in edible oils and biodiesel are discussed, as well as some current instrumental new developments.
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Analysis of oils by atomic spectroscopic techniques faces drawbacks including difficulty of sample introduction, unstable flames, excessive spreading in ETAAS, plasma destabilization, and carbon-based polyatomic interferences in ICP-MS.
“The other drawbacks which may be faced during analysis of oils by AS include dif fi culty of sample introduction by pneumatic aspiration or furnace tube, production of fuel-rich and unstable fl ames in the case of fl ame AAS and AES, excessive spreading of the sample in ETAAS, destabilization or extinction of plasma in ICP and interferences due to carbon-based polyatomic species in ICP-MS [18].”
Conventional extraction procedures are often time-consuming, tedious and multistage, and liquid-liquid phase extraction consumes a large amount of potentially hazardous organic solvents.
“However, conventional extraction procedures are often time-consuming, tedious and multistage operations, and the liquid-liquid phase extraction consumes a large amount of potentially hazardous organic solvents [18,23].”
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Metadata
- Authors
- Lepri, F. G., Chaves, E. S., Vieira, M. A., Ribeiro, A. S., Curtius, A. J., DeOliveira, L. C. C., & DeCampos, R. C.
- Affiliations
- Universidade Federal de Santa Catarina (BR)
- Universidade Federal de Pelotas (BR)
- Pontifícia Universidade Católica do Rio de Janeiro (BR)
- Venue
- Applied Spectroscopy Reviews
- Publisher
- Informa UK Limited
- Published
- 2011-03-25
- Volume
- 46
- Issue
- 3
- Pages
- 175-206
- ISSN
- 0570-4928 (ISSN-L)
- 1520-569X
- OpenAlex
- W2015410917
- Cited by
- 119
- References
- 1
- Citations by year
- 2026: 3 · 2025: 3 · 2024: 6 · 2023: 8 · 2022: 8 · 2021: 11 · 2020: 9 · 2019: 11 · 2018: 9 · 2017: 7 · 2016: 5 · 2015: 12 · 2014: 7 · 2013: 5 · 2012: 9
- FWCI
- 8.15
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Applied Spectroscopy Reviews (publishedVersion)
- Funders
- Conselho Nacional de Desenvolvimento Científico e Tecnológico
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Chemistry › Spectroscopy › Laser-induced spectroscopy and plasma
- Physical Sciences › Chemistry › Analytical Chemistry › Heavy Metals in Plants
- Keywords
- trace elements, edible oils, biodiesel, atomic absorption spectrometry, ICP-AES, inductively coupled plasma mass spectrometry, sample preparation, sample introduction, calibration, trace metal analysis
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