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Poly(Propylene Carbonate), Old Copolymers of Propylene Oxide and Carbon Dioxide with New Interests: Catalysis and Material Properties
Abstract
Current research efforts in the field of poly(propylene carbonate) prepared from carbon dioxide and propylene oxide are reviewed. Interest in the polymer has been revived in light of the current discussion on sustainability and biodegradability. The progress in understanding and increasing the activity of heterogeneous zinc catalysts is steadily increasing, but without a quantum leap. The microstructure, the properties of the melt, and the solid material are given. The material property profile can be expanded through the synthesis of terpolymers based on propylene oxide, carbon dioxide and other epoxides, lactones or anhydrides etc. with the same catalyst; or the preparation of poly(propylene carbonate) blends with biodegradable or biocompatible components like calcium carbonate, wood flour, fibers, or other biodegradable polymers.
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Citations
Cites
Darensbourg, D. J. (2007) · Chemical Reviews · doi:10.1021/cr068363q · Cited by 1,593
Cited by
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Chen, G.-Q., & Patel, M. K. (2012) · Chemical Reviews · doi:10.1021/cr200162d · Cited by 997
Catalysts for CO 2 /epoxide copolymerisation
Kember, M. R., Buchard, A., & Williams, C. K. (2011) · Chem. Commun. · doi:10.1039/c0cc02207a · Cited by 797
Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms
Klaus, S., Lehenmeier, M. W., Anderson, C. E., & Rieger, B. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.12.002 · Cited by 710
Green Polymer Chemistry and Bio‐based Plastics: Dreams and Reality
Mülhaupt, R. (2013) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201200439 · Cited by 709
Metadata
- Authors
- Luinstra, G.
- Venue
- Polymer Reviews
- Publisher
- Informa UK Limited
- Published
- 2008-01
- Volume
- 48
- Issue
- 1
- Pages
- 192-219
- ISSN
- 0736-6574 (ISSN-L)
- 1558-3724
- OpenAlex
- W1985040528
- Cited by
- 409
- References
- 1
- FWCI
- 5.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- Luinstra, G. (2008). Poly(Propylene Carbonate), Old Copolymers of Propylene Oxide and Carbon Dioxide with New Interests: Catalysis and Material Properties. Polymer Reviews. https://doi.org/10.1080/15583720701834240
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.