The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
End group removal and modification of RAFT polymers
Open accessAbstract
This paper describes both well-established routes and recent advances in the end group modification of polymers synthesised by reversible addition–fragmentation chain transfer (RAFT) polymerisation. The lability of the thiocarbonylthio group, which facilitates the RAFT mechanism, allows for ready post-polymerisation functionalisation of RAFT polymers by a number of techniques. In particular, end group thermolysis, radical induced reduction, hetero-Diels–Alder reactions and reaction with nucleophiles are discussed as are the applications and limitations of each method. The versatility of RAFT as a polymerisation tool for the synthesis of polymers with functional end groups for a range of applications is demonstrated.
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Cites
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
Radical chemistry associated with the thiocarbonyl group
Crich, D., & Quintero, L. (1989) · Chemical Reviews · doi:10.1021/cr00097a001 · Cited by 496
Universal (switchable) RAFT agents
Benaglia, M., Chiefari, J., Chong, Y. K., Moad, G., Rizzardo, E., & Thang, S. H. (2009) · Journal of the American Chemical Society · doi:10.1021/ja901955n · Cited by 302
The future of reversible addition fragmentation chain transfer polymerization
Barner‐Kowollik, C., & Perrier, S. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22866 · Cited by 280
Cited by
Redox-responsive polymers for drug delivery: from molecular design to applications
Huo, M., Yuan, J., Tao, L., & Wei, Y. (2014) · Polym. Chem. · doi:10.1039/c3py01192e · Cited by 561
Gregory, A., & Stenzel, M. H. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.08.004 · Cited by 470
The pH-responsive behaviour of poly(acrylic acid) in aqueous solution is dependent on molar mass
Swift, T., Swanson, L., Geoghegan, M., & Rimmer, S. (2016) · Soft Matter · doi:10.1039/c5sm02693h · Cited by 455
Duong, H. T. T., Jung, K., Kutty, S. K., Agustina, S., Adnan, N. N. M., Basuki, J. S., Kumar, N., Davis, T. P., Barraud, N., & Boyer, C. (2014) · Biomacromolecules · doi:10.1021/bm500422v · Cited by 126
Thiocarbonyl chemistry in polymer science
Bingham, N. M., Abousalman-Rezvani, Z., Collins, K., & Roth, P. J. (2022) · Polymer Chemistry · doi:10.1039/d2py00050d · Cited by 66
Metadata
- Authors
- Willcock, H., & O'Reilly, R. K.
- Venue
- Polym. Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 1
- Issue
- 2
- Pages
- 149-157
- ISSN
- 1759-9954 (ISSN-L)
- 1759-9962
- OpenAlex
- W2113752987
- Cited by
- 607
- References
- 4
- FWCI
- 11.97
- Type
- journal article
- Language
- en
- Open access
- green
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