Column solid phase extraction of copper, iron, and zinc ions at trace levels in environmental samples on amberlite XAD-7 for their flame atomic absorption spectrometric determinations
Abstract
A column solid‐phase extraction method for the separation and preconcentration of copper, zinc, and iron at trace levels has been established prior to their flame atomic absorption spectrometric determinations. Analytes from 0.5 M KSCN in a 1 M HCl solution were recovered using of an Amberlite XAD‐7 column. The chemical variables affecting the analytical performance of the combined methodology including reagent amounts, sample volume, flow rates of sample, and eluent solutions on the quantitative recoveries of analyte ions were studied and optimized. The presented method was applied to the analysis of natural waters and red wine sample with satisfactory results (recoveries greater than 95%, relative standard deviations (RSD) lower than 8%). The accuracy and precision of the method were confirmed by the analysis of three kinds of certified reference materials (NRCC‐SLRS‐4 riverine water, SRM 1515 apple leaves, and SRM 2711 Montana soil).
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The sample volume is an important factor for obtaining a high preconcentration factor.
“The sample volume is an important factor for obtaining a high preconcentration factor [51,52,53,54,55,56,57,58].”
From Deep Eutectic Solvent-Based Microextraction of Lead(II) Traces from Water and Aqueous Extracts before FAAS Measurements (2020) · cites this paper as [55]
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- Authors
- Tuzen, M., Soylak, M., Elci, L., & Dogan, M.
- Affiliations
- Erciyes University (TR)
- Corresponding author
- Soylak, Mustafa
- ORCID
- Soylak, Mustafa
- Venue
- Analytical Letters
- Publisher
- Informa UK Limited
- Published
- 2004-12-28
- Volume
- 37
- Issue
- 6
- Pages
- 1185-1201
- ISSN
- 0003-2719 (ISSN-L)
- 1532-236X
- OpenAlex
- W2024008182
- Cited by
- 25
- References
- 31
- Citations by year
- 2026: 1 · 2024: 2 · 2020: 1 · 2018: 1 · 2016: 2 · 2015: 2 · 2014: 4 · 2013: 1 · 2012: 3
- FWCI
- 1.71
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Analytical Letters (publishedVersion)
- Funders
- Erciyes Üniversitesi
- Gaziosmanpasa Üniversitesi
- Bilimsel Araştırma Projeleri, Erciyes Üniversitesi
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Physical Sciences › Chemistry › Spectroscopy › Analytical Chemistry and Chromatography
- Keywords
- Amberlite XAD-7, copper, iron, zinc, trace metal preconcentration, flame atomic absorption spectrometry, natural waters, red wine, method optimization
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