Cited by 25Analytical chemistry methods developmentEnvironmental and Analytical Chemistry StudiesAnalytical Chemistry and Chromatography

Column solid phase extraction of copper, iron, and zinc ions at trace levels in environmental samples on amberlite XAD-7 for their flame atomic absorption spectrometric determinations

Tuzen, Mustafa, Soylak, Mustafa, Elci, Latif, Dogan, Mehmet·2004·Analytical Letters

Abstract

A column solid‐phase extraction method for the separation and preconcentration of copper, zinc, and iron at trace levels has been established prior to their flame atomic absorption spectrometric determinations. Analytes from 0.5 M KSCN in a 1 M HCl solution were recovered using of an Amberlite XAD‐7 column. The chemical variables affecting the analytical performance of the combined methodology including reagent amounts, sample volume, flow rates of sample, and eluent solutions on the quantitative recoveries of analyte ions were studied and optimized. The presented method was applied to the analysis of natural waters and red wine sample with satisfactory results (recoveries greater than 95%, relative standard deviations (RSD) lower than 8%). The accuracy and precision of the method were confirmed by the analysis of three kinds of certified reference materials (NRCC‐SLRS‐4 riverine water, SRM 1515 apple leaves, and SRM 2711 Montana soil).

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Crossref · 10.1081/al-120034063

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Authors
Tuzen, M., Soylak, M., Elci, L., & Dogan, M.
Affiliations
Erciyes University (TR)
Corresponding author
Soylak, Mustafa
Venue
Analytical Letters
Published
2004-12-28
Volume
37
Issue
6
Pages
1185-1201
ISSN
  • 0003-2719 (ISSN-L)
  • 1532-236X
OpenAlex
W2024008182
Cited by
25
References
31
Citations by year
2026: 1 · 2024: 2 · 2020: 1 · 2018: 1 · 2016: 2 · 2015: 2 · 2014: 4 · 2013: 1 · 2012: 3
FWCI
1.71
Type
journal article
Language
en
Open access
closed
Locations
Analytical Letters (publishedVersion)
Funders
  • Erciyes Üniversitesi
  • Gaziosmanpasa Üniversitesi
  • Bilimsel Araştırma Projeleri, Erciyes Üniversitesi
Topics
  • Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
  • Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
  • Physical Sciences › Chemistry › Spectroscopy › Analytical Chemistry and Chromatography
Keywords
Amberlite XAD-7, copper, iron, zinc, trace metal preconcentration, flame atomic absorption spectrometry, natural waters, red wine, method optimization

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