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Rare-earth nickelates R NiO 3 : thin films and heterostructures
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This review stands in the larger framework of functional materials by focussing on heterostructures of rare-earth nickelates, described by the chemical formula R NiO 3 where R is a trivalent rare-earth R = La, Pr, Nd, Sm, …, Lu. Nickelates are characterized by a rich phase diagram of structural and physical properties and serve as a benchmark for the physics of phase transitions in correlated oxides where electron–lattice coupling plays a key role. Much of the recent interest in nickelates concerns heterostructures, that is single layers of thin film, multilayers or superlattices, with the general objective of modulating their physical properties through strain control, confinement or interface effects. We will discuss the extensive studies on nickelate heterostructures as well as outline different approaches to tuning and controlling their physical properties and, finally, review application concepts for future devices.
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“The electrical properties of LNO are sensitive to mechanical stress, grain boundaries, and pores [1,22].”
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“However, the increase in annealing time from 5 to 10 min slightly decreases the resistivity value, and this can be caused by improving of the film crystalline performance [1,22].”
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“The progress in the synthesis and understanding of nickelates is summarized in a number of reviews, including the most cited and most recent ones [1,2].”
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“In the perovskites, a split phase transition (meaning to the right of E 1 in Figure 1) is seen for rare earth ions smaller than Nd [30] where the CDW condenses first and the SDW second.”
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“In the case of LuNiO 3 (and NdNiO 3 ), the frontier subspace consists of the bands immediately around the Fermi level with dominant Ni e g character, resulting in two e g -like frontier orbitals per Ni site, while for the localizedsubspacewealsoincludethelower-lyingbandswithNi t 2 g andO p…”
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Self-citationElectronic Coupling of Metal‐to‐Insulator Transitions in Nickelate‐Based Heterostructures
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Electron doping of NdNiO3 thin films using dual chamber CaH2 annealing
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Dependence of band gaps in d -electron perovskite oxides on magnetism
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Tuning the Spin Transition and Carrier Type in Rare‐Earth Cobaltates via Compositional Complexity
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Structural study of nickelate based heterostructures
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Chemical Synthesis of La0.75Sr0.25CrO3 Thin Films for p-Type Transparent Conducting Electrodes
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Dynamics of Voltage-Driven Self-Sustained Oscillations in NdNiO3 Neuristors
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Quantum nickelate platform for future multidisciplinary research
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“As observed with other perovskite oxides such as nickelates 40 , the biaxial in-plane tensile strain in LSCO (larger Cr-O bond length, <Cr-O-Cr> bond angle up to 180° and unit cell volume) would decrease the Cr 3 d -”
InfluentialGeorgescu, A., & Millis, A. (2021) · doi:10.48550/arxiv.2105.02271 · Cited by 7
“The material properties depend systematically on the choice of rare-earth ion, with LuNiO3 exhibiting the highest metal insulator transition temperature TMIT = 600K, SmNiO3 having TMIT ≈ 400K, NdNiO3 having a TMIT ≈ 240K and PrNiO3 having a TMIT ≈ 130K[11, 52, 53].”
BackgroundOxygen vacancy induced site-selective Mott transition in LaNiO3
Liao, X., Singh, V., & Park, H. (2020) · doi:10.1103/physrevb.103.085110 · Cited by 7
Emergent behavior of LaNiO3 in short-periodic nickelate superlattices
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Unusual Mott transition associated with charge-order melting in BiNiO3 under pressure
Leonov, I., Belozerov, A., & Skornyakov, S. L. (2019) · Physical review B · doi:10.1103/physrevb.100.161112 · Cited by 7
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Rare-Earth Iron Garnet Superlattices with Sub-unit Cell Composition Modulation.
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Electrically-driven IMT and volatile memristor behavior in NdNiO3 films
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“…( R NiO 3 , where R = rare-earth) have IMTs spanning a wide range of temperatures (100–600 K) and can be alloyed to achieve intermediate properties, making them interesting for volatile memristors operating at typical microprocessor temperatures (350–450 K) with potentially tunable properties [6].”
Orbital control of metal-to-insulator transition in high-entropy nickelates
Cui, T., Lin, T., Jin, Q.-L., Chen, S.-R., Hong, H.-T., Zhang, Q., Fan, Y., Rong, D.-K., Wang, J.-O., Wang, C., et al. (2023) · PHYSICAL REVIEW MATERIALS · doi:10.1103/physrevmaterials.7.115802 · Cited by 6
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“Indeed, rare-earth nickelates [14–16] and certain ferrites [17–19] have been identified as charge-disproportionated insulators .”
BackgroundTaniguchi, Y., Li, H., Shimoyama, K., Hattori, A., & Tanaka, H. (2023) · Applied Physics Letters · doi:10.1063/5.0152640 · Cited by 6
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Kim, H.-S., Park, S. H., & Han, M. (2023) · Current applied physics · doi:10.1016/j.cap.2023.03.012 · Cited by 6
“Introduction Rare-earth nickelates have been attracting significant research interests by exhibiting a number of distinct phases including non-Fermi liquid, charge-disproportionated (CD) insulating states with and without magnetic orders, and unconventional superconductivity more recently [1, 2, 3, 4, 5, 6, 7, 8, 9, 1…”
BackgroundThin-film samarium nickelate as a potential material for methane sensing
Tang, Q., Wang, X., Zhang, H., Liu, Z. G., & Guan, X. (2022) · Journal of Materials Research · doi:10.1557/s43578-022-00755-3 · Cited by 6
Karmakar, S., Gavali, D. S., Mistari, C. D., Thapa, R., More, M., Behera, D., & Haque, A. (2022) · ACS Applied Electronic Materials · doi:10.1021/acsaelm.2c00569 · Cited by 6
Fowlie, J., Georgescu, A. B., Mundet, B., del Valle, J., & Tückmantel, P. (2021) · Frontiers in Physics · doi:10.3389/fphy.2021.725853 · Cited by 6
“The family of perovskite rare earth nickelates, R NiO 3 , where R can be most of the rare earths, has been widely studied for many decades already [8, 9].”
BackgroundSelf-citationSun, W.-J., Li, Y.-Y., Cai, X.-B., Yang, J.-F., Guo, W., Gu, Z.-B., Zhu, Y., & Nie, Y. (2021) · Physical review B · doi:10.1103/physrevb.104.184518 · Cited by 6
Wang, K., Hao, Y.-F., Zhang, L., Zhang, Y., Chen, X.-G., & Hong, X. (2021) · PHYSICAL REVIEW MATERIALS · doi:10.1103/physrevmaterials.5.074402 · Cited by 6
Systematic effects of Ti doping on the electronic properties of LaNiO3 thin films
Tomar, S. S., Yadav, E., Soni, K., & Mavani, K. (2021) · Bulletin of Materials Science · doi:10.1007/s12034-021-02380-y · Cited by 6
Metadata
- Authors
- Catalano, S., Gibert, M., Fowlie, J., Íñiguez, J., Triscone, J.-M., & Kreisel, J.
- Affiliations
- University of Geneva (CH)
- Luxembourg Institute of Science and Technology (LU)
- University of Luxembourg (LU)
- Corresponding author
- Kreisel, J
- Venue
- Reports on Progress in Physics
- Publisher
- IOP Publishing
- Published
- 2018-02-14
- Volume
- 81
- Issue
- 4
- Pages
- 046501
- ISSN
- 0034-4885 (ISSN-L)
- 1361-6633
- OpenAlex
- W2778004626
- Cited by
- 453
- References
- 250
- Citations by year
- 2026: 23 · 2025: 69 · 2024: 55 · 2023: 69 · 2022: 68 · 2021: 61 · 2020: 52 · 2019: 49 · 2018: 7
- FWCI
- 12.47
- Type
- journal article
- Language
- en
- Open access
- green
- orbilu.uni.lu
- Licence
- Locations
- Reports on Progress in Physics (publishedVersion)
- PubMed (publishedVersion)
- Open Repository and Bibliography (University of Luxembourg) (submittedVersion, cc-by-nc-sa)
- Funders
- Fonds National de la Recherche Luxembourg (FNR/P12/4853155)
- FP7 Ideas: European Research Council (319286 (Q-MAC))
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Electronic and Structural Properties of Oxides
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Magnetic and transport properties of perovskites and related materials
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Multiferroics and related materials
- Keywords
- rare-earth nickelates, thin films, heterostructures, superlattices, multilayer structures, strain engineering, confinement effects, interface effects, phase transitions, correlated oxides, electron-lattice coupling, functional materials, device applications
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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