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Rare-earth nickelates R NiO 3 : thin films and heterostructures
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This review stands in the larger framework of functional materials by focussing on heterostructures of rare-earth nickelates, described by the chemical formula R NiO 3 where R is a trivalent rare-earth R = La, Pr, Nd, Sm, …, Lu. Nickelates are characterized by a rich phase diagram of structural and physical properties and serve as a benchmark for the physics of phase transitions in correlated oxides where electron–lattice coupling plays a key role. Much of the recent interest in nickelates concerns heterostructures, that is single layers of thin film, multilayers or superlattices, with the general objective of modulating their physical properties through strain control, confinement or interface effects. We will discuss the extensive studies on nickelate heterostructures as well as outline different approaches to tuning and controlling their physical properties and, finally, review application concepts for future devices.
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“The electrical properties of LNO are sensitive to mechanical stress, grain boundaries, and pores [1,22].”
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“However, the increase in annealing time from 5 to 10 min slightly decreases the resistivity value, and this can be caused by improving of the film crystalline performance [1,22].”
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“Mainly, a higher distortion of the SmNiO 3 structure adds a degree of difficulty due to the rare-earth size, which disfavors its crystallization [33,49–51].”
BackgroundMethodInfluentialOptical triggering of a metal-insulator transition in neodymium nickelate films
Stupakov, A., Kocourek, T., Vetokhina, V., More-Chevalier, J., Chmelíčková, H., Dejneka, A., & Tyunina, M. (2023) · Materials research bulletin · doi:10.1016/j.materresbull.2023.112305 · Cited by 5
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Synthesis and electronic properties of Ndn+1Nin<mml:mi ma
Pan, G. A., Song, Q.-Q., Segedin, D. F., Jung, M.-C., El-Sherif, H. M., Fleck, E. E., Goodge, B., Doyle, S., Carrizales, D. C., N'Diaye, A., et al. (2022) · PHYSICAL REVIEW MATERIALS · doi:10.1103/physrevmaterials.6.055003 · Cited by 5
Dimensionality‐Controlled Evolution of Charge‐Transfer Energy in Digital Nickelates Superlattices
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Influence of defects on antidoping behavior in SmNiO3
Espinosa-García, W., & Dalpian, G. (2021) · Physical review B · doi:10.1103/physrevb.104.205106 · Cited by 5
Template Engineering of Metal-to-Insulator Transitions in Epitaxial Bilayer Nickelate Thin Films.
Lee, J., Kim, G.-Y., Jeong, S., Yang, M., Kim, J.-W., Cho, B.-G., Choi, Y., Kim, S., Choi, J.-S., Lee, T. K., et al. (2021) · ACS Applied Materials and Interfaces · doi:10.1021/acsami.1c13675 · Cited by 5
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Optical properties of LaNiO3 films tuned from compressive to tensile strain
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Self-citationEvolution of Magnetic Order from the Localized to the Itinerant Limit.
Mazzone, D., Gauthier, N., Maimone, D. T., Yadav, R., Bartkowiak, M., Gavilano, J., Raymond, S., Pomjakushin, V., Casati, N., Révay, Z., et al. (2019) · Physical Review Letters · doi:10.1103/physrevlett.123.097201 · Cited by 5
Magnetic Oxides and Other Compounds
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Effects of stoichiometry and epitaxial strain on the stabilization of infinite-layer nickelates
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Magnetoelectric effect in multiferroic nickelate perovskite YNiO3
Hernández, N. O., Skoropata, E., Ueda, H., Burian, M., Alonso, J. A., & Staub, U. (2024) · Communications Materials · doi:10.1038/s43246-024-00604-2 · Cited by 4
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Emergence of Interfacial Magnetism in Strongly‐Correlated Nickelate‐Titanate Superlattices
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“We have developed optoelectronic control of a nickelate’s resistance, which adds to the list of methodologies used to gain control of the material’s resistance such as doping, gating, pressure, magnetic and electric fields[9, 24, 42-45].”
MethodHigh-temperature resistivity in rare-earth nickelates films
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“Currently, thin film deposition techniques, such as pulsed laser deposition (PLD) and molecular beam epitaxy (MBE), are the main methods used to obtain high-quality RENiO3 films [9].”
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“, epitaxial and symmetry conditions) and on the type and amount of defects (off-stoichiometry, oxygen content, extended structural defects) [9,10].”
BackgroundProton distribution visualization in perovskite nickelate devices utilizing nanofocused x rays
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Evolution of the metallic state in LaNiO3/LaAlO3 superlattices measured by Li8β -detected NMR
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Low oxygen pressure synthesis of NdNiO3-δ nanowires by electrospinning
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Operator Lanczos Approach enabling Neural Quantum States as Real-Frequency Impurity Solvers
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“Examples range from Mott insulators in transition metal oxides [4, 5] and heavy fermion metals in rare-earth intermetallics [6, 7], to unconventional superconductors [8, 9] and quantum spin liquids in frustrated magnets [10].”
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Signatures of polarized chiral spin disproportionation in rare earth nickelates
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Self-citationCoherent control of rare earth 4f shell wavefunctions in the quantum spin liquid Tb2Ti2O7
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Self-citationResistive switching of VO2 films grown on a thermal insulator
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Self-citationMetal-to-insulator transition in platinum group compounds
Xia, Y., He, J., Chen, N.-F., & Chen, J.-K. (2024) · Rare Metals · doi:10.1007/s12598-023-02598-1 · Cited by 3
“…are 3d-TM oxides exhibiting the MIT behaviors have developed, such as vanadium oxides [6–8] (e.g., VO 2 and V 2 O 3 ), rare-earth (RE) nickelates [9–11] (RENiO 3 ), Fe-based oxides [12, 13] (e.g., RE 2 FeO 4 , CaFeO 3 , and RECu 3 Fe 4 O 12 ), cobaltites [14–16] (RECoO 3 ) and manganates [17–20]…”
Ionic liquid gating induced insulating phase transition in LaNiO3 thin films
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BackgroundMultiferroic properties induced by defect dipoles in thin Ca3Mn2O7 films at room temperature
Zhao, W.-Y., Wang, Z., Li, Z.-X., Peng, Y.-Z., Shi, L., Hua, W., Wang, L.-D., Fei, W., & Zhao, Y. (2022) · Ceramics International · doi:10.1016/j.ceramint.2022.12.269 · Cited by 3
Coupling of magnetic phases at nickelate interfaces
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Self-citationMagnetic order driven ultrafast phase transition in NdNiO3
Stoica, V., Puggioni, D., Zhang, J., Singla, R., Dakovski, G., Coslovich, G., Seaberg, M., Kareev, M., Middey, S., Kissin, P., et al. (2022) · Physical review B · doi:10.1103/physrevb.106.165104 · Cited by 3
Large Negative Photoresistivity in Amorphous NdNiO3 Film
Stupakov, A., Kocourek, T., Nepomniashchaia, N., Tyunina, M., & Dejneka, A. (2021) · Coatings · doi:10.3390/coatings11111411 · Cited by 3
“A film–substrate mismatch in the lattice parameters introduces a strain influencing the resistive behavior of the nickelate thin films as compared with their bulk analogues [4,5].”
BackgroundNovel magnetization and susceptibility originated in the nanomagnet of disordered nickelates
Haldar, S., Saha, R., & Ghosh, A. (2021) · The European Physical Journal Plus · doi:10.1140/epjp/s13360-021-02045-z · Cited by 3
Structural, electrical, and magnetic properties of bulk Nd1-xSrxNiO3 (x = 0–0.3)
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Hard x-ray photoemission study on strain effect in LaNiO3 thin films
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Tuning electronic properties in LaNiO3 thin films by B-site Cu-substitution
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Picosecond evolution of an induced metallic state under infinitesimal optical doping in NdNiO3
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Metadata
- Authors
- Catalano, S., Gibert, M., Fowlie, J., Íñiguez, J., Triscone, J.-M., & Kreisel, J.
- Affiliations
- University of Geneva (CH)
- Luxembourg Institute of Science and Technology (LU)
- University of Luxembourg (LU)
- Corresponding author
- Kreisel, J
- Venue
- Reports on Progress in Physics
- Publisher
- IOP Publishing
- Published
- 2018-02-14
- Volume
- 81
- Issue
- 4
- Pages
- 046501
- ISSN
- 0034-4885 (ISSN-L)
- 1361-6633
- OpenAlex
- W2778004626
- Cited by
- 453
- References
- 250
- Citations by year
- 2026: 23 · 2025: 69 · 2024: 55 · 2023: 69 · 2022: 68 · 2021: 61 · 2020: 52 · 2019: 49 · 2018: 7
- FWCI
- 12.47
- Type
- journal article
- Language
- en
- Open access
- green
- orbilu.uni.lu
- Licence
- Locations
- Reports on Progress in Physics (publishedVersion)
- PubMed (publishedVersion)
- Open Repository and Bibliography (University of Luxembourg) (submittedVersion, cc-by-nc-sa)
- Funders
- Fonds National de la Recherche Luxembourg (FNR/P12/4853155)
- FP7 Ideas: European Research Council (319286 (Q-MAC))
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Electronic and Structural Properties of Oxides
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Magnetic and transport properties of perovskites and related materials
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Multiferroics and related materials
- Keywords
- rare-earth nickelates, thin films, heterostructures, superlattices, multilayer structures, strain engineering, confinement effects, interface effects, phase transitions, correlated oxides, electron-lattice coupling, functional materials, device applications
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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