The DOI matches its Crossref record.
Interpretation of Raman spectra of disordered and amorphous carbon
Abstract
The model and theoretical understanding of the Raman spectra in disordered and amorphous carbon are given. The nature of the G and D vibration modes in graphite is analyzed in terms of the resonant excitation of \ensuremath{\pi} states and the long-range polarizability of \ensuremath{\pi} bonding. Visible Raman data on disordered, amorphous, and diamondlike carbon are classified in a three-stage model to show the factors that control the position, intensity, and widths of the G and D peaks. It is shown that the visible Raman spectra depend formally on the configuration of the ${\mathrm{sp}}^{2}$ sites in ${\mathrm{sp}}^{2}$-bonded clusters. In cases where the ${\mathrm{sp}}^{2}$ clustering is controlled by the ${\mathrm{sp}}^{3}$ fraction, such as in as-deposited tetrahedral amorphous carbon (ta-C) or hydrogenated amorphous carbon (a-C:H) films, the visible Raman parameters can be used to derive the ${\mathrm{sp}}^{3}$ fraction.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
No references could be resolved yet.
Research works printed but not linked: 76
- J. Robertson, 1991, Prog. Solid State Chem., 21, 199, 10.1016/0079-6786(91)90002-H · DOI · Paper page
- J. Robertson, 1994, Pure Appl. Chem., 66, 1789, 10.1351/pac199466091789 · DOI
- D. S. Knight, 1989, J. Mater. Res., 4, 385, 10.1557/JMR.1989.0385 · DOI
- F. Tuinstra, 1970, J. Chem. Phys., 53, 1126, 10.1063/1.1674108 · DOI · Paper page
- R. J. Nemanich, 1979, Phys. Rev. B, 20, 392, 10.1103/PhysRevB.20.392 · DOI · Paper page
- P. Lespade, 1982, Carbon, 20, 427, 10.1016/0008-6223(82)90043-4 · DOI
- P. Lespade, 1984, Carbon, 22, 375, 10.1016/0008-6223(84)90009-5 · DOI
- N. Wada, 1980, J. Non-Cryst. Solids, 35&36, 543, 10.1016/0022-3093(80)90651-1 · DOI
- S. R. Salis, 1996, Diamond Relat. Mater., 5, 589, 10.1016/0925-9635(96)90031-X · DOI
- R. O. Dillon, 1984, Phys. Rev. B, 29, 3482, 10.1103/PhysRevB.29.3482 · DOI · Paper page
- M. Yoshikawa, 1992, Phys. Rev. B, 46, 7169, 10.1103/PhysRevB.46.7169 · DOI
- J. Wagner, 1989, Phys. Rev. B, 40, 1817, 10.1103/PhysRevB.40.1817 · DOI
- M. A. Tamor, 1989, Appl. Phys. Lett., 54, 123, 10.1063/1.101228 · DOI
- M. A. Tamor, 1994, J. Appl. Phys., 76, 3823, 10.1063/1.357385 · DOI
- J. Schwan, 1996, J. Appl. Phys., 80, 440, 10.1063/1.362745 · DOI · Paper page
- K. W. R. Gilkes, 1997, Appl. Phys. Lett., 70, 1980, 10.1063/1.118798 · DOI
- V. I. Merkulov, 1997, Phys. Rev. Lett., 78, 4869, 10.1103/PhysRevLett.78.4869 · DOI
- J. Robertson, 1987, Phys. Rev. B, 35, 2946, 10.1103/PhysRevB.35.2946 · DOI
- J. Robertson, 1986, Adv. Phys., 35, 317, 10.1080/00018738600101911 · DOI · Paper page
- W. A. Harrison, 1973, Phys. Rev. B, 8, 4487, 10.1103/PhysRevB.8.4487 · DOI
- C. A. Coulson, 1947, Proc. R. Soc. London, Ser. A, 191, 39, 10.1098/rspa.1947.0102 · DOI
- C. A. Coulson, 1948, Proc. R. Soc. London, Ser. A, 193, 447, 10.1098/rspa.1948.0056 · DOI
- J. Robertson, 1995, Diamond Relat. Mater., 4, 297, 10.1016/0925-9635(94)05264-6 · DOI
- C. Mapelli, 1999, Phys. Rev. B, 60, 12, 10.1103/PhysRevB.60.12710 · DOI
- G. Kresse, 1995, Europhys. Lett., 32, 729, 10.1209/0295-5075/32/9/005 · DOI
- P. Pavone, 1993, Phys. Rev. B, 48, 3164, 10.1103/PhysRevB.48.3156 · DOI
- T. Kohler, 1995, Phys. Rev. B, 52, 11, 10.1103/PhysRevB.52.11837 · DOI
- A. Richter, 1986, J. Non-Cryst. Solids, 88, 131, 10.1016/S0022-3093(86)80093-X · DOI
- R. Alben, 1975, Phys. Rev. B, 11, 2271, 10.1103/PhysRevB.11.2271 · DOI · Paper page
- D. Beeman, 1977, Adv. Phys., 26, 339, 10.1080/00018737700101403 · DOI
- R. Al-Jishi, 1982, Phys. Rev. B, 26, 4514, 10.1103/PhysRevB.26.4514 · DOI
- R. A. Jishi, 1993, Chem. Phys. Lett., 209, 77, 10.1016/0009-2614(93)87205-H · DOI
- R. J. Nemanich, 1981, Phys. Rev. B, 23, 6348, 10.1103/PhysRevB.23.6348 · DOI
- R. Shuker, 1970, Phys. Rev. Lett., 25, 222, 10.1103/PhysRevLett.25.222 · DOI
- F. Li, 1992, Appl. Phys. Lett., 61, 2116, 10.1063/1.108324 · DOI
- G. P. Lopinski, 1996, Appl. Phys. Lett., 69, 3348, 10.1063/1.117302 · DOI
- D. Lin-Vien, 1991, The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules
- R. P. Vidano, 1981, Solid State Commun., 39, 341, 10.1016/0038-1098(81)90686-4 · DOI
- A. V. Baranov, 1987, Opt. Spectrosc., 62, 612
- I. Pocsik, 1998, J. Non-Cryst. Solids, 227–230, 1083, 10.1016/S0022-3093(98)00349-4 · DOI
- M. J. Matthews, 1999, Phys. Rev. B, 59, 6585, 10.1103/PhysRevB.59.R6585 · DOI
- P. Y. Yu, 1996, Fundamentals of Semiconductors, 10.1007/978-3-662-03313-5 · DOI
- P. Tan, 1998, Phys. Rev. B, 58, 5435, 10.1103/PhysRevB.58.5435 · DOI
- D. G. McCulloch, 1994, Phys. Rev. B, 50, 5905, 10.1103/PhysRevB.50.5905 · DOI
- D. G. McCulloch, 1995, J. Appl. Phys., 78, 3040, 10.1063/1.360054 · DOI
- S. Prawer, 1996, Diamond Relat. Mater., 5, 433, 10.1016/0925-9635(95)00363-0 · DOI
- M. V. Klein, 1982, Light Scattering in Solids III
- D. Beeman, 1984, Phys. Rev. B, 30, 870, 10.1103/PhysRevB.30.870 · DOI
- S. Prawer, 1998, Diamond Relat. Mater., 7, 106, 10.1016/S0925-9635(97)00194-5 · DOI
- J. D. Hund, 1995, Phys. Rev. B, 52, 8106, 10.1103/PhysRevB.52.8106 · DOI
- A. Cuesta, 1998, J. Mater. Chem., 8, 2875, 10.1039/a805841e · DOI
- H. Wilhem, 1998, J. Appl. Phys., 84, 6552, 10.1063/1.369027 · DOI
- F. Li, 1990, Phys. Rev. Lett., 65, 1905, 10.1103/PhysRevLett.65.1905 · DOI
- M. Chhowalla, 2000, Appl. Phys. Lett., 76, 1419, 10.1063/1.126050 · DOI
- F. Parmigiani, 1988, J. Appl. Phys., 64, 3031, 10.1063/1.341566 · DOI
- G. Galli, 1989, Phys. Rev. Lett., 62, 555, 10.1103/PhysRevLett.62.555 · DOI · Paper page
- U. Stephan, 1994, Phys. Rev. B, 49, 1489, 10.1103/PhysRevB.50.1489 · DOI
- K. W. R. Gilkes, 1995, Phys. Rev. B, 51, 12
- D. A. Drabold, 1994, Phys. Rev. B, 49, 16, 10.1103/PhysRevB.49.16415 · DOI
- N. A. Marks, 1996, Phys. Rev. B, 54, 9703, 10.1103/PhysRevB.54.9703 · DOI
- Y. Yacoby, 1991, Light Scattering in Solid IV
- J. W. Ager, 1995, Appl. Phys. Lett., 66, 3444, 10.1063/1.113382 · DOI
- A. C. Ferrari, 1999, J. Appl. Phys., 85, 7191, 10.1063/1.370531 · DOI
- T. A. Friedmann, 1997, Appl. Phys. Lett., 71, 3820, 10.1063/1.120515 · DOI
- S. Anders, 1997, Thin Solid Films, 308, 186, 10.1016/S0040-6090(97)00385-4 · DOI
- D. R. Tallant, 1998, MRS Symposia Proceedings
- D. G. McCulloch, 1995, Phys. Rev. B, 52, 850, 10.1103/PhysRevB.52.850 · DOI
- D. G. McCulloch, 1997, Diamond Relat. Mater., 6, 1622, 10.1016/S0925-9635(97)00033-2 · DOI
- P. Koidl, 1990, Mater. Sci. Forum, 52, 41, 10.4028/www.scientific.net/MSF.52-53.41 · DOI
- J. Ristein, 1998, J. Appl. Phys., 84, 3836, 10.1063/1.368563 · DOI · Paper page
- N. A. Morrison, 1999, Thin Solid Films, 337, 71, 10.1016/S0040-6090(98)01187-0 · DOI
- B. Marchon, 1997, IEEE Trans. Magn., 33, 3148, 10.1109/20.617873 · DOI
- J. Robertson, 1997, Philos. Mag. B, 76, 335, 10.1080/01418639708241098 · DOI
- M. A. Tamor, 1991, Appl. Phys. Lett., 58, 592, 10.1063/1.104597 · DOI
- R. Kleber, 1991, Thin Solid Films, 205, 274, 10.1016/0040-6090(91)90314-N · DOI
- R. H. Jarman, 1986, Appl. Phys. Lett., 49, 1065, 10.1063/1.97476 · DOI
Cited by
Raman spectroscopy as a versatile tool for studying the properties of graphene
Ferrari, A. C., & Basko, D. M. (2013) · Nature Nanotechnology · doi:10.1038/nnano.2013.46 · Cited by 7,405
Self-citationThe production of carbon materials by hydrothermal carbonization of cellulose
Sevilla, M., & Fuertes, A. B. (2009) · Carbon · doi:10.1016/j.carbon.2009.04.026 · Cited by 2,021
Precise calculation of crystallite size of nanomaterials: A review
Hassanzadeh-Tabrizi, S. A. (2023) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2023.171914 · Cited by 649
Rapid electron transfer by the carbon matrix in natural pyrogenic carbon
Sun, T., Levin, B. D. A., Guzman, J. J. L., Enders, A., Muller, D. A., Angenent, L. T., & Lehmann, J. (2017) · Nature Communications · doi:10.1038/ncomms14873 · Cited by 626
Yu, J., Tang, L., Pang, Y., Zeng, G., Wang, J., Deng, Y., Liu, Y., Feng, H., Chen, S., & Ren, X. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.01.163 · Cited by 552
Gao, Z., Wang, J., Li, Z., Yang, W., Wang, B., Hou, M., He, Y., Liu, Q., Mann, T., Yang, P., et al. (2011) · Chemistry of Materials · doi:10.1021/cm200975x · Cited by 542
Kouketsu, Y., Mizukami, T., Mori, H., Endo, S., Aoya, M., Hara, H., Nakamura, D., & Wallis, S. (2014) · Island Arc · doi:10.1111/iar.12057 · Cited by 461
High Surface Area, sp2-Cross-Linked Three-Dimensional Graphene Monoliths
Worsley, M. A., Olson, T. Y., Lee, J. R. I., Willey, T. M., Nielsen, M. H., Roberts, S. K., Pauzauskie, P. J., Biener, J., Satcher, J. H., & Baumann, T. F. (2011) · The Journal of Physical Chemistry Letters · doi:10.1021/jz200223x · Cited by 230
Lu, P., Huang, Q., (Thanos) Bourtsalas, A. C., Chi, Y., & Yan, J. (2018) · Fuel · doi:10.1016/j.fuel.2018.05.072 · Cited by 190
Echtermeyer, T. J., Nene, P. S., Trushin, M., Gorbachev, R. V., Eiden, A. L., Milana, S., Sun, Z., Schliemann, J., Lidorikis, E., Novoselov, K. S., et al. (2014) · Nano Letters · doi:10.1021/nl5004762 · Cited by 188
Self-citationLisowski, P., Colmenares, J. C., Mašek, O., Lisowski, W., Lisovytskiy, D., Kamińska, A., & Łomot, D. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b01251 · Cited by 179
Xu, J., Tang, H., Su, S., Liu, J., Xu, K., Qian, K., Wang, Y., Zhou, Y., Hu, S., Zhang, A., et al. (2018) · Applied Energy · doi:10.1016/j.apenergy.2017.11.094 · Cited by 174
Marshall, C. P., Love, G. D., Snape, C. E., Hill, A. C., Allwood, A. C., Walter, M. R., Van Kranendonk, M. J., Bowden, S. A., Sylva, S. P., & Summons, R. E. (2007) · Precambrian Research · doi:10.1016/j.precamres.2006.12.014 · Cited by 174
Ma, W., Wang, N., Du, Y., Xu, P., Sun, B., Zhang, L., & Lin, K.-Y. A. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b05801 · Cited by 161
Biomass to porous carbon in one step: directly activated biomass for high performance CO 2 storage
Balahmar, N., Al-Jumialy, A. S., & Mokaya, R. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta01722g · Cited by 160
Evaluation of residual iron in carbon nanotubes purified by acid treatments
Edwards, E. R., Antunes, E. F., Botelho, E. C., Baldan, M. R., & Corat, E. J. (2011) · Applied Surface Science · doi:10.1016/j.apsusc.2011.07.032 · Cited by 155
Graphene nanosheets derived from plastic waste for the application of DSSCs and supercapacitors
Pandey, S., Karakoti, M., Surana, K., Dhapola, P. S., SanthiBhushan, B., Ganguly, S., Singh, P. K., Abbas, A., Srivastava, A., & Sahoo, N. G. (2021) · Scientific Reports · doi:10.1038/s41598-021-83483-8 · Cited by 155
CO2 capture using N-containing nanoporous activated carbon obtained from argan fruit shells
Boujibar, O., Souikny, A., Ghamouss, F., Achak, O., Dahbi, M., & Chafik, T. (2018) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2018.03.005 · Cited by 137
Zhang, J., Kang, W., Jiang, M., You, Y., Cao, Y., Ng, T.-W., Yu, D. Y. W., Lee, C.-S., & Xu, J. (2017) · Nanoscale · doi:10.1039/c6nr09166k · Cited by 127
Aadil, M., Zulfiqar, S., Shahid, M., Agboola, P. O., Al-Khalli, N. F., Warsi, M. F., & Shakir, I. (2021) · Electrochimica Acta · doi:10.1016/j.electacta.2021.138332 · Cited by 108
CTF-based soft touch actuator for playing electronic piano
Mahato, M., Tabassian, R., Nguyen, V. H., Oh, S., Nam, S., Hwang, W.-J., & Oh, I.-K. (2020) · Nature Communications · doi:10.1038/s41467-020-19180-3 · Cited by 94
Mir, R. A., & Pandey, O. P. (2019) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2019.02.004 · Cited by 92
Phounglamcheik, A., Wang, L., Romar, H., Kienzl, N., Broström, M., Ramser, K., Skreiberg, Ø., & Umeki, K. (2020) · Energy & Fuels · doi:10.1021/acs.energyfuels.0c00592 · Cited by 75
Dubey, P., Tripathi, K. M., & Sonkar, S. K. (2014) · RSC Advances · doi:10.1039/c3ra45261a · Cited by 72
Kohl, F. R., Grieco, C., & Kohler, B. (2020) · Chemical Science · doi:10.1039/c9sc04527a · Cited by 70
Bhaumik, S., Pathak, S. D., Dey, S., & Datta, S. (2019) · Tribology International · doi:10.1016/j.triboint.2019.06.006 · Cited by 68
Thakur, S., & Karak, N. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta02162f · Cited by 64
Baik, S., & Lee, J. W. (2015) · RSC Advances · doi:10.1039/c5ra00687b · Cited by 50
Stephens-Fripp, B., Sencadas, V., Mutlu, R., & Alici, G. (2018) · Frontiers in Bioengineering and Biotechnology · doi:10.3389/fbioe.2018.00179 · Cited by 29
Recycling of polyethylene via hydrothermal carbonization for the Li-ion battery anode
Hong, S., Ku, J., Park, S., Park, J., Yu, Y.-S., & Kim, C. (2024) · Carbon Letters · doi:10.1007/s42823-024-00721-5 · Cited by 13
Holistic utilization of waste plastics through a tandem process
Dai, L., Karakas, O., Lata, S., Cobb, K., Lei, H., He, C., Cheng, Y., Chen, P., & Ruan, R. (2023) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2023.110547 · Cited by 12
Transforming Nonrecyclable Plastic Waste into Cathode Materials for Energy Storage Devices
Ahmadian Hoseini, A. H., Mir, R. A., Aboonasr Shiraz, M. H., Arjmand, M., & Liu, J. (2025) · Advanced Sustainable Systems · doi:10.1002/adsu.202400650 · Cited by 7
Zheng, H., Guo, Y., Hao, X., Zhang, Y., Yu, J., Zhang, B., Guan, L., Li, X., Huang, X., & Wang, F. (2024) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2024.173834 · Cited by 6
Zhong, M., Sun, J., Shu, X., Guan, J., Tong, G., Ding, H., Chen, L., Zhou, N., & Shuai, Y. (2022) · Nanotechnology · doi:10.1088/1361-6528/ac5286 · Cited by 6
Characteristics of carbon films prepared by thermal chemical vapor deposition using camphor
Lai, L.-H., Yang, J.-S., & Shiue, S.-T. (2014) · Thin Solid Films · doi:10.1016/j.tsf.2014.01.035 · Cited by 5
Metadata
- Authors
- Ferrari, A. C., & Robertson, J.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 2000-05-15
- Volume
- 61
- Issue
- 20
- Pages
- 14095-14107
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W2235679284
- Cited by
- 15,651
- References
- 0
- FWCI
- 82.40
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.