The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Room-temperature coexistence of large electric polarization and magnetic order inBiFeO3single crystals
Open accessAbstract
From an experimental point of view, room-temperature ferroelectricity in $\mathrm{Bi}\mathrm{Fe}{\mathrm{O}}_{3}$ is raising many questions. Electric measurements made a long time ago on solid solutions of $\mathrm{Bi}\mathrm{Fe}{\mathrm{O}}_{3}$ with $\mathrm{Pb}(\mathrm{Ti},\mathrm{Zr}){\mathrm{O}}_{3}$ indicate that a spontaneous electric polarization exists in $\mathrm{Bi}\mathrm{Fe}{\mathrm{O}}_{3}$ below the Curie temperature ${T}_{C}=1143\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. Yet in most reported works, the synthesized samples are too conductive at room temperature to get a clear polarization loop in the bulk without any effects of extrinsic physical or chemical parameters. Surprisingly, up to now there has been no report of a $P(E)$ (polarization versus electric field) loop at room temperature on single crystals of $\mathrm{Bi}\mathrm{Fe}{\mathrm{O}}_{3}$. We describe here our procedure to synthesize ceramics and to grow good quality sizeable single crystals by a flux method. We demonstrate that $\mathrm{Bi}\mathrm{Fe}{\mathrm{O}}_{3}$ is indeed ferroelectric at room temperature through evidence by piezoresponse force microscopy and $P(E)$ loops. The polarization is found to be large, around $60\phantom{\rule{0.3em}{0ex}}\ensuremath{\mu}\mathrm{C}∕{\mathrm{cm}}^{2}$, a value that has only been reached in thin films. Magnetic measurements using a superconducting quantum interference device magnetometer and M\"ossbauer spectroscopy are also presented. The latter confirms the results of nuclear magnetic resonance measurements concerning the anisotropy of the hyperfine field attributed to the magnetic cycloidal structure.
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Cites
WinGX suite for small-molecule single-crystal crystallography
Farrugia, L. J. (1999) · Journal of Applied Crystallography · doi:10.1107/s0021889899006020 · Cited by 18,930
Multiferroic and magnetoelectric materials
Eerenstein, W., Mathur, N. D., & Scott, J. F. (2006) · Nature · doi:10.1038/nature05023 · Cited by 8,002
Epitaxial BiFeO 3 Multiferroic Thin Film Heterostructures
Wang, J., Neaton, J. B., Zheng, H., Nagarajan, V., Ogale, S. B., Liu, B., Viehland, D., Vaithyanathan, V., Schlom, D. G., Waghmare, U. V., et al. (2003) · Science · doi:10.1126/science.1080615 · Cited by 6,217
Spiral magnetic ordering in bismuth ferrite
Sosnowska, I., Neumaier, T. P., & Steichele, E. (1982) · Journal of Physics C: Solid State Physics · doi:10.1088/0022-3719/15/23/020 · Cited by 1,689
First-principles study of spontaneous polarization in multiferroicBiFeO3
Neaton, J. B., Ederer, C., Waghmare, U. V., Spaldin, N. A., & Rabe, K. M. (2005) · Physical Review B · doi:10.1103/physrevb.71.014113 · Cited by 1,462
Structure of a ferroelectric and ferroelastic monodomain crystal of the perovskite BiFeO3
Kubel, F., & Schmid, H. (1990) · Acta Crystallographica Section B Structural Science · doi:10.1107/s0108768190006887 · Cited by 1,317
Electrical control of antiferromagnetic domains in multiferroic BiFeO3 films at room temperature
Zhao, T., Scholl, A., Zavaliche, F., Lee, K., Barry, M., Doran, A., Cruz, M. P., Chu, Y. H., Ederer, C., Spaldin, N. A., et al. (2006) · Nature Materials · doi:10.1038/nmat1731 · Cited by 1,297
Lebeugle, D., Colson, D., Forget, A., & Viret, M. (2007) · Applied Physics Letters · doi:10.1063/1.2753390 · Cited by 674
Self-citationInfluence of parasitic phases on the properties of BiFeO3 epitaxial thin films
Béa, H., Bibes, M., Barthélémy, A., Bouzehouane, K., Jacquet, E., Khodan, A., Contour, J.-P., Fusil, S., Wyczisk, F., Forget, A., et al. (2005) · Applied Physics Letters · doi:10.1063/1.2009808 · Cited by 411
Self-citationBai, F., Wang, J., Wuttig, M., Li, J., Wang, N., Pyatakov, A. P., Zvezdin, A. K., Cross, L. E., & Viehland, D. (2005) · Applied Physics Letters · doi:10.1063/1.1851612 · Cited by 391
Space-time parity violation and magnetoelectric interactions in antiferromagnets
Kadomtseva, A. M., Zvezdin, A. K., Popov, Y. F., Pyatakov, A. P., & Vorob’ev, G. P. (2004) · Journal of Experimental and Theoretical Physics Letters · doi:10.1134/1.1787107 · Cited by 248
Magnetic hysteresis and superantiferromagnetism in ferritin nanoparticles
Gilles, C., Bonville, P., Rakoto, H., Broto, J. M., Wong, K. K. W., & Mann, S. (2002) · Journal of Magnetism and Magnetic Materials · doi:10.1016/s0304-8853(01)00461-9 · Cited by 124
Self-citationFerroelectricity Down to at Least 2 nm in Multiferroic BiFeO3 Epitaxial Thin Films
Béa, H., Fusil, S., Bouzéhouane, K., et al. (2006) · Japanese Journal of Applied Physics · doi:10.1143/jjap.45.l187 · Cited by 61
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A Resistive Memory in Semiconducting BiFeO3 Thin‐Film Capacitors
Jiang, A. Q., Wang, C., Jin, K. J., Liu, X. B., Scott, J. F., Hwang, C. S., Tang, T. A., Lu, H. B., & Yang, G. Z. (2011) · Advanced Materials · doi:10.1002/adma.201004317 · Cited by 438
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Metadata
- Authors
- Lebeugle, D., Colson, D., Forget, A., Viret, M., Bonville, P., Marucco, J. F., & Fusil, S.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 2007-07-31
- Volume
- 76
- Issue
- 2
- ISSN
- 1098-0121 (ISSN-L)
- 1550-235X
- OpenAlex
- W1983114908
- Cited by
- 676
- References
- 13
- FWCI
- 21.43
- Type
- journal article
- Language
- en
- Open access
- green
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