The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Cavity-Controlled Chemistry in Molecular Ensembles
Open accessAbstract
The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic molecules has opened new routes to control chemical dynamics at the nanoscale. We show that strong resonant coupling of a cavity field with an electronic transition can effectively decouple collective electronic and nuclear degrees of freedom in a disordered molecular ensemble, even for molecules with high-frequency quantum vibrational modes having strong electron-vibration interactions. This type of polaron decoupling can be used to control chemical reactions. We show that the rate of electron transfer reactions in a cavity can be orders of magnitude larger than in free space for a wide class of organic molecular species.
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Cites
Vahala, K. J. (2003) · Nature · doi:10.1038/nature01939 · Cited by 4,878
Grabowski, Z. R., Rotkiewicz, K., & Rettig, W. (2003) · Chemical Reviews · doi:10.1021/cr940745l · Cited by 3,714
Electron transfer reactions in chemistry. Theory and experiment
Marcus, R. A. (1993) · Reviews of Modern Physics · doi:10.1103/revmodphys.65.599 · Cited by 3,667
Room-Temperature Polariton Lasing in an Organic Single-Crystal Microcavity
Kéna-Cohen, S., & Forrest, S. R. (2010) · Nature Photonics · doi:10.1038/nphoton.2010.86 · Cited by 942
Cited by
Tilting a ground-state reactivity landscape by vibrational strong coupling
Thomas, A., Lethuillier-Karl, L., Nagarajan, K., Vergauwe, R. M. A., George, J., Chervy, T., Shalabney, A., Devaux, E., Genet, C., Moran, J., et al. (2019) · Science · doi:10.1126/science.aau7742 · Cited by 852
Polaritonic Chemistry with Organic Molecules
Feist, J., Galego, J., & Garcia-Vidal, F. J. (2018) · ACS Photonics · doi:10.1021/acsphotonics.7b00680 · Cited by 438
Cavity QED with quantum gases: new paradigms in many-body physics
Mivehvar, F., Piazza, F., Donner, T., & Ritsch, H. (2021) · Advances in Physics · doi:10.1080/00018732.2021.1969727 · Cited by 336
Theoretical Advances in Polariton Chemistry and Molecular Cavity Quantum Electrodynamics
Mandal, A., Taylor, M. A. D., Weight, B. M., Koessler, E. R., Li, X., & Huo, P. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00855 · Cited by 270
Quantum Information and Computation for Chemistry
Olson, J., Cao, Y., Romero, J., Johnson, P., Dallaire-Demers, P.-L., Sawaya, N., Narang, P., Kivlichan, I., Wasielewski, M., & Aspuru-Guzik, A. (2017) · arXiv · doi:10.48550/arxiv.1706.05413 · Cited by 15
“Progress in quantum electrodynamical density-functional theory and Cavity Born-Oppenheimer approximation methods could play a key role in the prediction (Frediani and Sundholm, 2015; Herrera and Spano, 2016) and design of novel experiments, as identified in the workshop.”
Method
Metadata
- Authors
- Herrera, F., & Spano, F. C.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2016-06-08
- Volume
- 116
- Issue
- 23
- Pages
- 238301-238301
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2200146405
- Cited by
- 581
- References
- 4
- FWCI
- 21.91
- Type
- journal article
- Language
- en
- Open access
- green
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