The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Formation and Splitting of Paired Hydroxyl Groups on ReducedTiO2(110)
Abstract
A combination of high-resolution scanning tunneling microscopy and density functional theory is utilized to study the interaction of water with the reduced TiO2(110)-(1 x 1) surface. As the direct product of water dissociation in oxygen vacancies, paired hydroxyl groups are formed. These pairs are immobile and stable unless they interact with adsorbed water molecules. As a result of these interactions, protons are transferred to adjacent oxygen rows, thereby forming single hydroxyl groups. Additionally, we show that hydroxyl groups facilitate the diffusion of water molecules over the oxygen rows.
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Cites
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Self-citationWendt, S., Schaub, R., Matthiesen, J., Vestergaard, E. K., Wahlström, E., Rasmussen, M. D., Thostrup, P., Molina, L. M., Lægsgaard, E., Stensgaard, I., et al. (2005) · Surface Science · doi:10.1016/j.susc.2005.08.041 · Cited by 600
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Cited by
Fundamentals of TiO2 Photocatalysis: Concepts, Mechanisms, and Challenges
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Electronic Structure of Defect States in Hydroxylated and Reduced RutileTiO2(110)Surfaces
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Single Molecule Photocatalysis on TiO2 Surfaces: Focus Review
Guo, Q., Ma, Z., Zhou, C., Ren, Z., & Yang, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00226 · Cited by 371
Metadata
- Authors
- Wendt, S., Matthiesen, J., Schaub, R., Vestergaard, E. K., Lægsgaard, E., Besenbacher, F., & Hammer, B.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2006-02-14
- Volume
- 96
- Issue
- 6
- Pages
- 066107-066107
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2059426590
- Cited by
- 419
- References
- 18
- FWCI
- 23.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wendt, S., Matthiesen, J., Schaub, R., Vestergaard, E. K., Lægsgaard, E., Besenbacher, F., & Hammer, B. (2006). Formation and Splitting of Paired Hydroxyl Groups on ReducedTiO2(110). Physical Review Letters. https://doi.org/10.1103/physrevlett.96.066107
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