Charge-transfer dynamics studied using resonant core spectroscopies
Abstract
The authors review the use of core-level resonant photoemission and resonant Auger spectroscopy to study femtosecond charge-transfer dynamics. Starting from simple models of the relevant processes, they examine the rationale for this approach and illustrate the approximations and known subtleties for the inexperienced experimentalist. Detailed analysis of case studies of increasing complexity are taken up, as well as the connection to related approaches using both valence excitation and the core-level fluorescent channel.
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Until recently, charge transfer studies after inner-shell photoabsorption were limited to measurements in the energy domain because of the lack of short x-ray pulses.
“However, until recently, these studies were limited to measurements in the energy domain [83] because of the lack of short x-ray pulses.”
From Roadmap of ultrafast x-ray atomic and molecular physics (2018) · cites this paper as [83]
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Self-citation
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- Authors
- Brühwiler, P. A., Karis, O., & Mårtensson, N.
- Affiliations
- Uppsala University (SE)
- Venue
- Reviews of Modern Physics
- Publisher
- American Physical Society (APS)
- Published
- 2002-07-12
- Volume
- 74
- Issue
- 3
- Pages
- 703-740
- ISSN
- 0034-6861 (ISSN-L)
- 1539-0756
- OpenAlex
- W2082594363
- Cited by
- 372
- References
- 170
- Citations by year
- 2026: 9 · 2025: 15 · 2024: 4 · 2023: 9 · 2022: 9 · 2021: 16 · 2020: 14 · 2019: 7 · 2018: 16 · 2017: 25 · 2016: 15 · 2015: 27 · 2014: 23 · 2013: 25 · 2012: 18
- FWCI
- 7.13
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Reviews of Modern Physics (publishedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Laser-Matter Interactions and Applications
- Physical Sciences › Physics and Astronomy › Radiation › X-ray Spectroscopy and Fluorescence Analysis
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › Electron and X-Ray Spectroscopy Techniques
- Keywords
- charge transfer dynamics, femtosecond dynamics, resonant Auger spectroscopy, core-level spectroscopy, valence excitations, ultrafast electron dynamics
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