The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Catalytic nanoarchitectures—The importance of nothing and the unimportance of periodicity
Abstract
Heterogeneous catalysis has always been an inherently nanoscopic phenomenon with important technological and societal consequences for energy conversion and the production of chemicals. New opportunities for improved performance arise when the multifunctionality inherent in catalytic processes, including molecular transport of reactants and products, is rethought in light of architectures designed and fabricated from the appropriate nanoscale building blocks, including the use of "nothing" (void space) and deliberate disorder as design components. Architectures with all of the appropriate electrochemical and catalytic requirements, including large surface areas readily accessible to molecules, may now be assembled on the benchtop. Designing catalytic nanoarchitectures that depart from the hegemony of periodicity and order offers the promise of even higher activity.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the citing paper
“With these unique features, porous materials present great value for applications in energy conversion and storage [132,133,134,135], catalysis [136], drug delivery [137], gas capture [138,139], and water purification [140,141].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [136]
In the citing paper
“Larger pore size facilitates a more efficient diffusion of guest molecules within the pores [136], and also allows the loading of metal catalyst particles [154,155].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [136]
Citations
Cites
Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
Synthesis of thiol-derivatised gold nanoparticles in a two-phase Liquid–Liquid system
Brust, M., Walker, M., Bethell, D., Schiffrin, D. J., & Whyman, R. (1994) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39940000801 · Cited by 6,714
Ordered porous materials for emerging applications
Davis, M. E. (2002) · Nature · doi:10.1038/nature00785 · Cited by 5,308
Valden, M., Lai, X., & Goodman, D. W. (1998) · Science · doi:10.1126/science.281.5383.1647 · Cited by 4,151
(1990) · Elsevier eBooks · doi:10.1016/c2009-0-22386-5 · Cited by 3,311
Monolayer-Protected Cluster Molecules
Templeton, A. C., Wuelfing, W. P., & Murray, R. W. (1999) · Accounts of Chemical Research · doi:10.1021/ar9602664 · Cited by 2,387
Chemistry of Aerogels and Their Applications
Pierre, A. C., & Pajonk, G. M. (2002) · Chemical Reviews · doi:10.1021/cr0101306 · Cited by 2,239
Surface science studies of model fuel cell electrocatalysts
Markovic, N. (2002) · Surface Science Reports · doi:10.1016/s0167-5729(01)00022-x · Cited by 2,172
Bond, G. C., & Thompson, D. T. (1999) · Catalysis Reviews · doi:10.1081/cr-100101171 · Cited by 1,727
Amphiphilic Block Copolymers in Structure-Controlled Nanomaterial Hybrids
Förster, S., & Antonietti, M. (1998) · Advanced Materials · doi:10.1002/(sici)1521-4095(199802)10:3 · Cited by 1,256
A general template-based method for the preparation of nanomaterials
Hulteen, J. C., & Martin, C. R. (1997) · Journal of Materials Chemistry · doi:10.1039/a700027h · Cited by 1,054
Non-siliceous Mesostructured and Mesoporous Materials
Schüth, F. (2001) · Chemistry of Materials · doi:10.1021/cm011030j · Cited by 845
Schmidt‐Winkel, P., Lukens, W. W., Yang, P., Margolese, D. I., Lettow, J. S., Ying, J. Y., & Stucky, G. D. (2000) · Chemistry of Materials · doi:10.1021/cm991097v · Cited by 581
Silica Sol as a Nanoglue: Flexible Synthesis of Composite Aerogels
Morris, C. A., Anderson, M. L., Stroud, R. M., Merzbacher, C. I., & Rolison, D. R. (1999) · Science · doi:10.1126/science.284.5414.622 · Cited by 409
Self-citationElectrically conductive oxide aerogels: new materials in electrochemistry
Rolison, D. R., & Dunn, B. (2001) · Journal of Materials Chemistry · doi:10.1039/b007591o · Cited by 357
Self-citationHow To Make Electrocatalysts More Active for Direct Methanol OxidationAvoid PtRu Bimetallic Alloys!
Long, J. W., Stroud, R. M., Swider‐Lyons, K. E., & Rolison, D. R. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp001954e · Cited by 347
Self-citationDmowski, W., Egami, T., Swider‐Lyons, K. E., Love, C. T., & Rolison, D. R. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp026228l · Cited by 314
Self-citationApplications of Sol−Gel-Processed Interphase Catalysts
Lu, Z., Lindner, E., & Mayer, H. A. (2002) · Chemical Reviews · doi:10.1021/cr010358t · Cited by 272
SCHNEIDER, M., & Baiker, A. (1995) · Catalysis Reviews · doi:10.1080/01614949508006450 · Cited by 251
Mukerjee, S., & Urian, R. C. (2002) · Electrochimica Acta · doi:10.1016/s0013-4686(02)00242-6 · Cited by 218
Anderson, M. L., Stroud, R. M., & Rolison, D. R. (2002) · Nano Letters · doi:10.1021/nl015707d · Cited by 198
Self-citationPolarz, S., & Antonietti, M. (2002) · Chemical Communications · doi:10.1039/b205708p · Cited by 197
Toshima, N., Shiraishi, Y., Teranishi, T., Miyake, M., Tominaga, T., Watanabe, H., Brijoux, W., Bönnemann, H., & Schmid, G. (2001) · Applied Organometallic Chemistry · doi:10.1002/aoc.146 · Cited by 176
Leventis, N., Elder, I. A., Rolison, D. R., Anderson, M. L., & Merzbacher, C. I. (1999) · Chemistry of Materials · doi:10.1021/cm9901966 · Cited by 163
Self-citationUsing Three Dimensions in Catalytic Mesoporous Nanoarchitectures
Pietron, J. J., Stroud, R. M., & Rolison, D. R. (2002) · Nano Letters · doi:10.1021/nl025536s · Cited by 148
Self-citationDouble Layer Capacitance and Charging Rate of Ultramicroporous Carbon Electrodes
Koresh, J. E., & Soffer, A. (1977) · Journal of The Electrochemical Society · doi:10.1149/1.2133657 · Cited by 113
Armstrong, D. R., Kennedy, A. R., Mulvey, R. E., & Rowlings, R. B. (1999) · Angewandte Chemie International Edition · doi:10.1002/(sici)1521-3773(19990115)38:1/2 · Cited by 107
McBreen, J., Olender, H., Srinivasan, S. G., & KORDESCH, K. V. (1981) · Journal of Applied Electrochemistry · doi:10.1007/bf00615184 · Cited by 76
Feature articls. Doped glassy carbon: a new material for electrocatalysis
Pocard, N. L., Alsmeyer, D. C., McCreery, R. L., Neenan, T. X., & Callstrom, M. R. (1992) · Journal of Materials Chemistry · doi:10.1039/jm9920200771 · Cited by 76
Bringing Fuel Cells Down to Earth
Service, R. F. (1999) · Science · doi:10.1126/science.285.5428.682 · Cited by 60
The Chemical State of Sulfur in Carbon‐Supported Fuel‐Cell Electrodes
Swider, K. E., & Rolison, D. R. (1996) · Journal of The Electrochemical Society · doi:10.1149/1.1836542 · Cited by 54
Self-citationTailoring Advanced Nanoscale Materials Through Synthesis of Composite Aerogel Architectures
Anderson, M. L., Stroud, R. M., Morris, C. A., Merzbacher, C. I., & Rolison, D. R. (2000) · Advanced Engineering Materials · doi:10.1002/1527-2648(200008)2:8 · Cited by 52
Self-citationStroud, R. M., Long, J. W., Swider‐Lyons, K. E., & Rolison, D. R. (2002) · Microscopy and Microanalysis · doi:10.1017/s1431927602010097 · Cited by 25
Self-citationA new electrocatalyst consisting of a molecularly homogeneous platinum–aerogel nanocomposite
Ye, S., Vijh, A. K., Wang, Z., & Dao, L. H. (1997) · Canadian Journal of Chemistry · doi:10.1139/v97-198 · Cited by 16
Research works printed but not linked: 1
- K. E. Swider-Lyons G. B. Cotton J. A. Stanley W. Dmowski T. Egami in 2002 Annual Progress Report for the Hydrogen Fuel Cells and Infrastructure Technologies Program (U.S. Department of Energy Washington DC 2002) pp. 413–417.
Cited by
Sorted by citations
A review of electrode materials for electrochemical supercapacitors
Wang, G., Zhang, L., & Zhang, J. J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15060j · Cited by 9,228
Recent Advances in the Liquid-Phase Syntheses of Inorganic Nanoparticles
Cushing, B. L., Kolesnichenko, V. L., & O’Connor, C. J. (2004) · Chemical Reviews · doi:10.1021/cr030027b · Cited by 2,973
High-performance lithium-ion anodes using a hierarchical bottom-up approach
Magasinski, A., Dixon, P., Hertzberg, B. J., Kvit, A. V., Ayala, J., & Yushin, G. N. (2010) · Nature Materials · doi:10.1038/nmat2725 · Cited by 2,052
Wang, D.-W., Li, F., Liu, M., Lu, G., & Cheng, H.-M. (2008) · Angewandte Chemie · doi:10.1002/anie.200702721 · Cited by 1,999
Li, X., Yu, J., & Jaroniec, M. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00838g · Cited by 1,820
Metadata
- Authors
- Rolison, D. R.
- Affiliations
- United States Naval Research Laboratory (US)
- Corresponding author
- Rolison, Debra R.
- ORCID
- Rolison, Debra R.
- Venue
- Science
- Published
- 2003-03-14
- Volume
- 299
- Issue
- 5613
- Pages
- 1698-1701
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1965751645
- Cited by
- 1,037
- References
- 35
- Citations by year
- 2026: 10 · 2025: 16 · 2024: 13 · 2023: 19 · 2022: 22 · 2021: 22 · 2020: 19 · 2019: 24 · 2018: 45 · 2017: 53 · 2016: 63 · 2015: 55 · 2014: 53 · 2013: 67 · 2012: 73
- FWCI
- 33.53
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Keywords
- heterogeneous catalysis, voids, disorder, aperiodic structures, molecular transport, surface area, electrocatalysis, nanoscale building blocks, catalyst design
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
