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High-Performance Silicon Photoanodes Passivated with Ultrathin Nickel Films for Water Oxidation
Abstract
Stabilizing Silicon: Solar-driven water splitting has potential as an energy storage mechanism to supplement the direct conversion of sunlight to electricity. A submersed integrated device has been proposed both to absorb the light and to catalyze the reaction, but stability has been a problem. Kenney et al. (p. 836 ; see the Perspective by Turner ) found that a nickel coating, thin enough to let light through, could protect a silicon absorber in the alkaline environment of a lithium/potassium borate electrolyte. The nickel also functioned as the oxidation catalyst, and the lithium ions helped to establish a protective film structure in situ.
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Self-citation
Metadata
- Authors
- Kenney, M. J., Gong, M., Li, Y., Wu, J. Z., Feng, J., Lanza, M., & Dai, H.
- Venue
- Science
- Published
- 2013-11-15
- Volume
- 342
- Issue
- 6160
- Pages
- 836-840
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2015855251
- Cited by
- 689
- References
- 0
- FWCI
- 25.49
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kenney, M. J., Gong, M., Li, Y., Wu, J. Z., Feng, J., Lanza, M., & Dai, H. (2013). High-Performance Silicon Photoanodes Passivated with Ultrathin Nickel Films for Water Oxidation. Science. https://doi.org/10.1126/science.1241327
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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