The DOI matches its Crossref record; 89 of the 92 references it cites were found in a registry or an index.
The Early Faint Sun Paradox: Organic Shielding of Ultraviolet-Labile Greenhouse Gases
Abstract
Atmospheric mixing ratios of ∼10 −5 ± 1 for ammonia on the early Earth would have been sufficient, through the resulting greenhouse warming, to counteract the temperature effects of the faint early sun. One argument against such model atmospheres has been the short time scale for ammonia photodissociation by solar ultraviolet light. Here it is shown that ultraviolet absorption by steady-state amounts of high-altitude organic solids produced from methane photolysis may have shielded ammonia sufficiently that ammonia resupply rates were able to maintain surface temperatures above freezing.
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In the citing paper
“Possibly, a stratospheric organic haze, such as that on Saturn’s moon, Titan, shielded tropospheric NH3 from UV (162).”
From The Archean atmosphere (2020) · cites this paper as [162]
In the citing paper
“Earlier, we noted that an organic haze might protect tropospheric ammonia from UV (162), but whether NH3 was a viable greenhouse gas is unclear.”
From The Archean atmosphere (2020) · cites this paper as [162]
Citations
Cites
Woese, C. R. (1987) · Microbiological Reviews · doi:10.1128/mr.51.2.221-271.1987 · Cited by 5,042
The Chemical Evolution of the Atmosphere and Oceans
Holland, H. D. (1984) · doi:10.1515/9780691220239 · Cited by 1,836
The Carbon Cycle and Atmospheric CO2 : Natural Variations Archean to Present
Sundquist, E. T., & Broecker, W. S. (1985) · Geophysical monograph · doi:10.1029/gm032 · Cited by 1,659
Organic Compound Synthesis on the Primitive Earth
Miller, S. L., & Urey, H. C. (1959) · Science · doi:10.1126/science.130.3370.245 · Cited by 1,403
Evidence for life on Earth before 3,800 million years ago
Mojzsis, S. J., Arrhenius, G., McKeegan, K. D., Harrison, T. M., Nutman, A. P., & Friend, C. R. L. (1996) · Nature · doi:10.1038/384055a0 · Cited by 1,370
Chyba, C., & Sagan, C. (1992) · Nature · doi:10.1038/355125a0 · Cited by 1,321
Self-citationEarth and Mars: evolution of atmospheres and surface temperatures
Sagan, C., & Mullen, G. (1972) · Science · doi:10.1126/science.177.4043.52 · Cited by 942
Self-citationOptical constants from the far infrared to the x-ray region: Mg, Al, Cu, Ag, Au, Bi, C, and Al_2O_3
Hagemann, H. ‐., Gudat, W., & Kunz, C. (1975) · Journal of the Optical Society of America · doi:10.1364/josa.65.000742 · Cited by 897
Solar interior structure and luminosity variations
Gough, D. O. (1981) · Solar Physics · doi:10.1007/bf00151270 · Cited by 798
Ancient oceans, ice sheets and the hydrological cycle on Mars
Baker, V. R., Strom, R. G., Gulick, V. C., Kargel, J. S., Komatsu, G., & Kale, V. S. (1991) · Nature · doi:10.1038/352589a0 · Cited by 714
Research works printed but not linked: 15
- Wang W. C., Stoner P. H., ibid. 37, 545 (1980) .
- Eiler J. M., Mojzsis S. J., Arrhenius G., ibid. 386, 665 (1997).
- Karhu J., Epstein S., ibid. 50, 1745 (1986)].
- ]. On an Earth as warm as or warmer than today cloud feedback effects do not seem to be the answer [J. F. Kasting and D. H. Grinspoon in The Sun in Time C. P. Sonett M. S. Giampapa M. S. Matthews Eds. (Univ. of Arizona Press Tucson 1991) pp. 447–462].
- J. B. Pollack and C. Sagan in Near Earth Resources J. Lewis and M. Matthews Eds. (Univ. of Arizona Press Tucson 1993)
- J. M. Goldspiel thesis Cornell University (1994). An upper limit on the total amount of CO 2 ice in a martian polar cap can be set by the condition that it not liquefy at its base as a result of hydrostatic pressure load giving an upper limit of ∼60 mbar CO 2 [
- Sagan C., J. Geophys. Res. 78, 1250 (1973)].
- Khare B. N., Sagan C., Bandurski E. L., Nagy B., ibid. 199, 1199 (1978)].
- Sagan C., Thompson W. R., ibid. 59, 133 (1984).
- CH 4 is present at 0.1 to 1% of [H 2 O] in comets [M. J. Mumma P. R. Weissman S. A. Stern in Protostars and Planets III E. H. Levy and J. I. Lunine Eds. (Univ. of Arizona Tucson 1993) pp. 1177–1252]. For an impactor mass flux ∼5 × 10 14 g year −1 around 4 Ga (11) exogenous CH 4 supply provided <1% of the required flux.
- C. F. Chyba T. C. Owen W.-H. Ip in Hazards Due to Comets and Asteroids T. Gehrels Ed. (Univ. of Arizona Press Tucson 1994) pp. 9–58.
- C. Sagan B. N. Khare J. Lewis in Saturn T. Gehrels and M. S. Matthews Eds. (Univ. of Arizona Press Tucson 1984) pp. 788–807.
- Jenniskens P., Astron. Astrophys. 272, 465 (1993).
- Greenberg J. M., Hage J. I., ibid. 361, 260 (1990).
- Bussoletti E., Colangeli L., Borghesi A., Orofino V., Astron. Astrophys. Suppl. Ser. 70, 257 (1987).
Cited by
Sorted by citations
Atmospheric Influence of Earth's Earliest Sulfur Cycle
Farquhar, J., Bao, H., & Thiemens, M. (2000) · Science · doi:10.1126/science.289.5480.756 · Cited by 1,805
The habitat and nature of early life
Nisbet, E. G., & Sleep, N. H. (2001) · Nature · doi:10.1038/35059210 · Cited by 930
Martin, W., & Russell, M. J. (2003) · Philosophical Transactions of the Royal Society of London. Series B: Biological Sciences · doi:10.1098/rstb.2002.1183 · Cited by 856
Ribas, I., Guinan, E. F., Güdel, M., & Audard, M. (2005) · The Astrophysical Journal · doi:10.1086/427977 · Cited by 871
Hazen, R. M., Papineau, D., Bleeker, W., Downs, R. T., Ferry, J. M., McCoy, T. J., Sverjensky, D. A., & Yang, H. (2008) · American Mineralogist · doi:10.2138/am.2008.2955 · Cited by 701
Metadata
- Authors
- Sagan, C., & Chyba, C.
- Affiliations
- University of Arizona (US)
- Venue
- Science
- Published
- 1997-05-23
- Volume
- 276
- Issue
- 5316
- Pages
- 1217-1221
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1964099544
- Cited by
- 396
- References
- 92
- Citations by year
- 2026: 7 · 2025: 10 · 2024: 12 · 2023: 11 · 2022: 8 · 2021: 9 · 2020: 18 · 2019: 5 · 2018: 14 · 2017: 14 · 2016: 11 · 2015: 7 · 2014: 16 · 2013: 25 · 2012: 17
- FWCI
- 14.02
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Space and Planetary Science › Astro and Planetary Science
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Environmental Science › Global and Planetary Change › Earth Systems and Cosmic Evolution
- Keywords
- early Earth, ammonia, greenhouse gases, UV protection, organic solids, methane photolysis, ammonia photodissociation, atmospheric mixing ratios, surface temperature, early atmosphere
- MeSH terms
- Ammonia, Atmosphere, Carbon Dioxide, Methane, Models, Chemical, Photolysis, Ultraviolet Rays, Solar System, Greenhouse Effect, Earth, Planet, Evolution, Planetary
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