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Cited by 628Laser-Matter Interactions and ApplicationsSpectroscopy and Quantum Chemical StudiesTerahertz technology and applications

Measurement and laser control of attosecond charge migration in ionized iodoacetylene

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Kraus, P. M., Mignolet, B., Baykusheva, D., Rupenyan, A., Horný, L., Penka, E. F., Grassi, G., Tolstikhin, O. I. +6 more·2015·Science
DOI 10.1126/science.aab2160
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Abstract

Electronic movement flashing into view: Numerous chemical processes begin with ionization: the ejection of an electron from a molecule. What happens in the immediate aftermath of that event? Kraus et al. explored this question in iodoacetylene by detecting and analyzing the spectrum of emitted high harmonics (see the Perspective by Ueda). They traced the migration of the residual positively charged hole along the molecular axis on a time scale faster than a quadrillionth of a second. They thereby characterized the capacity of a laser field to steer the hole's motion in appropriately oriented molecules. Science , this issue p. 790 ; see also p. 740

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  • More recent experiments have addressed correlated two-electron dynamics, attosecond to few-femtosecond charge migration in molecules, and electric field-induced charge separation in solids.

    “More recent experiments have addressed correlated two-electron dynamics [169], attosecond to few-femtosecond charge migration in molecules [170, 171] and electric field-induced charge separation in solids [172].”

    From Roadmap of ultrafast x-ray atomic and molecular physics (2018) · cites this paper as [171]

  • Most recently, attosecond photoionization delays have been measured in molecules and high-harmonic spectroscopy has been developed to reconstruct charge migration in spatially oriented molecules on attosecond timescales.

    “Most recently, attosecond photoionization delays have been measured in molecules [200] and highharmonic spectroscopy has been developed further to reconstruct charge migration in spatially oriented molecules on attosecond timescales [171].”

    From Roadmap of ultrafast x-ray atomic and molecular physics (2018) · cites this paper as [171]

  • This challenge has been addressed by extensive computational work but will impose a limit on complexity of samples that can be investigated in the future.

    “This challenge has been addressed by extensive computational work in the past (see e.g.[170, 171]), but will clearly impose a limit on the complexity of the samples that can be investigated in the future.”

    From Roadmap of ultrafast x-ray atomic and molecular physics (2018) · cites this paper as [171]

  • The field already provides novel measurements of electron re-collision.

    “electron re-collision [171, 211]”

    From Roadmap of ultrafast x-ray atomic and molecular physics (2018) · cites this paper as [171]

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Authors
Kraus, P. M., Mignolet, B., Baykusheva, D., Rupenyan, A., Horný, L., Penka, E. F., Grassi, G., Tolstikhin, O. I., Schneider, J., Jensen, F., Madsen, L. B., Bandrauk, A. D., Remacle, F., & Wörner, H. J.
Affiliations
  • ETH Zurich (CH)
  • University of Liège (BE)
  • Laboratorium für Physikalische Chemie, ETH Zürich, 8093 Zürich, Switzerland.
  • Laboratoire de Chimie Théorique, Université de Sherbrooke, Sherbrooke, Quebec J1K 2R1, Canada.
  • Moscow Institute of Physics and Technology (RU)
  • Aarhus University (DK)
  • Université de Sherbrooke (CA)
Corresponding author
Wörner, H. J.
ORCID
Venue
Science
Publisher
American Association for the Advancement of Science (AAAS)
Published
2015-11-13
Volume
350
Issue
6262
Pages
790-795
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
DOI
10.1126/science.aab2160
OpenAlex
W2179476998
Cited by
628
References
101
Citations by year
2026: 40 · 2025: 44 · 2024: 64 · 2023: 48 · 2022: 64 · 2021: 61 · 2020: 51 · 2019: 65 · 2018: 68 · 2017: 77 · 2016: 44 · 2015: 2
FWCI
32.32
Type
journal article
Language
en
Open access
Licence
Locations
  • Science (publishedVersion)
  • PubMed (publishedVersion)
  • Repository for Publications and Research Data (ETH Zurich) (submittedVersion, other-oa)
  • Open Repository and Bibliography (University of Liège) (submittedVersion)
  • ETH Zürich Research Collection
Funders
  • Belgian American Education Foundation
  • ERC (307270-ATTOSCOPE)
  • Swiss National Science Foundation
  • Fonds National de la Recherche Scientifique of Belgium
  • Fonds de la Recherche Fondamentale Collective (2.4545.12)
  • Wallonie-Bruxelles International
Topics
  • Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Laser-Matter Interactions and Applications
  • Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Terahertz technology and applications
Keywords
high-harmonic spectroscopy, electron-hole dynamics, ionization, molecular orientation

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