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Vapor-assisted deposition of highly efficient, stable black-phase FAPbI 3 perovskite solar cells
Open accessAbstract
Moving a perovskite into the black: The bandgap of the black α-phase FAPbI 3 (where FA is formamidinium) is nearly ideal for solar cells, but it is unstable with respect to the photoinactive yellow δ-phase. Lu et al. found that a film of the yellow phase was converted to a highly crystalline black phase by vapor exposure to methylammonium thiocyanate at 100°C, and it retained this structure after 500 hours at 85°C. Solar cells fabricated with this material had a power conversion efficiency of more than 23%. After 500 hours under maximum power tracking and a period of dark recovery, 94% of the original efficiency was retained. Science , this issue p. eabb8985
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Metadata
- Authors
- Lu, H., Liu, Y., Ahlawat, P., Mishra, A., Tress, W. R., Eickemeyer, F. T., Yang, Y., Fu, F., Wang, Z., Avalos, C. E., Carlsen, B. I., Agarwalla, A., Zhang, X., Li, X., Zhan, Y., Zakeeruddin, S. M., Emsley, L., Rothlisberger, U., Zheng, L., Hagfeldt, A., & Grätzel, M.
- Venue
- Science
- Published
- 2020-10-02
- Volume
- 370
- Issue
- 6512
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W3091523599
- Cited by
- 815
- References
- 58
- FWCI
- 42.03
- Type
- journal article
- Language
- en
- Open access
- green
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