Palladium extraction by a cyanex 301-based binary extractant from chloride solutions
Abstract
We studied the extraction of chloropalladium complexes by solutions of trioctylmethylammonium di(2,4,4-trimethylpentyl)dithiophosphinate in toluene over a wide range of aqueous acidities. Distribution factors and spectroscopic studies of extraction products showed that (R4N)[Pd2Cl4A] complexes are formed in the organic phase during extraction under near-saturation conditions. As the concentration of the binary extractant or dialkyldithiophosphinic acid increases, palladium di(2,4,4-trimethylpentyl)dithiophosphinate is formed in the organic phase.
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Cyanex 301 and Cyanex 302 have high affinity for silver and palladium present in concentrated HCl solutions owing to strong interactions between soft bases (extractants) and soft acids (metal ions).
“Additionally, Cyanex 301 and Cyanex 302 are considered to have a high a nity for the silver and palladium present in concentrated HCl solutions owing to the strong interactions between soft bases (extractants) and soft acids (metal ions) [30-32].”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [32]
Cites
Wei, Y., Kumagai, M., TAKASHIMA, Y., Modolo, G., & Odoj, R. (2000) · Nuclear Technology · doi:10.13182/nt00-a3154 · Cited by 193 · see citing works
COBALT-NICKEL SEPARATION BY SOLVENT EXTRACTION WITH BIS(2,4,4 TRIMETHYLPENTYL)PHOSPHINIC ACID
Rickelton, W. A., Flett, D. S., & West, D. W. (1984) · Solvent Extraction and Ion Exchange · doi:10.1080/07366298408918476 · Cited by 126 · see citing works
Reddy, M. L. P., Bharathi, J. R. B., Peter, S., & Ramamohan, T. R. (1999) · Talanta · doi:10.1016/s0039-9140(99)00106-x · Cited by 95 · see citing works
Trivalent minor actinides/lanthanides separation, using organophosphinic acids
Hill, C., Madic, C., Baron, P., Ozawa, M., & Tanaka, Y. (1998) · Journal of Alloys and Compounds · doi:10.1016/s0925-8388(98)00045-0 · Cited by 88 · see citing works
Ionova, G. V., Ionov, S., Rabbe, C., Hill, C., Madic, C., Guillaumont, R., & Krupa, J. (2001) · Solvent Extraction and Ion Exchange · doi:10.1081/sei-100103277 · Cited by 83 · see citing works
Hinojosa‐Reyes, L., Medina, I., Navarro, R., Revilla, J., Rodríguez, M. A., & Guibal, E. (2001) · Industrial & Engineering Chemistry Research · doi:10.1021/ie0005349 · Cited by 71 · see citing works
Analytical Chemistry of the Platinum Metals
W., W. (1973) · Platinum Metals Review · doi:10.1595/003214073x1726565 · Cited by 67 · see citing works
Ionova, G. V., Ionov, S. G., Rabbe, C., Hill, C., Madic, C., Guillaumont, R., Modolo, G., & Krupa, J. C. (2001) · New Journal of Chemistry · doi:10.1039/b006745h · Cited by 51 · see citing works
Singh, R., Kliwaja, A. R., Gupta, B., & Tandon, S. N. (1999) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299908934618 · Cited by 47 · see citing works
Removal of Heavy Metals and Lanthanides from Industrial Phosphoric Acid Process Liquors
KOOPMAN, C., WITKAMP, G. J., & VAN ROSMALEN, G. M. (1999) · Separation Science and Technology · doi:10.1081/ss-100100818 · Cited by 39 · see citing works
Cavell, R. G., Byers, W., Day, E. D., & Watkins, P. M. (1972) · Inorganic Chemistry · doi:10.1021/ic50113a028 · Cited by 38 · see citing works
Extraction equilibria of some transition metal ions by bis(2-ethylhexyl)phosphinic acid
Nagaosa, Y. (1997) · Talanta · doi:10.1016/s0039-9140(96)02047-4 · Cited by 32 · see citing works
Hoshi, H., Tsuyoshi, A., & Akiba, K. (2000) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1023/a:1010641413379 · Cited by 19 · see citing works
Separation of americium from europium by biopolymer microcapsules enclosing Cyanex 301 extractant
Mimura, H., Hoshi, H., Akiba, K., & Onodera, Y. (2001) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1023/a:1006770021710 · Cited by 19 · see citing works
Chen, J., Jiao, R., & Zhu, Y. (1999) · Radiochimica Acta · doi:10.1524/ract.1999.86.34.151 · Cited by 7 · see citing works
Hoshi, H., Tsuyoshi, A., & Akiba, K. (1999) · Solvent Extraction Research and Development Japan · Cited by 1 · see citing works
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Nikoloski, A. N., & Ang, K. L. (2013) · Mineral Processing and Extractive Metallurgy Review · doi:10.1080/08827508.2013.764875 · Cited by 170 · see citing works
Selective extraction of palladium(II) from hydrochloric acid solutions with phosphonium extractants
Cieszyńska, A., & Wiśniewski, M. (2011) · Separation and Purification Technology · doi:10.1016/j.seppur.2011.05.025 · Cited by 162 · see citing works
Extractive recovery of palladium(II) from hydrochloric acid solutions with Cyphos®IL 104
Cieszyńska, A., & Wiśniewski, M. (2011) · Hydrometallurgy · doi:10.1016/j.hydromet.2011.12.006 · Cited by 153 · see citing works
Cieszyńska, A., & Wiśniewski, M. (2010) · Separation and Purification Technology · doi:10.1016/j.seppur.2010.04.001 · Cited by 138 · see citing works
Cieszyńska, A., & Wieczorek, D. (2017) · Hydrometallurgy · doi:10.1016/j.hydromet.2017.12.019 · Cited by 89 · see citing works
Recycling of Palladium from Spent Catalysts Using Solvent Extraction—Some Critical Points
Paiva, A. P. (2017) · Metals · doi:10.3390/met7110505 · Cited by 57 · see citing works
Nguyen, V. N. H., Nguyen, T. H., & Lee, M. S. (2020) · Metals · doi:10.3390/met10081105 · Cited by 55 · see citing works
Sahu, S., Mohapatra, M., & Devi, N. (2022) · Materials Today Proceedings · doi:10.1016/j.matpr.2022.05.491 · Cited by 22 · see citing works
Peng, C.-Y., & Tsai, T. (2013) · Desalination and Water Treatment · doi:10.1080/19443994.2013.826616 · Cited by 22 · see citing works
Suryavanshi, V. J., Pawar, R. R., Anuse, M. A., & Mulik, G. N. (2015) · Analytical Methods · doi:10.1039/c4ay03045a · Cited by 18 · see citing works
Artem’ev, A. V., Gusarova, N. K., Bagryanskaya, I. Y., Doronina, E. P., Verkhoturova, S. I., Sidorkin, V. F., & Trofimov, B. A. (2012) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201200947 · Cited by 13 · see citing works
Mowafy, E. A., & Shammari, A. M. A. (2019) · Russian Journal of Applied Chemistry · doi:10.1134/s1070427219020228 · Cited by 5 · see citing works
Gaikwad, A. P., Kamble, G. S., Kolekar, S. S., & Anuse, M. A. (2013) · Journal of Chemistry · doi:10.1155/2013/103192 · Cited by 4 · see citing works
Haiduc, I. (2013) · Elsevier eBooks · doi:10.1016/b978-0-12-409547-2.00884-2 · Cited by 4 · see citing works
Wpływ kwasu solnego i chlorku sodu na wydajność ekstrakcji palladu(II) reagentami fosfoniowymi
Cieszyńska, A., & Wiśniewski, M. (2011) · Zeszyty Naukowe / Uniwersytet Ekonomiczny w Poznaniu
Efficiency of the Palladium(II) Ions Removal from Acidic Media in the Extraction-Stripping Process
Cieszyńska, A. (2019) · Towaroznawcze Problemy Jakości. Polskie Towarzystwo Towaroznawcze
Mammadova, S. R. (2021) · Azerbaijan Chemical Journal · doi:10.32737/0005-2531-2021-3-67-71
Pd(II) extraction from acid solutions by bis-(2-hidroxyl-5-alkylbenzyl)amine
Mammadova, S. R. (2021) · Bulletin of the Karaganda University Chemistry series · doi:10.31489/2021ch2/24-30
- Authors
- Zhidkova, T. I., Belova, V. V., Brenno, Y. Y., Zhidkov, L. L., & Khol’kin, A. I.
- Affiliations
- Russian Academy of Sciences (RU)
- Venue
- Russian Journal of Inorganic Chemistry
- Publisher
- Pleiades Publishing Ltd
- Published
- 2009-09
- Volume
- 54
- Issue
- 9
- Pages
- 1502-1506
- ISSN
- 0036-0236 (ISSN-L)
- 1531-8613
- OpenAlex
- W2066532832
- Cited by
- 18
- References
- 16
- Citations by year
- 2022: 1 · 2021: 2 · 2020: 1 · 2019: 2 · 2017: 2 · 2015: 1 · 2013: 4 · 2012: 1
- FWCI
- 3.34
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Russian Journal of Inorganic Chemistry (publishedVersion)
- Funders
- Russian Foundation for Basic Research
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
- Physical Sciences › Chemistry › Inorganic Chemistry › Radioactive element chemistry and processing
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Keywords
- palladium extraction, Cyanex 301, chloride solutions, distribution factors, aqueous acidity, solvent extraction
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