EXTRACTION AND SEPARATION OF NICKEL(H) USING BIS (2,4,4-TRIMETHYLPENTYL) DITHIOPHOSPHINIC ACID (CYANEX 301) AND ITS RECOVERY FROM SPENT CATALYST AND ELECTROPLATING BATH RESIDUE
Abstract
The paper embodies the details on the extraction behaviour ofNi(II) along with Cr(III), Fe(ni), Mn(II), Co(II), Cu(II) and Zn(II) from sulfuric acid media employing Cyanex 301-toluene system. The effect of various parameters like concentration of acid, metal ion and extractant and nature of diluent on the extraction of Ni(II) has been studied. On the basis of the distribution data the extracting species has been proposed. The recycling capacity of the extractant has been assessed. Some binary and ternary separations have also been achieved. The practical utility of the extractant has been demonstrated by recovering Ni(II) from spent catalyst and electroplating bath residue.
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Optimum composition for stripping of Ni(II) was mixture of 5% NH4Cl and 75% ammonia.
“The optimum composition for the stripping of Ni(II) was reported to be the mixture of 5% NH4Cl and 75% ammonia [49].”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [49]
Addition of ammonium chloride to ammonia could enhance phase transfer rate and lead to good separation of the two phases.
“The addition of ammonium chloride to ammonia could enhance the phase transfer rate and lead to a good separation of the two phases.”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [49]
A mixture of ammonia and ammonium chloride was employed to strip Ni(II) from loaded Cyanex 301 by utilizing complex formation tendency between Ni(II) and ammonia.
“Along with these inorganic solutions, a mixture of ammonia and ammonium chloride was employed to strip Ni(II) from the loaded Cyanex 301 by utilizing the complex formation tendency between Ni(II) and ammonia [49].”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [49]
The decrease in the extractability of Cyanex 301 for Ni(II) from 5 M H2SO4 was insignificant within 3 days, while after 3 days, a 15% decline was observed.
“Besides, it has been reported that the decrease in the extractability of Cyanex 301 for Ni(II) from 5 M H2SO4 was insignificant within 3 days, while after 3 days, a 15% decline was observed [49].”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [49]
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- Authors
- Singh, R., Kliwaja, A. R., Gupta, B., & Tandon, S. N.
- Affiliations
- Indian Institute of Technology Roorkee (IN)
- Corresponding author
- Tandon, S.N.
- Venue
- Solvent Extraction and Ion Exchange
- Publisher
- Informa UK Limited
- Published
- 1999-03
- Volume
- 17
- Issue
- 2
- Pages
- 367-390
- ISSN
- 0736-6299 (ISSN-L)
- 1532-2262
- OpenAlex
- W2006316797
- Cited by
- 47
- References
- 9
- Citations by year
- 2026: 1 · 2022: 2 · 2021: 2 · 2020: 3 · 2019: 1 · 2018: 1 · 2017: 3 · 2016: 1 · 2014: 5 · 2013: 1 · 2012: 1
- FWCI
- 10.49
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Solvent Extraction and Ion Exchange (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
- Physical Sciences › Chemistry › Inorganic Chemistry › Radioactive element chemistry and processing
- Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
- Keywords
- nickel extraction, Cyanex 301, solvent extraction, metal ion separation, sulfuric acid medium, extractant recycling, ternary separation, distribution data
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