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Strong Correlations from Hund’s Coupling

Open access
Georges, Antoine, Medici, Luca de', Mravlje, Jernej·2013·Annual Review of Condensed Matter Physics

Abstract

Strong electronic correlations are often associated with the proximity of a Mott-insulating state. In recent years however, it has become increasingly clear that the Hund’s rule coupling (intra-atomic exchange) is responsible for strong correlations in multiorbital metallic materials that are not close to a Mott insulator. Hund’s coupling has two effects: It influences the energetics of the Mott gap and strongly suppresses the coherence scale for the formation of a Fermi liquid. A global picture has emerged recently, which emphasizes the importance of the average occupancy of the shell as a control parameter. The most dramatic effects occur away from half-filling or single occupancy. We review the theoretical understanding and physical properties of these Hund’s metals, together with the relevance of this concept to transition-metal oxides (TMOs) of the 3d, and especially 4d, series (such as ruthenates), as well as to the iron-based superconductors (iron pnictides and chalcogenides).

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Metadata

Authors
Georges, A., Medici, L. D., & Mravlje, J.
Venue
Annual Review of Condensed Matter Physics
Published
2013-04-01
Volume
4
Issue
1
Pages
137-178
ISSN
  • 1947-5454 (ISSN-L)
  • 1947-5462
OpenAlex
W2102084509
Cited by
852
References
65
FWCI
1.31
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Strong Correlations from Hund’s Coupling. https://app.cochat.ai/papers/10.1146/annurev-conmatphys-020911-125045
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Georges, A., Medici, L. D., & Mravlje, J. (2013). Strong Correlations from Hund’s Coupling. Annual Review of Condensed Matter Physics. https://doi.org/10.1146/annurev-conmatphys-020911-125045

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