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Electrocatalytic Corrosion of Carbon Support in PEMFC Cathodes
Open accessAbstract
The influence of platinum on the corrosion of carbon catalyst supports has been characterized by on-line mass spectroscopy during cyclic voltammetry, with varying Pt mass fraction, catalyst type, and temperature. The generation rates increased with higher Pt mass fraction (0, 10, and 39% balanced by Vulcan XC-72). A peak observed at approximately for Pt/C was lowered to for PtRu/C. An Arrenhius plot indicated higher apparent activation energy for production at the positive potential limit of the cyclic voltammogram on 0% Pt (carbon-only) electrode than on 39% Pt/C electrode. It was concluded that platinum accelerated the corrosion rate of the carbon catalyst support. © 2003 The Electrochemical Society. All rights reserved.
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Metadata
- Authors
- Roen, L. M., Paik, C. H., & Jarvi, T. D.
- Venue
- Electrochemical and Solid-State Letters
- Publisher
- The Electrochemical Society
- Published
- 2004
- Volume
- 7
- Issue
- 1
- Pages
- A19
- ISSN
- 1099-0062 (ISSN-L)
- OpenAlex
- W2050513027
- Cited by
- 658
- References
- 0
- FWCI
- 10.06
- Type
- journal article
- Language
- en
- Open access
- bronze
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