Cited by 344Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesBattery Modeling and Management

The DOI matches its Crossref record.

The Surface Chemistry of Lithium Electrodes in Alkyl Carbonate Solutions

Aurbach, Doron, Ein‐Ely, Yair, Zaban, Arie·1994·Journal of The Electrochemical Society

DOI 10.1149/1.2054718

Open this paper in CoChat — free account

Abstract

The chemical composition of the surface films formed on lithium in alkyl carbonate solutions was explored using surface sensitive Fourier transform infrared spectroscopy (external reflectance mode). The solvents included propylene carbonate, ethylene carbonate, and dimethyl carbonate. The salts included LiAsF 6 , LiClO 4 , LiBF 4 , and LiPF 6 . The advantages of this work over previous studies are that highly reflective Li surfaces were prepared fresh in solution and that the aging processes of the surface films initially formed could be rigorously investigated. Furthermore, these three important solvents were investigated in a single study. This work further proves that the films initially formed on Li surfaces in these solvents consist of ROCO 2 Li as the major constituents. Upon storage, the films initially formed react with trace water to form Li 2 CO 3 , which gradually also becomes a major surface species. It was found that these aging processes also depend on the salts used (for example ROCO 2 Li or Li 2 CO 3 films are not stable in LiPF 6 or LiBF 4 solutions).

Integrity signals

Registry

Crossref · 10.1149/1.2054718

Cites

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Sorted by citations

Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
Verma, P., Maire, P., & Novák, P. (2010) · Electrochimica Acta · doi:10.1016/j.electacta.2010.05.072 · Cited by 2,661
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling
An, S. J., Li, J., Daniel, C., Mohanty, D., Nagpure, S., & Wood, D. L. (2016) · Carbon · doi:10.1016/j.carbon.2016.04.008 · Cited by 2,121
“Amount of LiF increases during storage [74].”
Background
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries
Aurbach, D. (2000) · Journal of Power Sources · doi:10.1016/s0378-7753(00)00431-6 · Cited by 1,740
Self-citation
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
Li, Y., Li, Y., Pei, A., Yan, K., Sun, Y., Wu, C.-L., Joubert, L.-M., Chin, R., Koh, A. L., Yu, Y., et al. (2017) · Science · doi:10.1126/science.aam6014 · Cited by 1,547
Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries
Wang, A., Kadam, S., Li, H., Shi, S., & Qi, Y. (2018) · npj Computational Materials · doi:10.1038/s41524-018-0064-0 · Cited by 1,749
“SEI growth and battery aging: mechanisms and multi-scale modeling Though the initially formed SEI might be simple,(167) the SEI on the anode is subject to change during the electrochemical cycling process.(198,199) Its evolution, due to the above-mentioned mechanical and chemical failure mechanisms, can lead to variou…”
Background
Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries
Adams, B. D., Zheng, J.-M., Ren, X.-D., Xu, W., & Zhang, J.-G. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702097 · Cited by 1,223
Electrode Degradation in Lithium-Ion Batteries
Pender, J. P., Jha, G., Youn, D. H., Ziegler, J. M., Andoni, I., Choi, E. J., Heller, A., Dunn, B. S., Weiss, P. S., Penner, R. M., et al. (2020) · ACS Nano · doi:10.1021/acsnano.9b04365 · Cited by 873
On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries
Aurbach, D., Markovsky, B., Weissman, I., Levi, E., & Ein-Eli, Y. (1999) · Electrochimica Acta · doi:10.1016/s0013-4686(99)00194-2 · Cited by 833
Self-citation
Sodium Metal Anodes: Emerging Solutions to Dendrite Growth
Lee, B., Paek, E., Mitlin, D., & Lee, S. W. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00642 · Cited by 958
Fluorinated Solid-Electrolyte Interphase in High-Voltage Lithium Metal Batteries
Li, T., Zhang, X., Shi, P., & Zhang, Q. (2019) · Joule · doi:10.1016/j.joule.2019.09.022 · Cited by 719
Lithium Metal Anodes with Nonaqueous Electrolytes
Zhang, J., Xu, W., Xiao, J., Cao, X., & Liu, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00275 · Cited by 739
Recent Progress in Understanding Solid Electrolyte Interphase on Lithium Metal Anodes
Wu, H., Jia, H., Wang, C., Zhang, J., & Xu, W. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202003092 · Cited by 605
Liquid electrolyte: The nexus of practical lithium metal batteries
Wang, H., Yu, Z., Kong, X., Kim, S. C., Boyle, D. T., Qin, J., Bao, Z., & Cui, Y. (2022) · Joule · doi:10.1016/j.joule.2021.12.018 · Cited by 605
Applying Classical, Ab Initio , and Machine-Learning Molecular Dynamics Simulations to the Liquid Electrolyte for Rechargeable Batteries
Yao, N., Chen, X., Fu, Z., & Zhang, Q. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00904 · Cited by 583
Moving beyond 99.9% Coulombic efficiency for lithium anodes in liquid electrolytes
Hobold, G. M., Lopez, J., Guo, R., Minafra, N., Banerjee, A., Meng, Y. S., Shao‐Horn, Y., & Gallant, B. M. (2021) · Nature Energy · doi:10.1038/s41560-021-00910-w · Cited by 564
Deciphering the multi-step degradation mechanisms of carbonate-based electrolyte in Li batteries
Gachot, G., Grugeon, S., Armand, M., Pilard, S., Guenot, P., Tarascon, J., & Laruelle, S. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2007.11.110 · Cited by 388
On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions
Lu, Z., Schechter, A., Moshkovich, M., & Aurbach, D. (1999) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(99)00146-1 · Cited by 516
Self-citation
Correlating Structure and Function of Battery Interphases at Atomic Resolution Using Cryoelectron Microscopy
Li, Y., Huang, W., Li, Y., Pei, A., Boyle, D. T., & Cui, Y. (2018) · Joule · doi:10.1016/j.joule.2018.08.004 · Cited by 455
Visualization of electrode-electrolyte interfaces in LiPF6/EC/DEC electrolyte for lithium ion batteries via in situ TEM.
Zeng, Z., Liang, W.-I., Liao, H.-G., Xin, H.-L. L., Chu, Y.-H., & Zheng, H.-M. (2014) · Nano letters (Print) · doi:10.1021/nl403922u · Cited by 347
A Mathematical Model for the Lithium-Ion Negative Electrode Solid Electrolyte Interphase
Christensen, J., & Newman, J. (2004) · Journal of The Electrochemical Society · doi:10.1149/1.1804812 · Cited by 330
Interface Engineering for Lithium Metal Anodes in Liquid Electrolyte
Zhai, P., Liu, L., Gu, X., Wang, T., & Gong, Y. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001257 · Cited by 386
Performance Enhancing Electrolyte Additives for Lithium Ion Batteries with Silicon Anodes
Dalavi, S., Guduru, P., & Lucht, B. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.076205jes · Cited by 286
Poor Stability of Li 2 CO 3 in the Solid Electrolyte Interphase of a Lithium‐Metal Anode Revealed by Cryo‐Electron Microscopy
Han, B., Zhang, Z., Zou, Y., Xu, K., Xu, G., Wang, H., Meng, H., Deng, Y., Li, J., & Gu, M. D. (2021) · Advanced Materials · doi:10.1002/adma.202100404 · Cited by 349
Thermal abuse performance of high-power 18650 Li-ion cells
Roth, E., & Doughty, D. (2004) · Journal of Power Sources · doi:10.1016/j.jpowsour.2003.09.068 · Cited by 268
High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes
Yang, Y., Davies, D. M., Yin, Y., Borodin, O., Lee, J. Z., Fang, C., Olguin, M., Zhang, Y., Sablina, E. S., Wang, X., et al. (2019) · Joule · doi:10.1016/j.joule.2019.06.008 · Cited by 268
Electrode potential influences the reversibility of lithium-metal anodes
Ko, S., Obukata, T., Shimada, T., Takenaka, N., Nakayama, M., Yamada, A., & Yamada, Y. (2022) · Nature Energy · doi:10.1038/s41560-022-01144-0 · Cited by 266
Fast galvanic lithium corrosion involving a Kirkendall-type mechanism
Lin, D., Liu, Y., Li, Y., Li, Y., Pei, A., Xie, J., Huang, W., & Cui, Y. (2019) · Nature Chemistry · doi:10.1038/s41557-018-0203-8 · Cited by 318
Diagnostic examination of thermally abused high-power lithium-ion cells
Abraham, D., Roth, E., Kostecki, R., McCarthy, K., Maclaren, S., & Doughty, D. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.04.088 · Cited by 258
High lithium oxide prevalence in the lithium solid–electrolyte interphase for high Coulombic efficiency
Hobold, G. M., Wang, C., Steinberg, K. J., Li, Y., & Gallant, B. M. (2024) · Nature Energy · doi:10.1038/s41560-024-01494-x · Cited by 308
“All have marked presence of ROCO 2 Li, as expected 40 .”
Resolving Nanoscopic and Mesoscopic Heterogeneity of Fluorinated Species in Battery Solid-Electrolyte Interphases by Cryogenic Electron Microscopy
Huang, W., Wang, H., Boyle, D. T., Li, Y., & Cui, Y. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c00194 · Cited by 294
In situ and quantitative characterization of solid electrolyte interphases.
Cresce, A. V., Russell, S. M., Baker, D. R., Gaskell, K. J., & Xu, K. (2014) · Nano letters (Print) · doi:10.1021/nl404471v · Cited by 246
Sodium insertion in carboxylate based materials and their application in 3.6 V full sodium cells
Abouimrane, A., Weng, W., Eltayeb, H., Cui, Y., Niklas, J., Poluektov, O. G., & Amine, K. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22864e · Cited by 274
Examining Solid Electrolyte Interphase Formation on Crystalline Silicon Electrodes: Influence of Electrochemical Preparation and Ambient Exposure Conditions
Schroder, K., Celio, H., Webb, L. J., & Stevenson, K. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp307372m · Cited by 243
In-Depth Interfacial Chemistry and Reactivity Focused Investigation of Lithium-Imide- and Lithium-Imidazole-Based Electrolytes.
Eshetu, G. G., Diemant, T., Grugeon, S., Behm, R., Laruelle, S., Armand, M., & Passerini, S. (2016) · ACS Applied Materials and Interfaces · doi:10.1021/acsami.6b04406 · Cited by 209
Diagnostic Characterization of High Power Lithium-Ion Batteries for Use in Hybrid Electric Vehicles
Zhang, X.-R., Ross, P., Kostecki, R., Kong, F., Sloop, S., Kerr, J., Striebel, K., Cairns, E., & Mclarnon, F. (2001) · Journal of The Electrochemical Society · doi:10.1149/1.1362541 · Cited by 209
Unveiling the Stable Nature of the Solid Electrolyte Interphase between Lithium Metal and LiPON via Cryogenic Electron Microscopy
Cheng, D., Wynn, T. A., Wang, X., Wang, S., Zhang, M.-H., Shimizu, R., Bai, S., Nguyen, H., Fang, C., Kim, M., et al. (2020) · Joule · doi:10.2139/ssrn.3640837 · Cited by 205
“Regardless of the structural difference in the models, consensus is that most SEIs in organic liquid or polymer electrolytes are comprised both inorganic species that are thermodynamically stable against lithium metal and organic species that are partially reduced by lithium metal.(6,7) A recent study using tip-enhanc…”
Background
Fluorine Chemistry in Rechargeable Batteries: Challenges, Progress, and Perspectives
Wang, Y., Yang, X., Meng, Y., Wen, Z., Han, R., Hu, X., Sun, B., Kang, F., Li, B., Zhou, D., et al. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00826 · Cited by 270
Reduction Mechanisms of Ethylene, Propylene, and Vinylethylene Carbonates A Quantum Chemical Study
Vollmer, J., Curtiss, L., Vissers, D., & Amine, K. (2004) · Journal of The Electrochemical Society · doi:10.1149/1.1633765 · Cited by 183
Minimized lithium trapping by isovalent isomorphism for high initial Coulombic efficiency of silicon anodes
Zhu, B., Liu, G., Lv, G.-X., Mu, Y., Zhao, Y.-L., Wang, Y.-X., Li, X., Yao, P.-C., Deng, Y., Cui, Y., et al. (2019) · Science Advances · doi:10.1126/sciadv.aax0651 · Cited by 182
Solid Electrolyte Interphase in Li-Ion Batteries: Evolving Structures Measured In situ by Neutron Reflectometry
Owejan, J. E., Owejan, J., Decaluwe, S., & Dura, J. (2012) · Chemistry of Materials · doi:10.1021/cm3006887 · Cited by 171
Evolution of the Solid–Electrolyte Interphase on Carbonaceous Anodes Visualized by Atomic-Resolution Cryogenic Electron Microscopy
Huang, W., Attia, P. M., Wang, H., Renfrew, S. E., Jin, N., Das, S., Zhang, Z., Boyle, D. T., Li, Y., Bazant, M. Z., et al. (2019) · Nano Letters · doi:10.1021/acs.nanolett.9b01515 · Cited by 199
Editors' Choice—Growth of Ambient Induced Surface Impurity Species on Layered Positive Electrode Materials and Impact on Electrochemical Performance
Faenza, N., Bruce, L., Lebens-Higgins, Z., Plitz, I., Pereira, N., Piper, L., & Amatucci, G. G. (2017) · Journal of The Electrochemical Society · doi:10.1149/2.0921714jes · Cited by 165
Reactions of singly-reduced ethylene carbonate in lithium battery electrolytes: a molecular dynamics simulation study using the ReaxFF.
Bedrov, D., Smith, G. D., & van Duin, A. V. (2012) · Journal of Physical Chemistry A · doi:10.1021/jp210345b · Cited by 165
Suppressing dendrite growth by a functional electrolyte additive for robust Li metal anodes
Wang, G., Xiong, X., Xie, D., Fu, X., Ma, X., Li, Y., Liu, Y., Zhang, L., Yang, C., & Liu, M. (2019) · Energy storage materials · doi:10.1016/j.ensm.2019.02.026 · Cited by 189
Controlling Li deposition below the interface
Cao, W., Li, Q., Yu, X., & Li, H. (2022) · eScience · doi:10.1016/j.esci.2022.02.002 · Cited by 204
Electrolyte and SEI Decomposition Reactions of Transition Metal Ions Investigated by On-Line Electrochemical Mass Spectrometry
Solchenbach, S., Hong, G., Freiberg, A. T. S., Jung, R., & Gasteiger, H. A. (2018) · Journal of The Electrochemical Society · doi:10.1149/2.0511814jes · Cited by 210
In Situ Study of Lithiation and Delithiation of MoS2 Nanosheets Using Electrochemical Liquid Cell Transmission Electron Microscopy.
Zeng, Z., Zhang, X.-W., Bustillo, K., Niu, K.-Y., Gammer, C., Xu, J., & Zheng, H.-M. (2015) · Nano letters (Print) · doi:10.1021/acs.nanolett.5b02483 · Cited by 148
On Electrolyte-Dependent Formation of Solid Electrolyte Interphase Film in Lithium-Ion Batteries: Strong Sensitivity to Small Structural Difference of Electrolyte Molecules
Takenaka, N., Suzuki, Y., Sakai, H., & Nagaoka, M. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp5018696 · Cited by 137
Operando monitoring the lithium spatial distribution of lithium metal anodes
Lv, S.-S., Verhallen, T., Vasileiadis, A., Ooms, F., Xu, Y.-L., Li, Z.-L., Li, Z.-C., & Wagemaker, M. (2018) · Nature Communications · doi:10.1038/s41467-018-04394-3 · Cited by 133
Role of surface oxides in the formation of solid-electrolyte interphases at silicon electrodes for lithium-ion batteries.
Schroder, K., Dylla, A. G., Harris, S., Webb, L. J., & Stevenson, K. (2014) · ACS Applied Materials and Interfaces · doi:10.1021/am506517j · Cited by 131
A 3D Framework with Li 3 N–Li 2 S Solid Electrolyte Interphase and Fast Ion Transfer Channels for a Stabilized Lithium‐Metal Anode
Ni, S., Zhang, M., Li, C., Gao, R., Sheng, J., Wu, X., & Zhou, G. (2022) · Advanced Materials · doi:10.1002/adma.202209028 · Cited by 149
Porous LiF layer fabricated by a facile chemical method toward dendrite-free lithium metal anode
Yuan, Y., Wu, F., Chen, G., Bai, Y., & Wu, C. K. (2019) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2019.03.014 · Cited by 140
Toward a Mechanistic Model of Solid–Electrolyte Interphase Formation and Evolution in Lithium-Ion Batteries
Spotte-Smith, E., Kam, R. L., Barter, D., Xie, X., Hou, T., Dwaraknath, S., Blau, S. M., & Persson, K. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.2c00517 · Cited by 120
Understanding solid electrolyte interphases: Advanced characterization techniques and theoretical simulations
Wu, J., Ihsan‐Ul‐Haq, M., Chen, Y., & Kim, J. (2021) · Nano Energy · doi:10.1016/j.nanoen.2021.106489 · Cited by 143
Atomic to Nanoscale Origin of Vinylene Carbonate Enhanced Cycling Stability of Lithium Metal Anode Revealed by Cryo-Transmission Electron Microscopy
Xu, Y., Wu, H., He, Y., Chen, Q., Zhang, J., Xu, W., & Wang, C. (2019) · Nano Letters · doi:10.1021/acs.nanolett.9b04111 · Cited by 149
Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries
Tan, S., Shadike, Z., Cai, X., Lin, R., Kludze, A., Borodin, O., Lucht, B. L., Wang, C., Hu, E., Xu, K., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-023-00199-1 · Cited by 118
“Instead of a random distribution of organic and inorganic components, the SEI formed in the presence of FEC is more ordered and appears to have a multilayer structure, consistent with the multilayer system proposed by Aurbach et al. [167].”
Characterization of lithium electrode in lithium imides/ethylene carbonate and cyclic ether electrolytes. II. Surface chemistry
Ota, H., Sakata, Y., Wang, X.-M., Sasahara, J., & Yasukawa, E. (2004) · doi:10.1149/1.1644137 · Cited by 118
Characterisation of the SEI formed on natural graphite in PC-based electrolytes
Herstedt, M., Andersson, A. M., Rensmo, H., Siegbahn, H., & Edström, K. (2004) · Electrochimica Acta · doi:10.1016/j.electacta.2004.06.006 · Cited by 116
The study of electrolyte solutions based on solvents from the “glyme” family (linear polyethers) for secondary Li battery systems
Aurbach, D., & Granot, E. (1997) · Electrochimica Acta · doi:10.1016/s0013-4686(96)00231-9 · Cited by 111
Self-citation
Revealing solid electrolyte interphase formation through interface-sensitive Operando X-ray absorption spectroscopy
Swallow, J., Fraser, M. W., Kneusels, N.-J. H., Charlton, J. F., Sole, C. G., Phelan, C. M. E., Björklund, E., Bencok, P., Escudero, C., Pérez-Dieste, V., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-33691-1 · Cited by 108
Poly (dimethylsiloxane) modified lithium anode for enhanced performance of lithium-sulfur batteries
Li, Q., Zeng, F., Guan, Y.-P., Jin, Z.-Q., Huang, Y.-Q., Yao, M., Wang, W.-K., & Wang, A. (2018) · Energy Storage Materials · doi:10.1016/j.ensm.2018.01.002 · Cited by 106
RETRACTED ARTICLE: Polymer electrolytes: characteristics and peculiarities
Ahmad, S. (2009) · Ionics · doi:10.1007/s11581-008-0309-x · Cited by 104
Retracted
Understanding the transport mechanism of lithium ions in solid-electrolyte interphase in lithium metal batteries with liquid electrolytes
Sun, S., Zhang, X., Wang, Y.-N., Li, J., Zhao, Z., & Huang, J. (2024) · Materials Today · doi:10.1016/j.mattod.2024.06.001 · Cited by 126
In Situ Observation of Solid Electrolyte Interphase Formation in Ordered Mesoporous Hard Carbon by Small-Angle Neutron Scattering
Bridges, C. A., Sun, X., Zhao, J., Paranthaman, M. P., & Dai, S. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp3012393 · Cited by 111
A physics-based aging model for lithium-ion battery with coupled chemical/mechanical degradation mechanisms
Dong, G.-Z., & Wei, J.-W. (2021) · Electrochimica Acta · doi:10.1016/j.electacta.2021.139133 · Cited by 102
The Impact of CO 2 Evolved from VC and FEC during Formation of Graphite Anodes in Lithium-Ion Batteries
Schwenke, K. U., Solchenbach, S., Demeaux, J., Lucht, B. L., & Gasteiger, H. A. (2019) · Journal of The Electrochemical Society · doi:10.1149/2.0821910jes · Cited by 151
Molecular Dynamics Simulations and Experimental Study of Lithium Ion Transport in Dilithium Ethylene Dicarbonate
Borodin, O., Zhuang, G.-R. V., Ross, P., & Xu, K. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp4000494 · Cited by 101
Nanostructural and Electrochemical Evolution of the Solid-Electrolyte Interphase on CuO Nanowires Revealed by Cryogenic-Electron Microscopy and Impedance Spectroscopy.
Huang, W., Boyle, D. T., Li, Y.-Z., Li, Y.-B., Pei, A., Chen, H., & Cui, Y. (2018) · ACS Nano · doi:10.1021/acsnano.8b08012 · Cited by 97
Vinyl Ethylene Carbonate as an Effective SEI-Forming Additive in Carbonate-Based Electrolyte for Lithium-Metal Anodes.
Yang, Y., Xiong, J., Lai, S.-B., Zhou, R., Zhao, M., Geng, H., Zhang, Y.-F., Fang, Y., Li, C.-C., & Zhao, J.-B. (2019) · ACS Applied Materials and Interfaces · doi:10.1021/acsami.8b20706 · Cited by 95
Characterization of Lithium Electrode in Lithium Imides/Ethylene Carbonate, and Cyclic Ether Electrolytes I. Surface Morphology and Lithium Cycling Efficiency
Ota, H., Wang, X.-M., & Yasukawa, E. (2004) · Journal of The Electrochemical Society · doi:10.1149/1.1644136 · Cited by 88
The Challenge of Lithium Metal Anodes for Practical Applications
Chen, Y., Luo, Y., Zhang, H., Qu, C., Zhang, H., & Li, X. (2019) · Small Methods · doi:10.1002/smtd.201800551 · Cited by 110
Reductive Decomposition Reactions of Ethylene Carbonate by Explicit Electron Transfer from Lithium: An eReaxFF Molecular Dynamics Study
Islam, M., & van Duin, A. V. (2016) · doi:10.1021/acs.jpcc.6b08688 · Cited by 83
Challenge and Strategies in Room Temperature Sodium-Sulfur Batteries: A Comparison with Lithium-Sulfur Batteries.
Lin, L.-S., Zhang, C.-K., Huang, Y.-Z., Zhuang, Y.-P., Fan, M., Lin, J., Wang, L.-S., Xie, Q.-S., & Peng, D.-L. (2022) · Small · doi:10.1002/smll.202107368 · Cited by 82
Accurate Model Parameter Identification to Boost Precise Aging Prediction of Lithium‐Ion Batteries: A Review
Ding, S., Li, Y., Dai, H., Wang, L., & He, X. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202301452 · Cited by 67
Current Density Regulated Atomic to Nanoscale Process on Li Deposition and Solid Electrolyte Interphase Revealed by Cryogenic Transmission Electron Microscopy
Xu, Y., Wu, H., Jia, H., Zhang, J., Xu, W., & Wang, C. (2020) · ACS Nano · doi:10.1021/acsnano.0c03344 · Cited by 92
Li+ Transport and Mechanical Properties of Model Solid Electrolyte Interphases (SEI): Insight from Atomistic Molecular Dynamics Simulations
Bedrov, D., Borodin, O., & Hooper, J. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b04247 · Cited by 80
Interfacial Structure and Dynamics of the Lithium Alkyl Dicarbonate SEI Components in Contact with the Lithium Battery Electrolyte
Borodin, O. A., & Bedrov, D. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp504598n · Cited by 88
Rearrange SEI with artificial organic layer for stable lithium metal anode
Kang, D., Hart, N., Koh, J., Ma, L.-G., Liang, W.-B., Xu, J., Sardar, S., & Lemmon, J. (2020) · doi:10.1016/j.ensm.2019.06.014 · Cited by 78
Analyzing Energy Materials by Cryogenic Electron Microscopy
Ren, X., Zhang, X., Xu, R. X., Huang, J., & Zhang, Q. (2020) · Advanced Materials · doi:10.1002/adma.201908293 · Cited by 95
LiH formation and its impact on Li batteries revealed by cryogenic electron microscopy
Vilá, R. A., Boyle, D. T., Dai, A. X., Zhang, W.-B., Sayavong, P., Ye, Y., Yang, Y., Dionne, J., & Cui, Y. (2023) · Science Advances · doi:10.1126/sciadv.adf3609 · Cited by 73
“FFT analysis of the SEI on Li metal shows a diffuse ring near the spatial frequency of Li 2 O (1 1 1) planes, suggesting that the SEI on Li metal is predominantly amorphous with nanocrystalline Li 2 O grains and organic Li alkyl carbonates ( 35 , 36 ).”
New Insights on the Good Compatibility of Ether-Based Localized High-Concentration Electrolyte with Lithium Metal
Li, T., Li, Y., Sun, Y.-L., Qian, Z., & Wang, R. (2021) · ACS Materials Letters · doi:10.1021/acsmaterialslett.1c00276 · Cited by 71
Efficient Li-Metal Plating/Stripping in Carbonate Electrolytes Using a LiNO3-Gel Polymer Electrolyte, Monitored by Operando Neutron Depth Profiling
Liu, M., Cheng, Z., Qian, K., Verhallen, T., Wang, C., & Wagemaker, M. (2019) · Chemistry of Materials · doi:10.1021/acs.chemmater.9b01325 · Cited by 69
Operando Gas Monitoring of Solid Electrolyte Interphase Reactions on Lithium
Hobold, G. M., Khurram, A., & Gallant, B. M. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.9b04550 · Cited by 82
Transmission Line Model for Description of the Impedance Response of Li Electrodes with Dendritic Growth
Drvarič-Talian, S., Bobnar, J., Sinigoj, A., Humar, I., & Gaberšček, M. (2019) · Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b05887 · Cited by 67
Characterization of the Cathode Electrolyte Interface in Lithium Ion Batteries by Desorption Electrospray Ionization Mass Spectrometry.
Liu, Y.-M., Nicolau, B., Esbenshade, J. L., & Gewirth, A. (2016) · Analytical Chemistry · doi:10.1021/acs.analchem.6b01292 · Cited by 67
Electrochemical Reactivity and Passivation of Silicon Thin-Film Electrodes in Organic Carbonate Electrolytes
Hasa, I., Haregewoin, A. M., Zhang, L., Tsai, W., Guo, J., Veith, G. M., Ross, P. N., & Kostecki, R. M. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.0c09384 · Cited by 82
Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase
Cao, C.-T., Pollard, T., Borodin, O., Mars, J., Tsao, Y.-C., Lukatskaya, M., Kasse, R. M., Schroeder, M., Xu, K., Toney, M., et al. (2021) · Chemistry of Materials · doi:10.1021/acs.chemmater.1c01744.s001 · Cited by 64
Interphase Design for Lithium-Metal Anodes.
Wang, Q.-D., Zhao, C.-L., Wang, S., Wang, J.-L., Wu, F., Ombrini, P., Ganapathy, S., Eustace, S., Bai, X.-D., Li, B., et al. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.4c15759 · Cited by 63
Self-citation
Engineering battery corrosion films by tuning electrical double layer composition
Yuan, X.-T., Cheng, D., Liu, B., Liang, K.-Y., Liang, K.-Y., Yu, J., Mecklenburg, M., Sautet, P., & Li, Y. (2024) · Joule · doi:10.1016/j.joule.2024.07.011 · Cited by 63
Electrolyte additives for enhanced thermal stability of the graphite anode interface in a Li-ion battery
Herstedt, M., Rensmo, H., Siegbahn, H., & Edström, K. (2004) · doi:10.1016/j.electacta.2004.01.016 · Cited by 62
Decoding Electrochemical Processes of Lithium‐Ion Batteries by Classical Molecular Dynamics Simulations
Tan, X., Chen, M., Zhang, J., Li, S., Zhang, H., Yang, L., Sun, T. S., Qian, X., & Feng, G. (2024) · Advanced Energy Materials · doi:10.1002/aenm.202400564 · Cited by 67
The Impact of Electrolyte Composition on Parasitic Reactions in Lithium Ion Cells Charged to 4.7 V Determined Using Isothermal Microcalorimetry
Downie, L., Hyatt, S., & Dahn, J. (2016) · doi:10.1149/2.0081602jes · Cited by 57
Solid electrolyte interphases at Li-ion battery graphitic anodes in propylene carbonate (PC)-based electrolytes containing FEC, LiBOB, and LiDFOB as additives
Bhatt, M. D., & O'Dwyer, C. (2015) · Chemical Physics Letters · doi:10.1016/j.cplett.2014.11.018 · Cited by 55
Visualizing the SEI formation between lithium metal and solid-state electrolyte
Ren, F., Wu, Y.-Q., Zuo, W.-H., Zhao, W.-G., Pan, S.-Y., Lin, H.-X., Yu, H., Lin, J., Lin, M., Yao, X.-Y., et al. (2024) · Energy & Environmental Science · doi:10.1039/d3ee03536k · Cited by 53
Mixed Mode Growth Model for the Solid Electrolyte Interface (SEI)
Kamyab, N., Weidner, J., & White, R. (2019) · ECS Meeting Abstracts · doi:10.1149/2.1101902jes · Cited by 53
Spectroscopic Characterization of Surface Films Formed on Edge Plane Graphite in Ethylene Carbonate-Based Electrolytes Containing Film-Forming Additives
Tsubouchi, S., Domi, Y., Doi, T., Ochida, M., Nakagawa, H., Yamanaka, T., Abe, T., & Ogumi, Z. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.028211jes · Cited by 53
Leveraging cryogenic electron microscopy for advancing battery design
Cheng, D., Lu, B., Raghavendran, G., Zhang, M., & Meng, Y. S. (2022) · Matter · doi:10.1016/j.matt.2021.11.019 · Cited by 58
Combined In Situ Raman and IR Microscopy at the Interface of a Single Graphite Particle with Ethylene Carbonate/Dimethyl Carbonate
Lanz, P., & Novák, P. (2014) · doi:10.1149/2.0021410jes · Cited by 52
Rationally Designed Fluorinated Amide Additive Enables the Stable Operation of Lithium Metal Batteries by Regulating the Interfacial Chemistry.
Zhou, P., Xia, Y., Hou, W., Yan, S., Zhou, H.-Y., Zhang, W., Lu, Y., Wang, P., & Liu, K. (2022) · Nano letters (Print) · doi:10.1021/acs.nanolett.2c01961 · Cited by 51

Authors: Aurbach, D., Ein‐Ely, Y., & Zaban, A.
Affiliations: Bar-Ilan University (IL)
ORCID: Aurbach, Doron
Zaban, Arie
Venue: Journal of The Electrochemical Society
Publisher: The Electrochemical Society
Published: 1994-01-01
Volume: 141
Issue: 1
Pages: L1-L3
ISSN: 0013-4651 (ISSN-L)
1945-7111
DOI: 10.1149/1.2054718
OpenAlex: W1970581450
Cited by: 344
References: 0
Citations by year: 2026: 9 · 2025: 14 · 2024: 25 · 2023: 19 · 2022: 23 · 2021: 25 · 2020: 36 · 2019: 28 · 2018: 14 · 2017: 17 · 2016: 9 · 2015: 10 · 2014: 17 · 2013: 3 · 2012: 10
FWCI: 11.75
Type: journal article
Language: en
Open access: closed
Licence: iopscience.iop.org/page/copyright (vor, 9471 d)
iopscience.iop.org/info/page/text-and-data-mining (tdm, 9471 d)
Locations: Journal of The Electrochemical Society (publishedVersion)
Topics: Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
Keywords: lithium electrode, surface films, lithium carbonate, lithium alkoxides, propylene carbonate, ethylene carbonate, dimethyl carbonate, LiAsF6, lithium perchlorate, LiPF6, lithium tetrafluoroborate, water-induced degradation, lithium metal anode

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

The Surface Chemistry of Lithium Electrodes in Alkyl Carbonate Solutions

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cited by

Metadata

Record

About these checks