The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Interfacial Properties of the a-Si∕Cu:Active–Inactive Thin-Film Anode System for Lithium-Ion Batteries
Open accessAbstract
Amorphous silicon thin films deposited on copper foil have been observed to exhibit near theoretical capacity for a limited number of cycles. The films, however, eventually delaminate, leading to failure of the anode. In order to better understand the mechanism of capacity retention and the ultimate failure mode of a model brittle active:elastic/plastic inactive anode system, the films were subjected to in situ adhesion tests while observing the film surface using scanning electron microscopy. Atomic force and transmission electron microscopy, and electrochemical cycling were conducted to analyze the emerging morphology of the films during cycling. The adhesion of the as-deposited Si film to the Cu substrate was measured to , reflecting a weak interface adhesion strength. Plastic deformation of the underlying Cu substrate combined with a ratcheting mechanism is proposed to occur in the system, with delamination failure mode occurring only after the formation of an interface imperfection. From the analysis of slow rate cycling experiments, nucleation of a lithium compound based on the interdiffusion of Si and Cu is identified as the most probable cause of the ultimate delamination failure of the deposited film.
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Cites
Timoshenko, S. P. (1936) · UCLA Biblioteca de Ingenieria Civil · Cited by 7,592
Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material
Idota, Y., Kubota, T., Matsufuji, A., Maekawa, Y., & Miyasaka, T. (1997) · Science · doi:10.1126/science.276.5317.1395 · Cited by 2,578
Electrochemical lithiation of tin and tin-based intermetallics and composites
Winter, M., & Besenhard, J. O. (1999) · Electrochimica Acta · doi:10.1016/s0013-4686(99)00191-7 · Cited by 1,676
Colossal Reversible Volume Changes in Lithium Alloys
Beaulieu, L. Y., Eberman, K. W., Turner, R. L., Krause, L. J., & Dahn, J. R. (2001) · Electrochemical and Solid-State Letters · doi:10.1149/1.1388178 · Cited by 1,241
Lithium alloy negative electrodes
Huggins, R. A. (1999) · Journal of Power Sources · doi:10.1016/s0378-7753(99)00124-x · Cited by 717
Reaction of Li with Alloy Thin Films Studied by In Situ AFM
Beaulieu, L. Y., Hatchard, T. D., Bonakdarpour, A., Fleischauer, M. D., & Dahn, J. R. (2003) · Journal of The Electrochemical Society · doi:10.1149/1.1613668 · Cited by 628
Small particle size multiphase Li-alloy anodes for lithium-ionbatteries
Yang, J. (1996) · Solid State Ionics · doi:10.1016/s0167-2738(96)00389-x · Cited by 573
Active/Inactive Nanocomposites as Anodes for Li-Ion Batteries
Mao, O. (1999) · Electrochemical and Solid-State Letters · doi:10.1149/1.1390715 · Cited by 275
The Electrochemical Reaction of Li with Amorphous Si-Sn Alloys
Beaulieu, L. Y., Hewitt, K. C., Turner, R. L., Bonakdarpour, A., Abdo, A. A., Christensen, L., Eberman, K. W., Krause, L. J., & Dahn, J. R. (2003) · Journal of The Electrochemical Society · doi:10.1149/1.1530151 · Cited by 192
Thin Film Cracking and Ratcheting Caused by Temperature Cycling
Huang, M., Suo, Z., Ma, Q., & Fujimoto, H. H. (2000) · Journal of materials research/Pratt's guide to venture capital sources · doi:10.1557/jmr.2000.0177 · Cited by 76
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Tomaszewska, A., Chu, Z., Feng, X., O'Kane, S., Liu, X., Chen, J., Ji, C., Endler, E., Li, R., Liu, L., et al. (2019) · eTransportation · doi:10.1016/j.etran.2019.100011 · Cited by 1,592
Research progress on silicon/carbon composite anode materials for lithium-ion battery
Shen, X., Tian, Z., Fan, R., Shao, L., Zhang, D., Cao, G., Kou, L., & Bai, Y. (2018) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2017.12.012 · Cited by 451
Wang, R., Wang, L., Liu, R., Li, X., Wu, Y., & Ran, F. (2024) · ACS Nano · doi:10.1021/acsnano.3c08712 · Cited by 336
Materials for Rechargeable Lithium-Ion Batteries
Hayner, C. M., Zhao, X., & Kung, H. H. (2012) · Annual Review of Chemical and Biomolecular Engineering · doi:10.1146/annurev-chembioeng-062011-081024 · Cited by 263
Metadata
- Authors
- Maranchi, J. P., Hepp, A. F., Evans, A. G., Nuhfer, N. T., & Kumta, P. N.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2006
- Volume
- 153
- Issue
- 6
- Pages
- A1246
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W1996689450
- Cited by
- 296
- References
- 10
- FWCI
- 2.36
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Maranchi, J. P., Hepp, A. F., Evans, A. G., Nuhfer, N. T., & Kumta, P. N. (2006). Interfacial Properties of the a-Si∕Cu:Active–Inactive Thin-Film Anode System for Lithium-Ion Batteries. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2184753
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