CoChat
Sign Up
Cited by 661Fuel Cells and Related MaterialsMembrane-based Ion Separation TechniquesAdvancements in Solid Oxide Fuel Cells

A Comparative Study of Water Uptake By and Transport Through Ionomeric Fuel Cell Membranes

Open access
Zawodzinski, Thomas A., Springer, Thomas E., Davey, John, Jestel, Roger, Lopez, Cruz, Valerio, Judith, Gottesfeld, Shimshon·1993·Journal of The Electrochemical Society
DOI 10.1149/1.2220749
Open this paper in CoChat — free accountOpen PDF

Abstract

Water uptake and transport parameters measured at 30°C for several available perfluorosulfonic acid membranes are compared. The water sorption characteristics, diffusion coefficient of water, electroosmotic drag, and protonic conductivity were determined for Nafion® 117, Membrane C, and Dow XUS 13204.10 developmental fuel cell membrane. The diffusion coefficient and conductivity of each of these membranes were determined as functions of membrane water content. Experimental determination of transport parameters, enables us to compare membranes without the skewing effects of extensive features such as membrane thickness which contributes in a nonlinear fashion to performance in polymer electrolyte fuel cells.

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1149/1.2220749

Cites

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Cites

No references could be resolved yet.

Research works printed but not linked: 38

  1. [1]1. Kordesch, J. Eldridge, R. W. Hoffman, and J. Blue, Electrochim. Acta, 28, 1205 (1983).
  2. [3]3. D. Scherson, A. A. Tanaka, S. L. Gupta, D. Tryk, C. Fierro, R. Holze, and E. B. Yeager, Electrochim. Acta, 31, 1247 (1986).
  3. [4]4. K. A. Radyushkina and M. R. Tarasevich, Elek- trokhimiya, 22, 1155 (1986).
  4. [5]5. A. WidelSv and R. Larson, Electrochim. Acta, 37, 187 (1992).
  5. [6]6. J. Huang, in Fuel Cells, R. E. White and A. J. Appleby, Editors, PV 89-14, p. 268, The Electrochemical Soci- ety Softbound Proceedings Series, Pennington, NJ (1989).
  6. [7]7. T. Sawaguchi, T. Itabashi, T. Matsue, and I. Uchida, J. Electroanal. Chem., 279, 219 (1990).
  7. [8]8. A. Kaisheva, S. Gamburtsev, and I. Iliev, Sov. J. Elec- trochem., 18, 127 (1982).
  8. [9]9. K. Wiesener, Electrochim. Acta, 31, 1073 (1986).
  9. [10]10. K. Wiesener, D. Ohms, V. Neuman, and R. Franke, Mater Chem. Phys., 22, 457 (1989).
  10. [11]11. J. A. R. van Veen, H. A. Colijn, and J. E van Baar, Elec- trochim. Acta, 33, 801 (1988).
  11. [12]12. B. van Wingerden, J. A. R. van Veen, and C. T. J. Men- sih, J. Chem. Soc., Faraday Trans. 1, 84, 64 (1988).
  12. [13]13. J. McBreen, W. E. O'Grady, D. E. Sayers, and O. Y. Yang, Abstract 523, p. 746, The Electrochemical So- ciety Extended Abstracts, Vol. 87-1, Philadelphia, PA, May 10-15, 1987.
  13. [14]14. S. Gupta, D. Tryk, I. Bae, W. Aldred, and E. Yeager, J. Appl. Electrochem., 19, 19 (1989).
  14. [15]15. M. C. Martins Alves, J. P. Dodelet, D. Guay, M. Ladouceur, and G. Tourillon, J. Phys. Chem., 96, 10898 (1992).
  15. [16]16. L. Dignard-Bailey, R. Schultz, M. Trudeau, M. Ladouceur, G. Lalande, D. Guay, and J. P. Dodelet, To be published. 29. A. Van der Putten, W. Visscher, and E. Barendrecht, J. Electroanal. Chem., 195, 63 (1985).
  16. [17]17. E. Yeager, Electrochim. Acta, 29, 1527 (1984).
  17. [18]18. M. Savy, E Coowar, J. Riga, J. J. Verbiest, G. Brono~l, and S. Besse, J. Appl. Electrochem., 20, 260 (1990).
  18. [19]19. M.R. Tarasevich and K. A. Radyushkina, Mater. Chem. Phys., 22, 477 (1989).
  19. [20]20. G. Gruenig, K. Wiesener, S. Gamburzev, I. Iliev, and A. Kaisheva, J. Electroanal. Chem., 159, 155 (1983).
  20. [21]21. W. Betteridge, in Cobalt and Its Alloys, Ellis Horwood Series Industrial Metals, E. G. West, Series Editor, John Wiley & Sons, Inc., New York (1982).
  21. [22]22. E P. J. M. Kerkhof andJ. A. Moulijn, J. Phys. Chem., 83, 1612 (1979).
  22. [23]23. P. He, J. Lu, and C. Cha, J. Electroanal. Chem., 313, 347 (1991).
  23. [24]24. F. A. Walker, J. Am. Chem. Soc., 92, 4235 (1970).
  24. [25]25. Z. Deng, A. R. Wolf, L. C. Schumacher, T. G. Ryan, S. D. Howe, and M. J. Dignam, Abstract 52, p. 77, The Electrochemical Society Extended Abstracts, Vol. 92-2, Toronto, ON, Canada, Oct. 11-16, 1992.
  25. [27]27. T.E. Springer, T. A. Zawodzinski, Jr., and S. Gottesfeld, This Journal, 138, 2363 (1991).
  26. [28]28. T. A. Zawodzinski, Jr., C. Derouin, S. Radzinski, R. J. Sherman, T. Springer, and S. Gottesfeld, ibid., 140, 1041 (1993).
  27. [29]29. T. A. Zawodzinski, M. Neeman, L. Sillerud, and S. Gottesfeld, J. Phys. Chem., 95, 6040 (1991).
  28. [31]31. E. O. Stejskal and J. E. Tanner, J. Chem. Phys., 42, 288 (1965).
  29. [32]32. M. Neeman, K. Jarrett, L. Sillerud, and J. Freyer, Can- cer Research, 51, 4072 (1991).
  30. [33]33. N. Bunce, S. Sondheimer, and C. Fyfe, Macromol., 19, 333 (1986).
  31. [34]34. K. K. Pushpa, D. Nandan, and R. M. Iyer, J. Chem. Soc. Faraday 1, 84, 2047 (1988).
  32. [35]35. H. E Gibbard and G. Scatchard, J. Chem. Eng. Data, 18, 293 (1973).
  33. [38]38. R Schroeder, Z. Phys. Chem., 45, 75 (1903).
  34. [40]40. S. C. Yeo and A. Eisenberg, J. Appl. Poly. Sci., 21, 875 (1977).
  35. [41]41. A. B. LaConti, A. R. Fragala, and J. R. Boyack, in Elec- trode Materials and Processes for Energy Conversion and Storage, J. D. E. McIntyre, S. Srinivasan, and E G. Will, Editors, PV 77-6, p. 354, The Electrochem- ical Society Softbound Proceedings Series, Prince- ton, NJ (1977).
  36. [42]42. T.E. Springer, T. A. Zawodzinski, and S. Gottesfeld, in Modeling of Batteries and Fuel Cells, R. E. White, M. Verbrugge, and J. S. Stuckel, Editors, PV 91-10, p. 209, The Electrochemical Society Softbound Pro- ceedings Series, Pennington, NJ (1991).
  37. [43]43. R C. Rieke and N. E. Vanderborgh, J. Memb. Sci., 32, 313 (1987).
  38. [44]44. T. Fuller and J. Newman, This Journal, 139, 1332 (1992).

Cited by

Sorted by citations

Related

Authors
Zawodzinski, T. A., Springer, T. E., Davey, J., Jestel, R., Lopez, C., Valerio, J., & Gottesfeld, S.
Affiliations
  • Los Alamos National Laboratory (US)
  • Electronics Materials and Device Research, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
ORCID
Venue
Journal of The Electrochemical Society
Publisher
The Electrochemical Society
Published
1993-07-01
Volume
140
Issue
7
Pages
1981-1985
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
DOI
10.1149/1.2220749
OpenAlex
W2171743874
Cited by
661
References
0
Citations by year
2026: 10 · 2025: 12 · 2024: 11 · 2023: 15 · 2022: 14 · 2021: 18 · 2020: 12 · 2019: 18 · 2018: 14 · 2017: 12 · 2016: 29 · 2015: 28 · 2014: 19 · 2013: 22 · 2012: 46
FWCI
7.91
Type
journal article
Language
en
Open access
Licence
Locations
Journal of The Electrochemical Society (publishedVersion)
Funders
U.S. Department of Energy
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
  • Physical Sciences › Engineering › Biomedical Engineering › Membrane-based Ion Separation Techniques
  • Physical Sciences › Materials Science › Materials Chemistry › Advancements in Solid Oxide Fuel Cells
Keywords
water absorption, water transport, perfluorosulfonic acid membranes, proton exchange membrane fuel cells, water sorption, water diffusion coefficient, electro-osmotic drag, proton conductivity, membrane hydration, Nafion 117, membrane comparison

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review