Electrochemical Reduction of High Pressure CO 2 on Ni Electrodes
Open accessAbstract
The electrochemical reduction of under high pressures of was investigated on Ni electrodes. With an increase in pressure, the Faradaic efficiency for reduction was increased while that of evolution by water reduction was decreased. Current density at −1.8 V vs. did not depend greatly on pressure at 30°C. By increasing temperature, the Faradaic efficiency for hydrocarbon formation was increased, suggesting that thermal activation was needed, although the total reduction efficiency for reduction was decreased. The Faradaic efficiency for the hydrocarbon formation showed a maximum at −1.6 V , while those for and were increased with increasing cathodic polarization. The weight distribution of hydrocarbons formed on Fe, Co, and Ni electrodes agreed well with the Schultz‐Flory distribution, indicating that hydrocarbons were formed via a mechanism similar to a Fischer‐Tropsch reaction for thermal catalysis, i.e. , polymerization of surface carbene groups produced by the reduction of which was formed by reduction.
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In H cell reactors, the increased CO2 solubility achieved at lower temperatures improves the selectivity for CO2RR as compared to the HER.
“In these systems, the increased CO2 solubility achieved at lower temperatures (Figure .13) improves the selectivity for CO2RR as compared to the HER.[239][240][241][242][243][244]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [241]
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Cites
The publisher hasn’t deposited this paper’s reference list.
Research works printed but not linked: 28
- K. Ito, S. Ikeda, and IV[. Okabe, Denki Kagaku, 48, 247 (1980);
- K. Ira, S. Ikeda, T. Iida, and H. Niwa, ibid., 49, 106 (1981).
- S. Nakagawa, A. Kudo, M. Azuma, and T. Sakata, J. ElectroanaI. Chem., 308, 339 (1991).
- G. A. Mills and E W. Steffgen, Catal. Rev., 8, 159 (1973) and references therein.
- C. A. Luengo, A. L. Cabrera, H. B. MacKay, and M. B. Maple, J. Carat., 47, 1 (1977).
- J.-A. Dalmon and G. A. Martin, J. Chem. Sac., Faraday Trans. 1, 75, 1011 (1979).
- J. L. Falconer and A. E. Zagli, J. Catal., 62, 280 (1980).
- T. Inui, M. Funabiki, and Y. Takegami, J. Chem. Sac., Faraday Trans. 1, 76, 2237 (1980);
- T. Inui and T. Takeguchi, Catal. Today, 19, 95 (1991).
- G. D. Weatherbee and C. H. Bartholomew, J. Catal., 68, 67 (1981); ibid., 87, 352 (1984).
- M. Pijolat, V. Perrichon, M. Primet, and P. Bussi~re, J. Mol. Catal., 17, 367 (1982).
- Y. Arakawa, Syokubai (Catalysis), 31, 558 (1989).
- M. Azuma, K. Hashimoto, M. Hiramoto, M. Watanabe, and T. Sakata, J. Electroanal. Chem., 260, 441 (1989);
- M. Azuma, K. Hashimoto, M. Hiramoto, M. Wata- nabe, and T. Sakata, This Journal, 137, 1772 (1990).
- H. Noda, S. Ikeda, Y. Oda, K. Imai, M. Maeda, and K. Ito, Bull. Chem. Sac. Jpn., 63, 2459 (1990).
- Y. Hori, A. Murata, R. Takahashi, and S. Suzuki, J. Am. Chem. Sac., 109, 5022 (1987);
- Y. Hori, A. Murata, and R. Takahashi, J. Chem. Sac., Faraday Trans. 1, 85, 2309 (1989).
- R. L. Cook, R. C. MacDuff, and A. F. Sammells, This Journal, 135, 1320 (1988).
- D. W. DeWulf, T. Jin, and A. J. Bard, ibid., 136, 1686 (1989).
- J. J. Kim, D. P. Summers, and K. W. Frese, Jr., J. Elec- troanal. Chem., 245, 223 (1988).
- Y. Hori and A. Murata, Electrochim. Acta, 35, 1777 (1990).
- M. Azuma, K. Hashimoto, M. Watanabe, and T. Sakata, J. Electroanal. Chem., 294, 299 (1990).
- R. L. Cook, R. C. MacDuff, and A. E Sammells, in Pro- ceedings of International Symposium on Chemical Fixation of Carbon Dioxide, p. 39, Nagoya (1991).
- D. P. Summers and K. W. Frese, Jr., Langmuir, 4, 51 (1988).
- K. W. Frese, This Journal, 138, 3338 (1991).
- Yu. B. Vassiliev, V. S. Bagotzky, N. V. Osetrova, O. A. Khazova, and N. A. Mayorova, J. Electroanal. Chem., 189, 271 (1985).
- G. Henrici-Oliv6 and S. Oliv6, Angew. Chem. Int. Ed. Engl., 15, 136 (1976).
- S.-C. Chang and M. J. Weaver, J. Phys. Chem., 95, 5391 (1991).
Cited by
Sorted by citations
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990 · see citing works
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331 · see citing works
Ebbesen, S. D., Jensen, S. H., Hauch, A., & Mogensen, M. B. (2014) · Chemical Reviews · doi:10.1021/cr5000865 · Cited by 640 · see citing works
Garg, S., Li, M., Weber, A. Z., Ge, L., Li, L., Rudolph, V., Wang, G., & Rufford, T. E. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta13298h · Cited by 482 · see citing works
Catalyst–electrolyte interface chemistry for electrochemical CO 2 reduction
Jin, Y., Lee, C. W., Lee, S. Y., Na, J., Lee, U., & Hwang, Y. J. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00030b · Cited by 472 · see citing works
Dechlorination of Trichloroethene in Aqueous Solution Using Fe0
Orth, W. S., & Gillham, R. W. (1995) · Environmental Science & Technology · doi:10.1021/es950053u · Cited by 422 · see citing works
Electrochemical reduction of carbon dioxide on flat metallic cathodes
Jitaru, M., Löwy, D. A., Toma, M., Toma, B. C., & Oniciu, L. (1997) · Journal of Applied Electrochemistry · doi:10.1023/a:1018441316386 · Cited by 388 · see citing works
O’Brien, C. P., Miao, R. K., Zeraati, A. S., Lee, G., Sargent, E. H., & Sinton, D. A. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00206 · Cited by 367 · see citing works
Hara, K., Kudo, A., & Sakata, T. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)03935-a · Cited by 317 · see citing works
Self-citationNew trends in the development of heterogeneous catalysts for electrochemical CO 2 reduction
Kumar, B., Brian, J. P., Atla, V., Kumari, S., Bertram, K. A., White, R. T., & Spurgeon, J. M. (2016) · Catalysis Today · doi:10.1016/j.cattod.2016.02.006 · Cited by 313 · see citing works
Chaplin, R. P. S., & Wragg, A. A. (2003) · Journal of Applied Electrochemistry · doi:10.1023/b:jach.0000004018.57792.b8 · Cited by 290 · see citing works
Long-chain hydrocarbons by CO2 electroreduction using polarized nickel catalysts
Zhou, Y., Martín, A. J., Dattila, F., Xi, S., López, N., Pérez‐Ramírez, J., & Yeo, B. S. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00803-5 · Cited by 283 · see citing works
Electrocatalytic conversion of CO2 to long carbon-chain hydrocarbons
Centi, G., Perathoner, S., Win, G., & Gangeri, M. (2007) · Green Chemistry · doi:10.1039/b615275a · Cited by 197 · see citing works
Todoroki, M., Hara, K., Kudo, A., & Sakata, T. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)04010-l · Cited by 178 · see citing works
Self-citationOperation of a Pressurized System for Continuous Reduction of CO<sub>2</sub>
Dufek, E. J., Lister, T. E., Stone, S. G., & McIlwain, M. E. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.011209jes · Cited by 162 · see citing works
Hou, J., Chang, X., Li, J., Xu, B., & Lu, Q. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c09956 · Cited by 133 · see citing works
Pressure dependence in aqueous-based electrochemical CO2 reduction
Huang, L., Gao, G. F., Yang, C., Li, X., Miao, R. K., Xue, Y., Xie, K., Ou, P., Yavuz, C. T., Han, Y., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-38775-0 · Cited by 128 · see citing works
Gawel, A., Jaster, T., Siegmund, D., Holzmann, J., Lohmann, H., Klemm, E., & Apfel, U. (2022) · iScience · doi:10.1016/j.isci.2022.104011 · Cited by 128 · see citing works
“Furthermore, changes in selectivity of the CO2RR were reported and attributed to facilitated CO desorption at higher CO2 pressures (Hori and Murata, 1990; Kibria et al., 2019; Kudo et al., 1993; Ramdin et al., 2019).”
BackgroundEffect of CO2 pressure on photocatalytic reduction of CO2 using TiO2 in aqueous solutions
Mizuno, T., Adachi, K., Ohta, K., et al. (1996) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/1010-6030(96)04334-1 · Cited by 115 · see citing works
Bevilacqua, M., Filippi, J., Miller, H. A., & Vizza, F. (2015) · Energy Technology · doi:10.1002/ente.201402166 · Cited by 112 · see citing works
Carbon dioxide activation by aza-macrocyclic complexes
Costamagna, J., Ferraudi, G. J., Canales, J., & Vargas, J. (1996) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(95)01231-1 · Cited by 109 · see citing works
Electrochemical reduction of carbon dioxide at ruthenium dioxide deposited on boron-doped diamond
Spătaru, N., Tokuhiro, K., Terashima, C., Rao, T. N., & Fujishima, A. (2003) · Journal of Applied Electrochemistry · doi:10.1023/b:jach.0000003866.85015.b6 · Cited by 106 · see citing works
Innovations in catalysis towards efficient electrochemical reduction of CO2 to C1 chemicals
Ahmed, S., Hussain, M. S., Khan, M. K. I., & Kim, J. (2025) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2025.03.055 · Cited by 110 · see citing works
Recent Advances in Electrocatalytic Reduction of Carbon Dioxide Using Metal-Free Catalysts
Mao, X., & Hatton, T. A. (2015) · Industrial & Engineering Chemistry Research · doi:10.1021/ie504336h · Cited by 104 · see citing works
Mizuno, T., Ohta, K., Sasaki, A., AKAI, T., Hirano, M., & KAWABE, A. (1995) · Energy Sources · doi:10.1080/00908319508946098 · Cited by 98 · see citing works
Enabling Electrocatalytic Fischer–Tropsch Synthesis from Carbon Dioxide Over Copper-based Electrodes
Shibata, H., Moulijn, J. A., & Mul, G. (2008) · Catalysis Letters · doi:10.1007/s10562-008-9488-3 · Cited by 93 · see citing works
Formation of Hydrocarbons from the Reduction of Aqueous CO2 by Zero-Valent Iron
Hardy, L., & Gillham, R. W. (1995) · Environmental Science & Technology · doi:10.1021/es950054m · Cited by 88 · see citing works
Wang, Z., Zhou, Y., Qiu, P., Xia, C., Fang, W., Jin, J., Huang, L., Deng, P., Su, Y., Crespo‐Otero, R., et al. (2023) · Advanced Materials · doi:10.1002/adma.202303052 · Cited by 90 · see citing works
Vos, R. E., & Koper, M. T. M. (2024) · ACS Catalysis · doi:10.1021/acscatal.4c00009 · Cited by 84 · see citing works
Zhao, S., Guo, S., Zhu, C. Y., Gao, J., Li, H., Huang, H., Liu, Y., & Kang, Z. (2017) · RSC Advances · doi:10.1039/c6ra26868d · Cited by 87 · see citing works
Electrochemistry and environment: The role of electrocatalysis*1
Trasatti, S. P. M. (1995) · International Journal of Hydrogen Energy · doi:10.1016/0360-3199(95)00014-5 · Cited by 86 · see citing works
Large Current Density CO2 Reduction under High Pressure Using Gas Diffusion Electrodes
Hara, K., & Sakata, T. (1997) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.70.571 · Cited by 82 · see citing works
Self-citationSacco, A. (2018) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2018.06.020 · Cited by 81 · see citing works
Effects of mass transfer on the electrocatalytic CO 2 reduction on Cu
Lim, C. F. C., Harrington, D. A., & Marshall, A. T. (2017) · Electrochimica Acta · doi:10.1016/j.electacta.2017.04.017 · Cited by 80 · see citing works
Hydrocarbon Formation in Metallic Iron/Water Systems
Deng, B., Campbell, T. J., & Burris, D. R. (1997) · Environmental Science & Technology · doi:10.1021/es960698+ · Cited by 76 · see citing works
Electrochemical reduction of CO2 for synthesis of green fuel
Malik, K., Singh, S., Basu, S., & Verma, A. (2017) · Wiley Interdisciplinary Reviews Energy and Environment · doi:10.1002/wene.244 · Cited by 74 · see citing works
Electrochemical CO2 reduction on a glassy carbon electrode under high pressure
Hara, K., Kudo, A., & Sakata, T. (1997) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(96)01028-5 · Cited by 73 · see citing works
Self-citationProietto, F., Patel, U., Galia, A., & Scialdone, O. (2021) · Electrochimica Acta · doi:10.1016/j.electacta.2021.138753 · Cited by 75 · see citing works
Hirota, K., Tryk, D. A., Yamamoto, T., et al. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp9822945 · Cited by 72 · see citing works
Saeki, T., Hashimoto, K., Kimura, N., Omata, K., & Fujishima, A. (1996) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)04374-8 · Cited by 71 · see citing works
Jaster, T., Gawel, A., Siegmund, D., Holzmann, J., Lohmann, H., Klemm, E., & Apfel, U. (2022) · iScience · doi:10.1016/j.isci.2022.104010 · Cited by 70 · see citing works
“The diversity of possible products obtained by copper catalysts illustrates the complexity of the reduction reaction (Hori, 2008; Kuhl et al., 2012; Nitopi et al., 2019).”
BackgroundMa, M., & Seger, B. J. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202401185 · Cited by 67 · see citing works
Bagchi, D., Roy, S., Sarma, S. C., & Peter, S. C. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202209023 · Cited by 65 · see citing works
Wang, H., Kang, X., & Han, B. (2025) · Chemical Society Reviews · doi:10.1039/d5cs00780a · Cited by 72 · see citing works
Theoretical insight on reactivity trends in CO 2 electroreduction across transition metals
Akhade, S. A., Luo, W., Nie, X., Asthagiri, A., & Janik, M. J. (2015) · Catalysis Science & Technology · doi:10.1039/c5cy01339a · Cited by 62 · see citing works
High‐Pressure CO Electroreduction at Silver Produces Ethanol and Propanol
Raaijman, S. J., Schellekens, M. P., Corbett, P. J., & Koper, M. T. M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202108902 · Cited by 62 · see citing works
Saxena, A., Liyanage, W. P. R., Masud, J., Kapila, S., & Nath, M. (2021) · Journal of Materials Chemistry A · doi:10.1039/d0ta11518e · Cited by 63 · see citing works
Electrochemical reduction of dichloromethane to higher hydrocarbons
KOTSINARIS, A., Kyriacou, G., & Lambrou, C. (1998) · Journal of Applied Electrochemistry · doi:10.1023/a:1003202203067 · Cited by 58 · see citing works
De Jesús-Cardona, H., del Moral, C., & Cabrera, C. R. (2001) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(01)00598-8 · Cited by 54 · see citing works
Soontornchaiyakul, W., Yoshino, S., Kanazawa, T., et al. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c06413 · Cited by 54 · see citing works
Self-citationHara, K., Tsuneto, A., Kudo, A., & Sakata, T. (1997) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(97)00045-4 · Cited by 50 · see citing works
Self-citationMorrison, A. R. T., Ramdin, M., van den Broeke, L. J. P., de Jong, W., Vlugt, T. J. H., & Kortlever, R. (2022) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.2c00520 · Cited by 48 · see citing works
Electrochemical Reduction of CO2 in a Mixed Supercritical Fluid
Abbott, A. P., & Eardley, C. A. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp9932867 · Cited by 44 · see citing works
Electrochemical reduction of high pressure carbon dioxide on Fe electrodes at large current density
Hara, K., Kudo, A., & Sakata, T. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)03917-6 · Cited by 44 · see citing works
Self-citationCarbon dioxide utilization—Electrochemical reduction to fuels and synthesis of polycarbonates
Machado, A. S. R., Nunes, A. V. M., & da Ponte, M. N. (2017) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2017.12.023 · Cited by 41 · see citing works
Reduction of aqueous CO2 at ambient temperature using zero-valent iron-based composites
Guan, G., Kida, T., Ma, T., Kimura, K., Abe, E., & Yoshida, A. (2003) · Green Chemistry · doi:10.1039/b304395a · Cited by 39 · see citing works
Electrochemical Reduction of Protic Supercritical CO2 on Copper Electrodes
Melchaeva, O., Voyame, P., Bassetto, V. C., Prokein, M., Renner, M., Weidner, E., Petermann, M., & Battistel, A. (2017) · ChemSusChem · doi:10.1002/cssc.201701205 · Cited by 36 · see citing works
Padilla, M. A., Baturina, O. A., Gordon, J. P., Artyushkova, K., Atanassov, P. B., & Serov, A. (2017) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2017.03.006 · Cited by 31 · see citing works
Chen, J., Li, J., Xu, J. M., Zhu, M., & Han, Y. (2021) · Green Energy & Environment · doi:10.1016/j.gee.2021.05.006 · Cited by 29 · see citing works
A review on ultra‐small undoped MoS2 as advanced catalysts for renewable fuel production
Liu, G.-P., Ding, L., Meng, Y., Ali, A., Zuo, G., Meng, X.-G., Chang, K., Li, O.-L., & Ye, J.-H. (2024) · Carbon Energy · doi:10.1002/cey2.521 · Cited by 28 · see citing works
Efficient electrochemical conversion of CO2 into formic acid using colloidal NiCo@rGO catalyst
Arsalan, M., Ewis, D., Ba-Abbad, M. M., et al. (2024) · Results in Engineering · doi:10.1016/j.rineng.2024.101824 · Cited by 30 · see citing works
Nallas, G. N. A., & Brewer, K. J. (1996) · Inorganica Chimica Acta · doi:10.1016/s0020-1693(96)05103-1 · Cited by 29 · see citing works
Noble metal-free catalysts supported on carbon for CO 2 electrochemical reduction
Pérez-Rodríguez, S., Pastor, E., & Lázaro, M. J. (2017) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2017.01.010 · Cited by 27 · see citing works
Performing electrocatalytic CO2 reduction reactions at a high pressure
Chen, B., Feng, M., Chen, Y., Yang, J., & Liu, Y. (2024) · Carbon Neutrality · doi:10.1007/s43979-024-00106-7 · Cited by 28 · see citing works
“However, under high-pressure conditions, the main products shifted to CO and HCOOH, accompanied by a significant suppression of the hydrogen evolution reaction (HER) [43, 44, 54, 69].”
Proietto, F., Li, S., Loria, A., Hu, X., Galia, A., Ceccato, M., Daasbjerg, K., & Scialdone, O. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.132251 · Cited by 25 · see citing works
Sampling dynamics for pressurized electrochemical cells
Dufek, E. J., Lister, T. E., & Stone, S. G. (2014) · Journal of Applied Electrochemistry · doi:10.1007/s10800-014-0693-z · Cited by 26 · see citing works
NiO/MWCNT Catalysts for Electrochemical Reduction of CO2
Bashir, S., Hossain, S. S., Rahman, S. U., Ahmed, S., & Hossain, M. M. (2015) · Electrocatalysis · doi:10.1007/s12678-015-0270-1 · Cited by 25 · see citing works
Messias, S., Sousa, M. M., da Ponte, M. N., Rangel, C. M., Pardal, T. C., & Machado, A. S. R. (2019) · Reaction Chemistry & Engineering · doi:10.1039/c9re00271e · Cited by 24 · see citing works
Proietto, F., Berche, F., Galia, A., & Scialdone, O. (2020) · Journal of Applied Electrochemistry · doi:10.1007/s10800-020-01505-1 · Cited by 23 · see citing works
CO2 Conversion on N-Doped Carbon Catalysts via Thermo- and Electrocatalysis: Role of C–NOx Moieties
Hursán, D., Ábel, M., Baán, K., Fako, E., Samu, G. F., Nguyën, H. C., López, N., Atanassov, P. B., Kónya, Z., Sápi, A., et al. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c01589 · Cited by 23 · see citing works
Nellaiappan, S., & Sharma, S. (2019) · ACS Applied Energy Materials · doi:10.1021/acsaem.9b00242 · Cited by 22 · see citing works
Chlorine in NiO promotes electroreduction of CO2 to formate
Rodriguez-Olguin, M. A., Flox, C., Ponce-Pérez, R., et al. (2022) · Applied Materials Today · doi:10.1016/j.apmt.2022.101528 · Cited by 21 · see citing works
Nellaiappan, S., Kumar, R., Shivakumara, C., Irusta, S., Hachtel, J. A., Idrobo, J. C., Singh, A. K., Tiwary, C. S., & Sharma, S. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b05087 · Cited by 17 · see citing works
Electrochemical reduction of CO2 at metallic electrodes
Augustyński, J., Kedzierzawski, P., & Jermann, B. (1998) · Studies in surface science and catalysis · doi:10.1016/s0167-2991(98)80731-3 · Cited by 18 · see citing works
Progress and prospects of high-pressure CO 2 electrocatalytic reduction
Tian, X., Xu, G., Chen, S., Li, Q., & Duan, J. (2025) · Journal of Materials Chemistry A · doi:10.1039/d5ta03027g · Cited by 17 · see citing works
A temperature-controlled photoelectrochemical cell for quantitative product analysis
Corson, E. R., Creel, E. B., Kim, Y.-S., Urban, J. J., Kostecki, R. M., & McCloskey, B. D. (2018) · Review of Scientific Instruments · doi:10.1063/1.5024802 · Cited by 16 · see citing works
Hussain, M. S., Ahmed, S., Irshad, M., Bibi, S. S., Asif, M., Sher, F., & Khan, M. K. I. (2024) · Nano Materials Science · doi:10.1016/j.nanoms.2024.09.001 · Cited by 19 · see citing works
Wu, X., Zhang, Y., Zhou, Y., Sun, D., Yan, Q., Zhang, H., Yang, S., Wu, J., & Zou, Y. (2026) · Advanced Materials · doi:10.1002/adma.202522368 · Cited by 14 · see citing works
Electrochemical Reduction of CO2 in Micropores
Yamamoto, T., Hirota, K., Tryk, D. A., Hashimoto, K., Fujishima, A., & Okawa, M. (1998) · Chemistry Letters · doi:10.1246/cl.1998.825 · Cited by 14 · see citing works
Ougitani, Y., Aizawa, T., Sonoyama, N., & Sakata, T. (2001) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.74.2119 · Cited by 14 · see citing works
Self-citationHwang, S. Y., Maeng, J. Y., Park, G. E., Yang, S. Y., Kim, S. Y., Rhee, C. K., & Sohn, Y. (2023) · Chemosphere · doi:10.1016/j.chemosphere.2023.139616 · Cited by 13 · see citing works
High-Pressure Electrochemical CO 2 Capture and Reduction to Formic Acid
Lam, W.-Y. V., Wi, T., Elgazzar, A., et al. (2025) · ACS Energy Letters · doi:10.1021/acsenergylett.5c02165 · Cited by 12 · see citing works
Photocatalytic Reduction of CO2 with Dispersed TiO2/Cu Powder Mixtures in Supercritical CO2
Mizuno, T., Tsutsumi, H., Ohta, K., et al. (1994) · Chemistry Letters · doi:10.1246/cl.1994.1533 · Cited by 12 · see citing works
Hara, K., Sonoyama, N., & Sakata, T. (1997) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.70.745 · Cited by 12 · see citing works
Self-citationElectrochemical Fischer–Tropsch chemistry
Hwang, S. Y., Yun, G., Yeo, B. S., & Sohn, Y. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.165806 · Cited by 11 · see citing works
Chandrashekar, S., Nesbitt, N. T., & Smith, W. A. (2020) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.0c01894 · Cited by 11 · see citing works
Yang, J. H., Sim, G. B., Park, S. J., Rhee, C. K., Myung, C. W., & Sohn, Y. (2024) · Advanced Energy Materials · doi:10.1002/aenm.202402062 · Cited by 11 · see citing works
Electrochemical synthesis of methane on (110) facets of carbides via MvK mechanism
Ashraf, N., & Abghoui, Y. (2025) · Electrochimica Acta · doi:10.1016/j.electacta.2025.146069 · Cited by 9 · see citing works
Electroreduction of CO2 Catalyzed by Metallomacrocyclics
Costamagna, J. A., Isaacs, M. A., Aguirre, M. J., et al. (2007) · Springer eBooks · doi:10.1007/978-0-387-28430-9_5 · Cited by 9 · see citing works
Proietto, F., Raso, S. L., Prestigiacomo, C., et al. (2025) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2025.117871 · Cited by 7 · see citing works
Vos, R. E., & Koper, M. T. M. (2025) · ChemistryEurope · doi:10.1002/ceur.202500223 · Cited by 8 · see citing works
van den Berg, D., Izelaar, B., Fu, S., et al. (2023) · Catalysis Science & Technology · doi:10.1039/d3cy01411h · Cited by 6 · see citing works
Advances in Electrochemical Carbon Dioxide Reduction Toward Multi-carbon Products
Lawrence, K. R., Kumar, A. S., Asperti, S., van den Berg, D., Girichandran, N., & Kortlever, R. (2022) · Royal Society of Chemistry eBooks · doi:10.1039/9781839167645-00388 · Cited by 6 · see citing works
New approaches in CO2 reduction
Fujishima, A., Tryk, D. A., & Rao, T. N. (1998) · Studies in surface science and catalysis · doi:10.1016/s0167-2991(98)80724-6 · Cited by 6 · see citing works
Fabrication of superhydrophobic metallic porous surfaces via CO2 and water processing
Anagnostopoulos, A. N., Nikulin, A., Knauer, S., et al. (2023) · Applied Surface Science · doi:10.1016/j.apsusc.2023.157546 · Cited by 5 · see citing works
Proietto, F., Cammisa, G., Contino, M., et al. (2024) · ChemSusChem · doi:10.1002/cssc.202400440 · Cited by 5 · see citing works
Electrochemical Reduction of CO 2
Scibioh, M. A., & Viswanathan, B. (2018) · Elsevier eBooks · doi:10.1016/b978-0-444-63996-7.00007-9 · Cited by 5 · see citing works
Carbon Dioxide Recycling into Fuels and Valuable Chemicals
Beschkov, V. N. (2025) · Energies · doi:10.3390/en18030702 · Cited by 4 · see citing works
Experimental screening of intermetallic alloys for electrochemical CO2 reduction
van den Berg, D., Brouwer, J. C., Hendrikx, R. W. A., et al. (2024) · Catalysis Today · doi:10.1016/j.cattod.2024.114805 · Cited by 4 · see citing works
Nazir, M. A., Abou–Krisha, M. M., Afzal, S., Ullah, S., Najam, T., Bashir, S., Abdelrahman, E. A., & Shah, S. S. A. (2026) · Separation and Purification Technology · doi:10.1016/j.seppur.2026.138086 · Cited by 4 · see citing works
- Authors
- Kudo, A., Nakagawa, S., Tsuneto, A., & Sakata, T.
- Affiliations
- Tokyo Institute of Technology (JP)
- ORCID
- Kudo, Akihiko
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1993-06-01
- Volume
- 140
- Issue
- 6
- Pages
- 1541-1545
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2009745924
- Cited by
- 120
- References
- 0
- Citations by year
- 2026: 7 · 2025: 13 · 2024: 11 · 2023: 6 · 2022: 9 · 2021: 6 · 2020: 3 · 2019: 6 · 2018: 3 · 2017: 8 · 2016: 2 · 2015: 6 · 2014: 3 · 2013: 1 · 2012: 2
- FWCI
- 5.92
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Journal of The Electrochemical Society (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- electrochemical CO2 reduction, high-pressure CO2, nickel electrodes, Faradaic efficiency, hydrocarbon generation, water reduction, temperature effects, cathodic polarization
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
