Cited by 40Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationSubcritical and Supercritical Water Processes

Review—Supercritical Deposition: A Powerful Technique for Synthesis of Functional Materials for Electrochemical Energy Conversion and Storage

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Barim, Sansim Bengisu, Uzunlar, Erdal, Bozbag, Selmi Erim, Erkey, Can·2020·Journal of The Electrochemical Society

Abstract

Supercritical fluid-based technologies are increasingly being used to develop novel functional nanostructured materials or improve the properties of existing ones. Among these, supercritical deposition (SCD) is an emerging technique to incorporate metals on supports. It has been used to deposit a wide variety of single or multi-metallic morphologies such as highly dispersed species, nanoparticles, nanorods and conformal films on high surface area supports, polymers and crystalline substrates. SCD is also attracting increasing attention for preparation of micro or nano-architectured functional materials in a highly controllable manner for electrochemical energy conversion and storage systems. Increasing number of studies in the literature demonstrates that materials synthesized using SCD are comparable or superior in performance as compared to their conventional counterparts. In this review, an overview of the fundamentals of the SCD technique is presented. Properties of a wide variety of nanostructured functional materials such as supported nanoparticles and films prepared using SCD for electrochemical applications are summarized. The electrochemical performance of these materials in electrochemical tests and also in fuel cells, electrolyzers and Li-ion batteries are also presented.

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  • SCD in combination with aerogels eliminates the risk of meso- and micropore deformation or collapse during impregnation of the Pt precursor and during depressurization, due to the absence of capillary forces in the supercritical state.

    “SCD can be considered a particularly attractive technique in combination with aerogels, since the risk of meso- and micropore deformation or collapse during the impregnation of Pt precursor and during the depressurization is eliminated due to the absence of capillary forces in the supercritical state.[55–59]”

    From Synthesis of Pt Carbon Aerogel Electrocatalysts with Multiscale Porosity Derived from Cellulose and Chitosan Biopolymer Aerogels via Supercritical Deposition for Hydrogen Evolution Reaction (2025) · cites this paper as [55]

    The review describes Pt-precursor adsorption onto carbon aerogels by SCD (Functional Materials for Electrochemical Applications Using Supercritical Deposition; page unavailable). It also says supercritical fluids have zero surface tension and that avoiding a phase change during depressurization enables aerogel products (Li-ion battery applications and Abstract; pages unavailable). It does not state that these properties eliminate meso- or micropore deformation or collapse during Pt impregnation and depressurization. (LLM, conf=0.84)

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Cited by

Sorted by citations

Authors
Barim, S. B., Uzunlar, E., Bozbag, S. E., & Erkey, C.
Affiliations
  • Izmir Institute of Technology (TR)
  • Koç University (TR)
Corresponding author
Erkey, Can
Venue
Journal of The Electrochemical Society
Published
2020-01-22
Volume
167
Issue
5
Pages
054510
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
OpenAlex
W3001130977
Cited by
40
References
3
Citations by year
2026: 4 · 2025: 7 · 2024: 7 · 2023: 5 · 2022: 8 · 2021: 3 · 2020: 6
FWCI
1.09
Type
journal article
Language
en
Open access
Locations
  • Journal of The Electrochemical Society (publishedVersion, cc-by)
  • Digital Collections portal (Koç University) (submittedVersion)
  • IYTE GCRIS Database (Izmir Institute of Technology) (submittedVersion, other-oa)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
  • Physical Sciences › Engineering › Biomedical Engineering › Subcritical and Supercritical Water Processes
Keywords
supercritical fluid synthesis, supported nanoparticles, nanorods, conformal films, nanostructured materials, metal-support interaction, electrochemical energy conversion, electrochemical energy storage, fuel cells, electrolyzer, lithium-ion batteries, high surface area supports

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