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Differential scanning calorimetry/small-angle X-ray scattering analysis of ultraviolet sensible polypropylene filaments
Abstract
In this work, ultraviolet (UV) sensible metallocene isotactic polypropylene (miPP) filaments were produced with different drawing ratios and various concentrations of photochromic pigment. The effects of pigment concentration and drawing ratio on the chromatic properties and the structural modification for the miPP filaments were studied extensively by differential scanning calorimetry (DSC) and small- and wide-angle X-ray scattering (SAXS/WAXS) measurements. The change in melting temperature and the polymeric structures, such as lamellar thickness, long period and degree of crystallinity of miPP with the addition of a UV sensible pigment into miPP and the drawing process, were evaluated. The results show that the pigment concentration and the drawing ratio influence the inner structure of miPP filaments. Finally, our investigation shows that SAXS and also WAXS are appropriate to determine the lamellar thickness and the degree of crystallinity established by the DSC approach. This work attempts to correlate the results of lamellar thickness, the degree of crystallinity and the higher-order structure of the polymer acquired by DSC as well as X-ray diffraction (XRD) techniques in order to develop an appropriate approach to find the influence of pigment concentration and drawing ratio on miPP filaments.
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The application of mass coloring or mass functionalization in melt extrusion (e.g., polylactic acid, viscose, infinna, spinnova, renewcell, ioncel) has the potential to decrease the pollution burden associated with both synthetic and regenerated fibers.
“Furthermore, the application of mass coloring or mass functionalization in the process of melt extrusion, namely in the case of polylactic acid, or in manmade fibers like viscose, infinna, spinnova, renewcell and ioncel has the potential to decrease the pollution burden associated with both synthetic and regenerate fibers [336][337][338][339].”
From Recent Advances in the Remediation of Textile-Dye-Containing Wastewater: Prioritizing Human Health and Sustainable Wastewater Treatment (2024) · cites this paper as [336]
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Periyasamy, A. P. (2024) · Sustainability · doi:10.3390/su16020495 · Cited by 652
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Metadata
- Authors
- Vikova, M., Sakurai, S., Periyasamy, A. P., Yasunaga, H., Pechočiaková, M., & Ujhelyiová, A.
- Affiliations
- Faculty of Textile Engineering, Technical University of Liberec, Czech Republic
- Faculty of Fiber Science and Engineering, Kyoto Institute of Technology, Japan
- Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Slovak Republic
- Venue
- Textile Research Journal
- Publisher
- SAGE Publications
- Published
- 2021-10-18
- Volume
- 92
- Issue
- 17-18
- Pages
- 3142-3153
- ISSN
- 0040-5175
- 1746-7748
- Cited by
- 8
- References
- 0
- Language
- en
- Funders
- Ministry of Education, Youth and Sports of the Czech Republic and the European Union - European Structural and Investment Funds (Operational Programme Research, Development and Ed)
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