Cited by 1Cultural Heritage Materials AnalysisMineralogy and Gemology StudiesArchaeological and Geological Studies

The DOI matches its Crossref record; 26 of the 28 references it cites were found in a registry or an index; none of the 60 sources its claims cite is checked for support yet.

Compositional analysis and cross-cultural examination of blue and blue-green post-fire colorants on Tolita-Tumaco ceramics

Open access
Reiss, Breanna F., Spilde, Michael, Peterson, Eric·2019·Boletín De Arqueología PUCP

Abstract

Este estudio explora los colorantes azules y azul-verdoso utilizados por la cultura Tolita-Tumaco de las costas antiguas de Ecuador y Colombia. Utilizando la difracción de Rayos X (DRX) y la microscopía electrónica de barrido (SEM) con la espectroscopía de energía dispersiva (EDS), se analizaron muestras de cada uno de los colorantes azul y azul-verdoso para identificar las composicións mineral. La muestra azul verdosa de una cerámica encontrada en La Tolita fue identificada como celadonita o glauconita. Las pruebas de DRX y SEM en una muestra azul de un fragmento de figurilla de cerámica encontrado a lo largo del río Mataje se identificaron tentativamente como los anfíboles sódicos glaucofano y riebeckite. Las pruebas de DRX sugieren además otros minerales que pueden afectar el color, como la cordierita, antigorita y celadonita o glauconita. La comparación intercultural proporciona información sobre cómo los grupos ecuatorianos costeros utilizaron estos colorantes y ejemplifica la naturaleza innovadora detrás de su creación. Parece que el desarrollo de azul y azul verdosa ecuatoriano se derivó de las tradiciones de colorantes locales, con algunas fuentes de pigmentos localizadas.

Overview

AI snapshot

Written from the paper’s full text.

TL;DR

XRD and SEM-EDS of two post-fire colorant samples from Tolita-Tumaco ceramics (Maxwell Museum Ferdon collection) identify the La Tolita blue-green paint as celadonite or glauconite ("green earth") and tentatively identify the Rio Mataje blue as sodic amphiboles (glaucophane/riebeckite), with no copper present. Cross-cultural comparison suggests these blue and blue-green ceramic colorants were developed locally on the Ecuadorian coast rather than derived from outside traditions.

Key findings

  • The La Tolita blue-green colorant (Munsell BG5 5/4) was identified by XRD and SEM-EDS as a Mg-Fe-Al phyllosilicate with high potassium, consistent with celadonite or glauconite — the main minerals of "green earth"; the two are indistinguishable by these methods.
  • The Rio Mataje blue (B5 5/8) yielded tentative XRD identifications of glaucophane/riebeckite, cordierite, and antigorite (or possibly kaolinite); SEM showed amphibole group minerals but did not directly corroborate the XRD phases. SEM showed no copper, ruling out copper-carbonate blues such as azurite.
  • The La Tolita sample's Munsell hue (5BG, value 5–6, chroma 4) is bluer, lighter, and more saturated than published green earth ranges (2G–8G, value 2.7–3.0, chroma 1.0–1.5), possibly indicating unidentified additives; the Rio Mataje blue is likewise brighter than typical sodic-amphibole blues.
  • Green earth is rare as a ceramic pigment elsewhere in pre-Hispanic Latin America (e.g., Rosalila at Copán, La Quemada, Pachacamac's Painted Temple, Huaca Ventarrón); the nearest known celadonite/glauconite source is the Cayo Arc (Manabí Province), outside the Tolita-Tumaco area, implying exchange with the Jama-Coaque. Combined with Romero et al. (2018), four green samples plus this blue-green sample document green earth as a post-fire pigment in Jama-Coaque and Tolita-Tumaco traditions.

Methods

  • Two colorant samples from the Ferdon collection (Maxwell Museum of Anthropology): a blue-green-painted incised rim sherd from La Tolita and a blue-painted figurine head from the Rio Mataje area; provenance reconstructed from object labels, museum records, and prior dissertations.
  • XRD: intact testing on a Rigaku D/Max Rapid II was inconclusive, so ~20 mg samples were scraped off each surface and run unground on a Rigaku SmartLab with Eulerian-cradle oscillation; ten theta/two-theta scans per sample were combined to improve sampling statistics.
  • SEM-EDS: carbon-coated stubs on a Tescan Vega 3 with IXRF analyzer at 15 kV and 1 nA, using backscattered imaging, element mapping, and point analyses; results were contextualized through iconographic and cross-cultural comparison.

Limitations

  • The authors state the sample size (two samples) is too small for definitive claims, and the Rio Mataje blue results are "not entirely conclusive," with mineral identifications only tentative and XRD and SEM not directly verifying one another.
  • Celadonite and glauconite cannot be distinguished by XRD or SEM-EDS; samples were not ground (poor diffraction statistics), and the possible off-white slip on the figurine would require thin sections to confirm (not done).
  • Provenance is incomplete: most Ferdon field records were lost or faded, some pieces were mislabeled, and the Rio Mataje figurine's exact findspot is uncertain (evident from the text's provenance discussion). Binders and possible color-altering additives remain unidentified, and the exact green earth source deposit has not been located.

Model-written summary. Check it against the paper before relying on it.

Integrity signals

Registry

Crossref · 10.18800/boletindearqueologiapucp.201902.007

Cites

26 of 26 references verified0 citation errors · 0 not checkable

Statistics

Nothing to recompute.

Verification

Claims the paper makes

0 of 60 cited sources checked · 0 supported · 0 flagged

  • Findingown data

    SEM results for the Rio Mataje blue sample show with some certainty that no copper is present in the blue sample.

    “SEM results for the Rio Mataje blue sample show with some certainty that no copper is present in the blue sample, which rules out many possible blue minerals.”
    • Also stated in: § 5. Concluding Remarks · hedged
      “The SEM results offered here suggest that the blue does not contain copper, which is in direct contrast to many of the blue colorants used in pre-Hispanic Latin America.”
    Quote in the paperSubstantial claim
  • Findingown data

    The intact XRD method on the La Tolita sherd produced inconclusive results.

    “Results from this method of analysis were inconclusive.”
    Quote in the paperNot a substantial claim
  • Findingown data

    Riebeckite was only tentatively identifiable with the quantitative data gathered in SEM point analyses.

    “The sodic amphibole riebeckite was only tentatively identifiable with the quantitative data gathered in SEM point analyses, but the potential of riebeckite and glaucophane as colorants can be further examined.”
    Quote in the paperNot a substantial claim
  • Findingown data

    XRD results for the La Tolita sample demonstrated several clear peaks corresponding to the phyllosilicate minerals celadonite or glauconite.

    “XRD results for the La Tolita sample demonstrated several clear peaks corresponding to the phyllosilicate minerals celadonite or glauconite (Fig. 7).”
    Quote in the paperSubstantial claim
  • Findingnone given

    The La Tolita blue-green sample was determined to be celadonite or glauconite.

    “The La Tolita blue-green sample was determined to be celadonite or glauconite, which are known as the most common minerals used in «green earth» pigment.”
    Quote in the paperSubstantial claim
  • It may state two separate claims as one. 27
  • Probably not a substantial claim. 53
  • It may state two separate claims as one.

    Findingown data

    The La Tolita sample has a hue of 5BG, values ranging from 5-6, and a chroma of 4.

    “The sample itself has a hue of 5BG, values ranging from 5-6, and a chroma of 4.”
    Quote in the paperSubstantial claim
  • It may state two separate claims as one.

    Findingown data

    SEM results showed amphibole group minerals, clay, a mineral containing cerium, and a pyrite inclusion in the Rio Mataje sample.

    “SEM results showed amphibole group minerals (Fig. 9), clay, one instance of a mineral containing the rare earth metal cerium, and one pyrite inclusion.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Findingown data

    Clay, possibly kaolinite, quartz, and an amphibole group mineral were also found in XRD tests of the La Tolita sample.

    “Clay, which is possibly kaolinite, quartz, and an amphibole group mineral were also found in XRD tests of the sample.”
    Quote in the paperNot a substantial claim
  • It may state two separate claims as one.

    Findingnone given

    The sherd found at La Tolita exhibits differences in colorant degradation; the red and yellow colorants are almost completely degraded, whereas the blue-green pigment remains more intact.

    “The sherd found at La Tolita exhibits differences in colorant degradation; the red and yellow colorants on the piece are almost completely degraded, whereas the blue-green pigment remains more intact.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Findingnone given

    Remnants of red and yellow post-fire paint are also found on other incised sections of the La Tolita sherd.

    “Remnants of red and yellow post-fire paint are also found on other incised sections.”
    Quote in the paperNot a substantial claim
  • It may state two separate claims as one.

    Findingown data

    The serpentine mineral antigorite or kaolinite clay, and cordierite, a cyclosilicate, are potential mineral colorants identified in XRD tests.

    “Additionally, the serpentine mineral, antigorite or kaolinite clay, and cordierite, a cyclosilicate, are potential mineral colorants identified in XRD tests.”
    Quote in the paperNot a substantial claim
  • It may state two separate claims as one.

    Findingnone given

    The blue-green pigment sample tested here was well adhered to the ceramic surface and was much less fugitive than the red and yellow colorants present.

    “Potential binders are unknown, but the blue-green pigment sample tested here was well adhered to the ceramic surface, and was much less fugitive than the red and yellow colorants present.”
    Quote in the paperNot a substantial claim
  • It may state two separate claims as one.

    Interpretationown data

    The minerals identified in the Rio Mataje sample have the potential to be responsible for the blue-green color, but their identifications are only tentative.

    “All of these minerals have the potential to be responsible for the adding color in the range of green to blue, but their identifications are only tentative.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    These figures were often painted in post-fire polychrome.

    “These figures are associated with many different actions and regalia and were often painted in post-fire polychrome (Meggers 1966;Cummins 1992;Valdez 1992).”
    Quote in the paperNot a substantial claim0 of 3 sources checked
    • cites Meggers 1966

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Cummins 1992

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Valdez 1992

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • It may state two separate claims as one.

    Interpretationown data

    The La Tolita sample's color ranges more towards blue-green hue and is lighter with more saturation than reported green earth ranges, which may suggest other unidentified additives.

    “These results range more towards the blue-green hue and are lighter in value with more saturation to the color, which may suggest the presence of other unidentified additives.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Study design and conductown data

    The second sample is from a small figurine head found somewhere along the Rio Mataje.

    “The second sample (Figs.45) is from a small figurine head found somewhere along the Rio Mataje (Fig. 3).”
    Quote in the paperNot a substantial claim
    • Rests on an assumption: The original accompanying label accurately identifies the figurine as collected along the Rio Mataje.
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    At Copan, Honduras, green paint on the Rosalila building contains celadonite.

    “At the archaeological site Copan in Honduras, Rosemary Goodall and her team (2006) found that a green paint covering the exterior or the well-preserved Rosalila building contains celadonite.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Goodall et al. 2006 source
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Green earth is a collection of siliceous minerals commonly used as pigments in many cultures worldwide.

    “Green earth is a collection of siliceous minerals that are commonly used as pigments in many cultures worldwide (Grissom 1986).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Grissom 1986

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • It may state two separate claims as one.

    Interpretationnone given

    Across pre-Hispanic Latin America, green earth has a variety of uses, but coastal Ecuador is one of the few places where it is found as a post-fire ceramic pigment.

    “Across pre-Hispanic Latin America, green earth has a variety of uses, but it seems that coastal Ecuador is one of the few places where it is found as a post-fire ceramic pigment.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Green earth was used as a post-fire ceramic pigment on polychrome pseudo-cloisonné ceramics from La Quemada in western Mexico.

    “In a rare example of green earth used as a post-fire ceramic pigment in pre-Hispanic Latin America outside of the Ecuadorian coast, the pigment was found on polychrome pseudo-cloisonné ceramics from La Quemada in western Mexico (Strazicich 2002).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Strazicich 2002

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Light blue-green colorants appear on objects attributed to the earlier Chorrera Period (1200-300 BC).

    “Light blue-green colorants appear on objects attributed the earlier Chorrera Period (1200-300 BC) (Cummins 1992).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Cummins 1992

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Reported Munsell color equivalents for green earth range from 2G to 8G hue, values 2.7 to 3.0, and chromas 1.0 to 1.5.

    “Reported equivalents of Munsell color hues for green earth range from 2G to 8G, values from 2.7 to 3.0, and chromas from 1.0 to 1.5 (Grissom 1986: 145).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Grissom 1986: 145

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it. The paper may give no reason why it holds.

    Interpretationnone given

    The frequency of green earth as a post-fire ceramic pigment in coastal Ecuador is perhaps best explained by the localized nature of the source.

    “Perhaps this frequency is best explained by the localized nature of the source.”
    Quote in the paperNot a substantial claim
  • It may state two separate claims as one.

    Interpretationreasoning

    The peak identified as antigorite on the diffractogram can alternatively be identified as kaolinite, a more likely option considering the sample's color.

    “The peak identified as Antigorite on the diffractogram can alternatively be identified as kaolinite, a more likely option considering the sample's color.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Celadonite and glauconite are the most common minerals used in green earth pigment.

    “The La Tolita blue-green sample was determined to be celadonite or glauconite, which are known as the most common minerals used in «green earth» pigment.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Grissom 1986

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Study design and conductown data

    The first sample was taken from a sherd identified as originating from the site La Tolita by a label on the ceramic itself.

    “The first sample was taken from a sherd (Figs.12) identified as originating from the site La Tolita by a label on the ceramic itself.”
    Quote in the paperNot a substantial claim
    • Rests on an assumption: The label on the La Tolita sherd accurately identifies its origin from the site La Tolita.
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Premisenone given

    The static female figurine most commonly wears a long skirt and a similar head cloth or headdress that appears to wrap around the head.

    “This static female figurine most commonly wears a long skirt and a similar head cloth or headdress that appears to wrap around the head.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Meggers 1966

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Premisecitation

    Teotihuacan used azurite for murals and stuccoed polychrome ceramics.

    “Teotihuacan used azurite for murals and stuccoed polychrome ceramics, the Maya occasionally used it on murals as well, and it is also found in Peru at Chan Chan on Huaca Tacaynamo murals, and Paracas resin painted pottery (Brooks et al. 2008;Fletcher 2002;de la Fuente 1995;Magaloni et al. 1995;Proulx 2009).”
    Quote in the paperNot a substantial claim0 of 3 sources checked
    • cites Brooks et al. 2008

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Fletcher 2002 source
    • cites de la Fuente 1995

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it. The paper may give no reason why it holds.

    Study design and conductnone given

    The identifying markings on the figurine are consistent with Ferdon's labeling method.

    “The identifying markings on the piece are consistent with Ferdon's labeling method.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Study design and conductown data

    Provenance information for the figurine was found on the original accompanying label, suggesting it was collected along the Rio Mataje.

    “Provenance information for this figurine was found on the original accompanying label, which suggests that it was collected along the Rio Mataje.”
    Quote in the paperNot a substantial claim
    • Rests on an assumption: The original accompanying label accurately identifies the figurine as collected along the Rio Mataje.
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. The paper may give no reason why it holds.

    Interpretationnone given

    Outside of the Ecuadorian coast, green earth may be most commonly used in pre-Hispanic Latin America as an architectural and rock art colorant.

    “Outside of the Ecuadorian coast, green earth may be most commonly used in pre-Hispanic Latin America as an architectural and rock art colorant.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    White kaolinite pigment used on ceramics amongst the Jama-Coaque may have originated from southeast Ecuador.

    “For instance, white kaolinite pigment used on ceramics amongst the Jama-Coaque may have originated from southeast Ecuador (Romero et al. 2018).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Romero et al. 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Premisecitation

    A pale green colorant at the Painted Temple at Pachacamac was identified as ferroceladonite, an iron-rich form of celadonite, but it is sparingly used at the site.

    “Researchers have identified a pale green colorant at the Painted Temple as ferroceladonite, an iron rich form of celadonite, but it is sparingly used at the site (Lujan 2018).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Lujan 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim.

    Study design and conductreasoning

    Combining ten theta/two theta scans from each sample provided a final pattern more representative of a randomly-oriented powder.

    “Ten theta/two theta scan data sets collected from each sample were then combined to provide a final pattern that was more representative of a randomly-oriented powder.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Premisecitation

    Glauconite is of marine origin, whereas celadonite is of altered volcanic origin.

    “The difference between these minerals is their formation; glauconite is a mineral of marine origin, whereas celadonite is of altered volcanic origin (Grissom 1986).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Grissom 1986

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Premisecitation

    A stucco mask panel sampled by Goodall showed over twenty layers of paint, indicating repainting over 520-655 AD.

    “A panel holding a stucco mask sampled for Goodall's study showed over twenty layers of paint, demonstrating that the mask had been repainted over the century (520-655 AD) that the Rosalila building was maintained.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Goodall et al. 2006 source
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Premisecitation

    Azurite is found in Peru at Chan Chan on Huaca Tacaynamo murals and on Paracas resin painted pottery.

    “Teotihuacan used azurite for murals and stuccoed polychrome ceramics, the Maya occasionally used it on murals as well, and it is also found in Peru at Chan Chan on Huaca Tacaynamo murals, and Paracas resin painted pottery (Brooks et al. 2008;Fletcher 2002;de la Fuente 1995;Magaloni et al. 1995;Proulx 2009).”
    Quote in the paperNot a substantial claim0 of 3 sources checked
    • cites Brooks et al. 2008

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Fletcher 2002 source
    • cites de la Fuente 1995

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Frescos and ceramics with both glaucophane and riebeckite, often mixed with Egyptian Blue, have been found at several Bronze Age Greek sites, but they are uncommon outside that particular time and space.

    “Frescos and ceramics with both glaucophane and riebeckite, often mixed with Egyptian Blue, have been found at several Bronze Age Greek sites, but they are uncommon outside of that particular time and space (Aloupi et al. 2000;Profi et al. 1977).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Aloupi et al. 2000

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Profi et al. 1977 source
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. The paper may give no reason why it holds.

    Premisecitation

    The most common blue pigment used in pre-Hispanic Latin America may be azurite, a copper carbonate.

    “Manmade creations like Maya Blue aside, the most common blue pigment used in pre-Hispanic Latin America may be azurite, a copper carbonate.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Interpretationreasoning

    The brighter blue on the Rio Mataje sample may signify other unidentified additives.

    “The blue present on the Rio Mataje sample is brighter than the typical sodic amphibole-produced blue, which may signify other unidentified additives.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    The Maya occasionally used azurite on murals.

    “Teotihuacan used azurite for murals and stuccoed polychrome ceramics, the Maya occasionally used it on murals as well, and it is also found in Peru at Chan Chan on Huaca Tacaynamo murals, and Paracas resin painted pottery (Brooks et al. 2008;Fletcher 2002;de la Fuente 1995;Magaloni et al. 1995;Proulx 2009).”
    Quote in the paperNot a substantial claim0 of 3 sources checked
    • cites Brooks et al. 2008

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Fletcher 2002 source
    • cites de la Fuente 1995

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • It may state two separate claims as one.

    Interpretationown data

    Glaucophane and riebeckite both have the potential to be responsible for the blue color.

    “The Rio Mataje sample XRD tests instead identified the sodic amphiboles glaucophane and riebeckite, both of which have the potential to be responsible for the blue color.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Colorants found on objects in the royal tombs of the Maya site Calakmul were made of the copper-zinc phosphate, veszelyite.

    “For example, colorants found on objects in the royal tombs of the Maya site Calakmul were made of the copper-zinc phosphate, veszelyite (Moreno et al. 2008).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Moreno et al. 2008

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Another study showed the potential for celadonite and glauconite to be the source for green and blue-green ceramic colorants along the Ecuadorian coast.

    “Although it is not certain that all or the majority of Ecuadorian blue-green and green colorants contain green earth, another study has further showed the potential for celadonite and glauconite to be the source for green and blue-green ceramic colorants along the Ecuadorian coast (Romero et al. 2018).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Romero et al. 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Interpretationreasoning

    The presence of kaolinite in lieu of antigorite is possible in the Rio Mataje sample.

    “The presence of the clay mineral, kaolinite, in lieu of antigorite is also possible, having a major peak at the same location as the antigorite peak.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    The Maya used white calcite stucco underneath paint to brighten the shade.

    “The Maya used white calcite stucco underneath the paint to brighten the shade, and added finely ground magnetite to alter the color (Goodall et al. 2006).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Goodall et al. 2006 source
  • It may state two separate claims as one.

    Interpretationreasoning

    With the proximity of celadonite and glauconite source material, and if the majority of coastal green and blue-green colorants contain green earth, then the pigment likely originated from local sources within the Cayo Arc.

    “With the proximity of celadonite and glauconite source material, and if the majority of the coastal green and blue-green colorants contain green earth, then the pigment likely originated from local sources within the Cayo Arc.”
    Quote in the paperSubstantial claim
    • The authors state this as an assumption: The majority of coastal Ecuadorian green and blue-green colorants contain green earth.
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Study design and conductreasoning

    The samples were not ground, resulting in poor diffracted intensity sampling statistics.

    “To avoid losing any weight on the small amounts of each colorant, the samples were not ground, resulting in poor diffracted intensity sampling statistics.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Interpretationcitation

    It is possible that the Ecuadorians traveled some distance to obtain pigments, considering their maritime skills and known evidence of pigment exchange.

    “It is possible that the Ecuadorians traveled some distance to obtain pigments, considering their maritime skills and known evidence of pigment exchange mentioned in this study and elsewhere (Sánchez-Polo 2018; Romero et al. 2018).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Sánchez-Polo 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Romero et al. 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • Rests on an assumption: There are no known sources for riebeckite close to the Tolita-Tumaco area in Ecuador or Colombia.
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Many more sporadic examples across the Americas have been shown to contain copper.

    “Many more sporadic examples across the Americas have also been shown to contain copper.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Interpretationreasoning

    The color may hold political and ideological significance as it is often found in association with representations of elaborately dressed figurines.

    “The color may ISSN 1029ISSN -2004 hold political and ideological significance as it is often found in association with representations of elaborately dressed figurines.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Green earth has been identified on rock painting in cave shelters at several early hunter-gatherer sites in Argentina.

    “In Argentina, green earth has been identified on rock painting in cave shelters at several early hunter-gatherer sites (Aldazabal et al. 2018;Boschin 2011;Rousaki et al. 2017;Wainwright et al. 2000).”
    Quote in the paperNot a substantial claim0 of 3 sources checked
    • cites Aldazabal et al. 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Boschin 2011

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Rousaki et al. 2017 source

      Checked before — its earlier verdict is held back until a new check runs.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    A green clay tentatively identified as green earth through chemical composition was used on older murals at Huaca Ventarrón (2300-2035 BC) in the Lambayeque Valley of Northern Peru.

    “A green clay that could also be tentatively identified as green earth through its chemical composition was used on much older murals at Huaca Ventarrón (2300-2035 BC) in the Lambayeque Valley of Northern Peru (Wright et al. 2015).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Wright et al. 2015 source

      Checked before — its earlier verdict is held back until a new check runs.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    A study at the Precolumbian Art Museum Casa del Alabado demonstrated that three out of four white ceramic colorants from the Jama-Coaque contained kaolinite clay, whereas the other was made of calcite.

    “A study conducted on ceramics at the Precolumbian Art Museum Casa del Alabado demonstrated that three out of four white ceramic colorants from the Jama-Coaque contained kaolinite clay, whereas the other was made of calcite (Romero et al. 2018).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Romero et al. 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Premisecitation

    The relationship that blue and blue-green colorants have with the figural form is unknown, and little research has been done into color associations on the coast.

    “The relationship that blue and blue-green colorants have with the figural form is unknown, and little research has been done into color associations on the coast (Sánchez-Polo 2018).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Sánchez-Polo 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Betty Meggers first pointed out a type of female figurine as a stylistic trope used across the coast.

    “Betty Meggers (1966) first pointed out this type of female figurine as a stylistic trope used across the coast.”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Meggers 1966

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Interpretationreasoning

    White kaolinite clay may have been used to further alter the final color of the Rio Mataje sample.

    “White koalinite clay may have been used to further alter the final color.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Pachacamac in Peru is one of the few areas in South America where green earth has been identified.

    “The coastal site of Pachacamac in Peru is one of the few areas in South America where green earth has been identified (Lujan 2018).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Lujan 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    The trend of creating hollow polychrome ceramic figurines lasted for many centuries.

    “The trend of creating hollow polychrome ceramic figurines lasted for many centuries (Valdez 1987).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Valdez 1987

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • It may state two separate claims as one.

    Interpretationown data

    The amphibole's iron and sodium content could suggest it is riebeckite intergrown with another calcic mineral, or impure riebeckite.

    “However, it contains iron and sodium, which could suggest that it is riebeckite intergrown with another calcic mineral, or impure riebeckite.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. The paper may give no reason why it holds. It may state two separate claims as one.

    Interpretationnone given

    Green and blue-green were used as a reflection of costume elements in real performances or displays, which may hold ideological and ritual associations.

    “It appears that green and blue-green were used as a reflection of costume elements used in real performances or displays, which may hold ideological and ritual associations.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    The Maya added finely ground magnetite to alter paint color.

    “The Maya used white calcite stucco underneath the paint to brighten the shade, and added finely ground magnetite to alter the color (Goodall et al. 2006).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Goodall et al. 2006 source
  • Probably not a substantial claim. The paper’s conclusions may not depend on it. It may state two separate claims as one.

    Interpretationreasoning

    The closest access point to the Cayo Arc is within the Manabí Province, suggesting the potential for trade relations with the Jama-Coaque culture.

    “The closest access point to the Cayo Arc is within the Manabí Province, suggesting the potential for trade relations with the Jama-Coaque culture.”
    Quote in the paperNot a substantial claim
    • Rests on an assumption: The closest access point to the Cayo Arc is within the Manabí Province.
  • It may state two separate claims as one.

    Interpretationnone given

    Figurines and figural objects where these colorants are found display elite status associations, and the colors were used on figurines for certain clothing aspects, like jewelry, headdresses, and skirts.

    “Figurines and figural objects where these colorants are found display elite status associations, and the colors were used on figurines for certain clothing aspects, like jewelry, headdresses, and skirts.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Past studies of Ecuadorian blue and green colorants have shown modern colorant additives, like phthalocyanine blue, thought by the researchers to be a product of past restoration attempts.

    “Past studies of Ecuadorian blue and green colorants have also shown modern colorant additives, like phthalocyanine blue, thought by the researchers to be a product of past restoration attempts (Sánchez-Polo et al. 2018).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Sánchez-Polo et al. 2018

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    Celadonite and glauconite are considered suitable bases for many other organic and mineral colorants.

    “Celadonite and glauconite are considered to be suitable bases for many other organic and mineral colorants (Grissom 1986).”
    Quote in the paperNot a substantial claim0 of 1 sources checked
    • cites Grissom 1986

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • It may state two separate claims as one.

    Interpretationown data

    The results show potential mineral sources for the colors, suggesting that not all blue post-fire colorants found on coastal Ecuadorian ceramics are the result of later additions and restoration.

    “Alternatively, they show potential mineral sources for the colors, suggesting that not all blue post-fire colorants found on coastal Ecuadorian ceramics are the result of later additions and restoration.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Study design and conductnone given

    The results for the Rio Mataje blue colorant were not entirely conclusive.

    “The results for the Rio Mataje blue colorant were not entirely conclusive.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper may give no reason why it holds.

    Interpretationnone given

    The use of green earth is not commonly seen as a pigment elsewhere in pre-Hispanic Latin America, with only a handful of identified examples on both continents.

    “The use of green earth is not commonly seen as a pigment elsewhere in the pre-Hispanic Latin America, with only a handful of identified examples on both continents.”
    Quote in the paperNot a substantial claim
  • It may state two separate claims as one.

    Interpretationreasoning

    Use of blue colorants was much more sporadic than other colors along the RDP Ecuadorian coast, possibly as a result of source material rarity.

    “Use of blue colorants was much more sporadic than other colors along the RDP Ecuadorian coast, possibly as a result of source material rarity.”
    Quote in the paperNot a substantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Premisecitation

    As other scholars have proposed, ceramic figurines in northern Ecuador appear to have ideological and high status associations behind their production and use.

    “As other scholars have proposed, ceramic figurines in northern Ecuador appear to have ideological and high status associations behind their production and use (Cummins 1992;Valdez 1992).”
    Quote in the paperNot a substantial claim0 of 2 sources checked
    • cites Cummins 1992

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

    • cites Valdez 1992

      Couldn’t be matched to a paper in Crossref, so it can’t be checked.

  • Probably not a substantial claim.

    Interpretationnone given

    Green earth was known to have been used as a colorant mainly for rock art and architecture, and was rarely used on ceramics.

    “Known to have been used as a colorant mainly for rock art and architecture, this pigment was rarely used on ceramics.”
    Quote in the paperSubstantial claim
  • Probably not a substantial claim. The paper’s conclusions may not depend on it.

    Interpretationreasoning

    Kaolinite may have been added to make the overall colors lighter on the Tolita-Tumaco ceramics tested in this study.

    “In contrast to the Jama-Coaque area, where the clay was used to produce a white pigment, kaolinite may have been added to make the overall colors lighter on the Tolita-Tumaco ceramics tested in this study.”
    Quote in the paperNot a substantial claim
68 of 68
  • The paper relies on this without support.

    Coastal Ecuador during the Regional Development Period (RDP) may be one of the only places in South America where blue and blue-green colorants were used on ceramics.

    “Coastal Ecuador during the Regional Development Period (RDP), dating from around 500 BC to 600 AD, may be one of the only places in South America where blue and blue-green colorants were used on ceramics.”
  • The paper relies on this without support.

    Blue and blue-green ceramic colorants in ancient South America are almost non-existent.

    “In ancient Mesoamerica, examples of Maya Blue and blue copper carbonate-based pigments are relatively widespread, but blue and blue-green ceramic colorants in ancient South America are almost non-existent.”
  • The paper relies on this without support.

    The post-fire blue and blue-green colorants used along the northern coast of Ecuador are notable for their vivid colors and longevity.

    “The post-fire blue and blue-green colorants used along the northern coast of Ecuador are notable for their vivid colors and longevity.”
  • The paper relies on this without support.

    The label on the La Tolita sherd accurately identifies its origin from the site La Tolita.

    “The first sample was taken from a sherd (Figs.12) identified as originating from the site La Tolita by a label on the ceramic itself.”
  • The paper relies on this without support.

    The original accompanying label accurately identifies the figurine as collected along the Rio Mataje.

    “Provenance information for this figurine was found on the original accompanying label, which suggests that it was collected along the Rio Mataje.”
  • The paper relies on this without support.

    Celadonite and glauconite are closely related and indistinguishable using XRD and SEM-EDS testing methods.

    “These minerals are closely related and indistinguishable using XRD and SEM-EDS testing methods.”
  • The paper relies on this without support.

    No mineral other than celadonite or glauconite could produce the observed XRD and SEM-EDS results for the blue-green colorant.

    “Together, the two tests indicate that the bluegreen color originates from celadonite or glauconite.”
  • The authors state this as an assumption.

    The majority of coastal Ecuadorian green and blue-green colorants contain green earth.

    “if the majority of the coastal green and blue-green colorants contain green earth”
  • The paper relies on this without support.

    There are no known sources of celadonite and glauconite within the Tolita-Tumaco cultural area.

    “There are no known sources of celadonite and glauconite within the Tolita-Tumaco cultural area, suggesting that these pigments or the objects bearing the colorant were obtained from elsewhere.”
  • The paper relies on this without support.

    Green and blue-green post-fire colorants were used with some frequency on coastal Ecuadorian ceramics.

    “Green and blue-green post-fire colorants were used with some frequency on coastal Ecuadorian ceramics and are often found on figural imagery, though they can also be seen on ceramic house forms and other pieces, like the sherd tested in this study.”
  • The paper relies on this without support.

    There are no known sources for riebeckite close to the Tolita-Tumaco area in Ecuador or Colombia.

    “There are no known sources for riebeckite close to the Tolita-Tumaco area in Ecuador or Colombia.”
  • The paper relies on this without support.

    The closest access point to the Cayo Arc is within the Manabí Province.

    “The closest access point to the Cayo Arc is within the Manabí Province, suggesting the potential for trade relations with the Jama-Coaque culture.”
  • The paper relies on this without support.

    With the exception of kaolinite, the minerals identified as potential colorants are not frequently found as colorants.

    “With the exception of kaolinite, these minerals are not frequently found as colorants.”
13 of 13

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

Each contradiction between two passages listed here was confirmed by an independent check.

  • Ferdon 1940b citation points outside the listed page range

    Minor

    The text cites page 259 of Ferdon 1940b, but the reference list gives that work a page range of 138-143. Page 259 falls instead within the listed range for Ferdon 1940a.

1 of 1

Citations

Cites

Flagged first, then by citations

2 of the 28 references couldn’t be matched to a known paper.

Research works printed but not linked: 16

  1. Aloupi, E., A.G. Karydas, and T. Paradellis (2000). Pigment analysis of wall paintings and ceramics from Greece and Cyprus. The optimum use of X-ray Spectrometry on specific archaeological issues, X-Ray Spectrometry 29(1), 18-24. https://doi.org/10.1002/(SICI)1097-4539(200001/02)29:1%3C18::AID-XRS397%3E3.0.CO;2-5 · DOI
  2. Boschin, M. T. (2011). Chemical and mineralogical analysis of Argentine Patagonian Rock Paintings: A Multidisciplinary Reading, L'Anthropologie 115 (3-4), 360-383.
  3. Brooks, W. E., V. Piminchumo, H. Suárez, J. C. Jackson, and J. P. McGeehin (2008). Mineral pigments at Huaca Tacaynamo (Chan Chan, Peru), Bulletin de l'Institut français d'études andines 37(3), 441-450.
  4. Cummins, T. (1992). Tradition in Ecuadorian Prehispanic Art: The Ceramics of Chorrera and Jama-Coaque, in: F. Valdez, D. Veintimilla, and M. Reyes (eds.), Amerindian Signs: 5,000 Years of Precolumbian Art in Ecuador, Quito.
  5. Ferdon Jr., E. N. (1940b). The Archaeological Survey of Ecuador, Palacio 47(6), 138-43.
  6. Ferdon Jr., E. N. (1941). Reconnaissance in Esmeraldas, Palacio 49(1), 7-15.
  7. Grissom, C. A. (1986). A study of green earth, in: Feller, R. (ed.), Artists' pigments: A handbook of their history and characteristics, 141-167, Archetype Publications, Ontario.
  8. Lubensky, E. H. (1991). The Ferdon collections of prehistoric ceramic vessels and sherds from Esmeraldas Province, Ecuador, Ph.D. Dissertation, Department of Anthropology, University of Missouri-Columbia, Columbia.
  9. Masucci, M. A. (2008). Early regional polities of costal Ecuador, in: H. Silverman and W. Isbell (eds.), Handbook of South American Archaeology, Springer-Verlag, New York City.
  10. Morante Carballo, F. E. (2004). Las Zeolitas de la costa de Ecuador (Guayaquil): geología, caracterización y apli- caciones, Ph.D. dissertation, Universidad Politécnica de Madrid, Madrid.
  11. Rice, P. M. (2016). Pottery analysis: A sourcebook, Second Edition, University of Chicago Press, Chicago.
  12. Bastidas, M., A. Sánchez Polo, M. Mármol Villarroel, and F. Espinoza Guerra (2018 ). Los pigmentos del desarrollo regional en la costa ecuatoriana: hallazgos de los analisis de laboratorio, in: V. Bravo (ed.) Pigmentos y brillos en la costa del Ecuador precolombino, Museo de Arte Precolombino Casa del Alabado, Quito.
  13. Sánchez-Polo, A. (2018). Pigmentos y brillos en la costa del Ecuador precolombino/ Pigments and Sheens on the Coast of Pre-Columbian Ecuador in: V. Bravo (ed.) Pigmentos y brillos en la costa del Ecuador precolombino, 21-53, Museo de Arte Precolombino Casa del Alabado, Quito.
  14. M.G Guérin (ed.), Crónicas iniciales de la conquista del Perú, 37-63, Plus Ultra, Buenos Aires.
  15. Simmons, M. P. (1970). The Ceramic sequence from La Carolina, Santa Elena Peninsula, Ecuador, Ph.D. Dissertation, Department of Anthropology, University of Arizona, Tucson.
  16. Strazicich, N. M. (2002). La Quemada's Pseudo-Cloisonné Tradition, Archaeology Southwest Magazine 16(1), 7.

Cited by

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Metadata

Authors
Reiss, B. F., Spilde, M., & Peterson, E.
Affiliations
University of New Mexico (US)
Venue
Boletín De Arqueología PUCP
Published
2019-09-24
Issue
27
Pages
117-132
ISSN
  • 1029-2004 (ISSN-L)
  • 2304-4292
OpenAlex
W2946891078
Cited by
1
References
28
Citations by year
2024: 1
FWCI
0.00
Type
journal article
Language
es
Open access
Locations
  • Boletín de Arqueología PUCP (publishedVersion, cc-by)
  • UNM’s Digital Repository (University of New Mexico) (submittedVersion)
  • LA Referencia (Red Federada de Repositorios Institucionales de Publicaciones Científicas) (submittedVersion, cc-by)
  • Portal de Revistas PUCP (N/A) (submittedVersion, cc-by)
Topics
  • Social Sciences › Arts and Humanities › Archeology (arts and humanities) › Cultural Heritage Materials Analysis
  • Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
  • Social Sciences › Arts and Humanities › Archeology (arts and humanities) › Archaeological and Geological Studies
Keywords
blue pigments, blue-green pigment, ceramic pigments, celadonite, glauconite, riebeckite, glaucophane, cordierite, antigorite, mineralogical composition, cross-cultural comparison, Ecuadorian coast, ceramic figurines

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